Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Zeitschrift für Naturforschung A

Maxwell’s Demon Observing Creation of a Molecular Vibration

C. A. Chatzidimitriou‐Dreismann

Published Jun 2, 2014• 1 citation
Publisher

Abstract

Quantum correlations and associated quantum information concepts (e. g. quantum discord, entanglement, quantum Maxwell’s demon) provide novel insights in various quantum-information processing tasks, quantum-thermodynamics processes, open-system dynamics, quantum molecular dynamics, and general many-body physics. We investigate a new effect of correlations accompanying collision of two quantum systems A and B, the latter being part of a larger (interacting) system B+D. In contrast to the usual case of a classical ‘environment’ or ‘demon’ (which can have only classical correlations with A+B during and after the collision), the quantum case exhibits striking new features. Here, in the frame of incoherent inelastic neutron scattering (INS) and vibrational dynamics of molecules, we report experimental evidence of a new phenomenon: quantum deficit of momentum transfer in an elementary neutron-molecule collision, in particular, in INS from single H2O molecules confined in channels with sub-nanometer diameter. The INS findings are in clear contrast to conventional theoretical expectations, but are naturally (albeit qualitative) interpreted in the frame of modern theory of quantumness of correlations, thus also proposing a new operational meaning of quantum discord and related measures.

DOI
10.5560/zna.2014-0005

Related papers

Quantumness of correlations and Maxwell's demon in molecular excitations created by neutron scattering

C. A. Chatzidimitriou‐Dreismann

Nonclassical correlations known as entanglement, quantum discord, quantum deficit, measurement‐induced disturbance, quantum Maxwell's demon, etc., may provide novel insights into quantum‐information processing, quantum‐thermodynamics processes, open‐system dynamics, quantum molecular dynamics, and general quantum chemistry. We study a new effect of quantumness of correlations accompanying collision of two distinguishable quantum systems A and B, the latter being part of a larger (interacting) system B + D. In contrast to the common assumption of a classical environment or “demon” D, the quantum case exhibits striking new qualitative features. Here, in the context of incoherent inelastic neutron scattering from H‐atoms which create molecular excitations (vibration, rotation, translation), we report theoretical and experimental evidence of a new phenomenon: a considerably reduced effective mass of H, or equivalently, an anomalous momentum‐transfer deficit in the neutron‐H collision. These findings contradict conventional theoretical expectations even qualitatively, but find a straightforward interpretation in the new theoretical frame under consideration. © 2015 Wiley Periodicals, Inc.

International Journal of Quantum Chemistry•May 15, 2015•6 citations

Quantumness of correlations and Maxwell's demons in elementary scattering processes—Energetic consequences

C. A. Chatzidimitriou‐Dreismann, Alexander Dreismann

The interactions between physical systems generally lead to the formation of correlations. In this paper we consider the phenomena of entanglement and "quantumness of correlations", such as quantum discord, with particular emphasis on their energetic consequences for the participating systems. We describe a number of theoretical models that are commonly employed in this context, highlighting the general character of one of their most intriguing results: In contradiction to conventional expectations, erasure (decay, consumption) of quantum correlations may be a source of work, i.e. may have "negative energetic costs". We report experimental evidence of this surprising effect obtained within the framework of an elementary scattering experiment, namely ultrafast neutron Compton scattering from normal-state liquid 4 He. The general theory of quantumness of correlations provides a natural way of interpreting the reported results, which stand in blatant contrast to the conventional theory of scattering, where neutron-atom-environment quantum correlations and decoherence play no role. Moreover, they provide a new operational meaning of discord and related measures of quantumness.

Journal of Physics Conference Series•Oct 10, 2014•2 citations

Quantumness of correlations in nanomaterials—experimental evidence and unconventional effects

C. A. Chatzidimitriou‐Dreismann

Quantum correlations phenomena, such as entanglement, quantum discord and quantum coherence, are ubiquitous effects caused by interactions between physical systems—such as electrons and ions in a piece of metal, or H atoms/molecules adsorbed in nanoporous materials. Here, we address time-asymmetric quantumness of correlations (QoC), with particular emphasis on their energetic consequences for dynamics and non-equilibrium thermodynamics in condensed matter and/or many-body systems. Some known theoretical models—for example, the quantum Zeno effect and GKSL-type Markovian equations-of-motion, all of them being time-asymmetric—are shortly considered, with emphasis on the general character of one of their common and most intriguing result. Namely, that in clear contradistinction to conventional expectations, degradation (or destruction, decoherence, consumption, smearing out, coarse-graining) of quantum correlations can be a source of work (instead of heat production). The experimental relevance of the theoretical considerations is shown with the aid of a recent scattering experiment exploring the impulsively driven (by neutron collisions) translational dynamics of H$ _2 $ molecules in carbon nanotubes and other nanostructured materials—a topic of immediate relevance for material sciences and related technologies.

AIMS Materials Science•Jan 1, 2022•0 citations

Quantum discord and Maxwell’s demons

Wojciech Hubert Zurek

Quantum discord was proposed as an information-theoretic measure of the ``quantumness'' of correlations. I show that discord determines the difference between the efficiency of quantum and classical Maxwell's demons---that is, entities that can or cannot measure nonlocal observables or carry out conditional quantum operations---in extracting work from collections of correlated quantum systems.

arXiv:quant-ph/0202123•Physical Review A•Jan 29, 2003•346 citations

The classical-quantum boundary for correlations: Discord and related measures

Kavan Kishore Modi, Aharon Brodutch, Hugo V. Cable +2 more

One of the best signatures of nonclassicality in a quantum system is the existence of correlations that have no classical counterpart. Different methods for quantifying the quantum and classical parts of correlations are among the more actively studied topics of quantum-information theory over the past decade. Entanglement is the most prominent of these correlations, but in many cases unentangled states exhibit nonclassical behavior too. Thus distinguishing quantum correlations other than entanglement provides a better division between the quantum and classical worlds, especially when considering mixed states. Here different notions of classical and quantum correlations quantified by quantum discord and other related measures are reviewed. In the first half, the mathematical properties of the measures of quantum correlations are reviewed, related to each other, and the classical-quantum division that is common among them is discussed. In the second half, it is shown that the measures identify and quantify the deviation from classicality in various quantum-information-processing tasks, quantum thermodynamics, open-system dynamics, and many-body physics. It is shown that in many cases quantum correlations indicate an advantage of quantum methods over classical ones.

arXiv:1112.6238•Reviews of Modern Physics•Nov 26, 2012•1,599 citations

QUANTUM DISCORD UNDER SYSTEM–ENVIRONMENT COUPLING: THE TWO-QUBIT CASE

Jin‐Shi Xu, Chuan‐Feng Li

Open quantum systems have attracted great attention, since inevitable coupling between quantum systems and their environment greatly affects the features of interest of these systems. Quantum discord, is a measure of the total nonclassical correlation in a quantum system that includes, but is not exclusive to, the distinct property of quantum entanglement. Quantum discord can exist in separated quantum states and plays an important role in many fundamental physics problems and practical quantum information tasks. There have been numerous investigations on quantum discord and its counterpart classical correlation. This short review focuses on highlighting the system–environment dynamics of two-qubit quantum discord and the influence of initial system–environment correlations on the dynamics of open quantum systems. The external control effect on the dynamics of open quantum systems are involved. Several related experimental works are discussed.

arXiv:1205.0871•International Journal of Modern Physics B•Oct 24, 2012•13 citations
Quantum correlations and associated quantum information concepts (e. g. quantum discord, entanglement, quantum Maxwell’s demon) provide novel insights in various quantum-information processing tasks, quantum-thermodynamics processes, open-system dynamics, quantum molecular dynamics, and general many-body physics. We investigate a new effect of correlations accompanying collision of two quantum systems A and B, the latter being part of a larger (interacting) system B+D. In contrast to the usual case of a classical ‘environment’ or ‘demon’ (which can have only classical correlations with A+B during and after the collision), the quantum case exhibits striking new features. Here, in the frame of incoherent inelastic neutron scattering (INS) and vibrational dynamics of molecules, we report experimental evidence of a new phenomenon: quantum deficit of momentum transfer in an elementary neutron-molecule collision, in particular, in INS from single H2O molecules confined in channels with sub-nanometer diameter. The INS findings are in clear contrast to conventional theoretical expectations, but are naturally (albeit qualitative) interpreted in the frame of modern theory of quantumness of correlations, thus also proposing a new operational meaning of quantum discord and related measures.
Nonclassical correlations known as entanglement, quantum discord, quantum deficit, measurement‐induced disturbance, quantum Maxwell's demon, etc., may provide novel insights into quantum‐information processing, quantum‐thermodynamics processes, open‐system dynamics, quantum molecular dynamics, and general quantum chemistry. We study a new effect of quantumness of correlations accompanying collision of two distinguishable quantum systems A and B, the latter being part of a larger (interacting) system B + D. In contrast to the common assumption of a classical environment or “demon” D, the quantum case exhibits striking new qualitative features. Here, in the context of incoherent inelastic neutron scattering from H‐atoms which create molecular excitations (vibration, rotation, translation), we report theoretical and experimental evidence of a new phenomenon: a considerably reduced effective mass of H, or equivalently, an anomalous momentum‐transfer deficit in the neutron‐H collision. These findings contradict conventional theoretical expectations even qualitatively, but find a straightforward interpretation in the new theoretical frame under consideration. © 2015 Wiley Periodicals, Inc.
The interactions between physical systems generally lead to the formation of correlations. In this paper we consider the phenomena of entanglement and "quantumness of correlations", such as quantum discord, with particular emphasis on their energetic consequences for the participating systems. We describe a number of theoretical models that are commonly employed in this context, highlighting the general character of one of their most intriguing results: In contradiction to conventional expectations, erasure (decay, consumption) of quantum correlations may be a source of work, i.e. may have "negative energetic costs". We report experimental evidence of this surprising effect obtained within the framework of an elementary scattering experiment, namely ultrafast neutron Compton scattering from normal-state liquid 4 He. The general theory of quantumness of correlations provides a natural way of interpreting the reported results, which stand in blatant contrast to the conventional theory of scattering, where neutron-atom-environment quantum correlations and decoherence play no role. Moreover, they provide a new operational meaning of discord and related measures of quantumness.
Quantum correlations phenomena, such as entanglement, quantum discord and quantum coherence, are ubiquitous effects caused by interactions between physical systems—such as electrons and ions in a piece of metal, or H atoms/molecules adsorbed in nanoporous materials. Here, we address time-asymmetric quantumness of correlations (QoC), with particular emphasis on their energetic consequences for dynamics and non-equilibrium thermodynamics in condensed matter and/or many-body systems. Some known theoretical models—for example, the quantum Zeno effect and GKSL-type Markovian equations-of-motion, all of them being time-asymmetric—are shortly considered, with emphasis on the general character of one of their common and most intriguing result. Namely, that in clear contradistinction to conventional expectations, degradation (or destruction, decoherence, consumption, smearing out, coarse-graining) of quantum correlations can be a source of work (instead of heat production). The experimental relevance of the theoretical considerations is shown with the aid of a recent scattering experiment exploring the impulsively driven (by neutron collisions) translational dynamics of H$ _2 $ molecules in carbon nanotubes and other nanostructured materials—a topic of immediate relevance for material sciences and related technologies.
One of the best signatures of nonclassicality in a quantum system is the existence of correlations that have no classical counterpart. Different methods for quantifying the quantum and classical parts of correlations are among the more actively studied topics of quantum-information theory over the past decade. Entanglement is the most prominent of these correlations, but in many cases unentangled states exhibit nonclassical behavior too. Thus distinguishing quantum correlations other than entanglement provides a better division between the quantum and classical worlds, especially when considering mixed states. Here different notions of classical and quantum correlations quantified by quantum discord and other related measures are reviewed. In the first half, the mathematical properties of the measures of quantum correlations are reviewed, related to each other, and the classical-quantum division that is common among them is discussed. In the second half, it is shown that the measures identify and quantify the deviation from classicality in various quantum-information-processing tasks, quantum thermodynamics, open-system dynamics, and many-body physics. It is shown that in many cases quantum correlations indicate an advantage of quantum methods over classical ones.
Open quantum systems have attracted great attention, since inevitable coupling between quantum systems and their environment greatly affects the features of interest of these systems. Quantum discord, is a measure of the total nonclassical correlation in a quantum system that includes, but is not exclusive to, the distinct property of quantum entanglement. Quantum discord can exist in separated quantum states and plays an important role in many fundamental physics problems and practical quantum information tasks. There have been numerous investigations on quantum discord and its counterpart classical correlation. This short review focuses on highlighting the system–environment dynamics of two-qubit quantum discord and the influence of initial system–environment correlations on the dynamics of open quantum systems. The external control effect on the dynamics of open quantum systems are involved. Several related experimental works are discussed.