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Quantum mechanics

Vlatko Vedral

Published Sep 28, 2006• 0 citations
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Abstract

Abstract This chapter reviews all the rules of quantum mechanics and their mathematical notation. It also considers quantum entanglement, a fundamental resource in quantum information. There are four basic postulates of quantum mechanics, that indicate how to represent physical systems, how to represent observations, how to carry out measurements, and how systems evolve when “not measured”. Before describing the laws of quantum mechanics, their mathematical background is first described, along with a Mach Zehnder interferometer experiment in which the (strange) readings on the detectors can be explained by quantum mechanics. This chapter also discusses the Dirac notation, qubits, Hilbert spaces, projective measurements and operations, unitary operations, eigenvectors and eigenvalues, spectral decomposition, applications of the spectral theorem, Dirac notation shorthands, and mixed states.

DOI
10.1093/acprof:oso/9780199215706.003.0002

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Abstract This chapter reviews all the rules of quantum mechanics and their mathematical notation. It also considers quantum entanglement, a fundamental resource in quantum information. There are four basic postulates of quantum mechanics, that indicate how to represent physical systems, how to represent observations, how to carry out measurements, and how systems evolve when “not measured”. Before describing the laws of quantum mechanics, their mathematical background is first described, along with a Mach Zehnder interferometer experiment in which the (strange) readings on the detectors can be explained by quantum mechanics. This chapter also discusses the Dirac notation, qubits, Hilbert spaces, projective measurements and operations, unitary operations, eigenvectors and eigenvalues, spectral decomposition, applications of the spectral theorem, Dirac notation shorthands, and mixed states.
We review the postulates of quantum mechanics with respect to the representation of physical states and measurable quantities, their time evolution, and the interpretation of measurements. We first formulate the postulates in terms of wave functions and differential operators, and then reformulate them in the abstract Hilbert space of state vectors, using Dirac’s notations. Improper states subject to Dirac’s delta normalization are introduced, and the space of physical states is extended to include them. The postulates are rationalized by associating each Hermitian linear operator with a complete orthonormal system of its eigenvectors, where measurement probabilities depend on the projections of these eigenvectors on the system’s state vector. Particularly, wave functions are identified as projections of state vectors on the position operator eigenstates. State vectors representing multidimensional systems are formulated as tensor products of vectors in their subspaces. Finally, we address the general uncertainty relations in simultaneous measurements of different observables.
The authors present briefly the basic notions of the quantum formalism: pure and mixed states; quantum observables; quantum probability; Born’s rule, superposition, and ‘state collapse’; the projection postulate (von Neumann–Lüders postulate); Dirac’s ket and bra-vector notations; elements of quantum information theory and quantum logic; Schrödinger’s and von Neumann’s equations; unitary dynamics; and positive operator valued measures. They also define the basic mathematical notions related to the quantum formalism: Hilbert space; scalar product; norm; Hermitian operator (matrix); projector; and unitary operator and adjoint operator. This chapter may be useful for newcomers to the field, but for those readers who have preliminary knowledge about quantum mechanics (QM) they can proceed directly to advanced chapters. These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This chapter contains a brief introduction to mathematical formalism and QM axiomatics. It is oriented to non-physicists. Since QM is a statistical theory it is natural to start with the classical probability model (Kolmogorov [ 191 ], 1933). Then we present the basics of the theory of Hilbert spaces and Hermitian operators and the representation of pure and mixed states by normalized vectors and density operators. This introduction is sufficient to formulate the axiomatics of QM in the form of five postulates. The projection postulate (the most questionable postulate of QM) is presented in a separate section. We sharply distinguish between the cases of quantum observables represented by Hermitian operators with nondegenerate and degenerate spectra, von Neumann’s and Ltiders’s forms of the projection postulate. The axiomatics is completed by a short section on the main interpretations of QM. The projection postulate (LUders’s form) plays a crucial role in the definition of quantum conditional (transition) probability. By operating with the latter we consider interference of probabilities for two incompatible observables as a modification of the formula of total probability by adding the interference term. This viewpoint to interference of probabilities was elaborated in a series of works by Khrennikov. Since classical probability theory is based on the 142 Boolean algebra of events, a violation of the law of total probability can be treated as the probabilistic sign of a violation of the laws of the Boolean logics. From this viewpoint, quantum theory can be considered as representing a new kind of logic, so-called quantum logic. The latter is also briefly presented in a separate section. We continue this review with a new portion of quantum mathematics, namely the notion of the tensor product of Hilbert spaces and the tensor product of operators. After the section on Dirac’s notation with ket and bra vector, we discuss briefly the notion of qubit and entanglement of a few qubits. This chapter concludes with a presentation of the detailed analysis of the probabilistic structure of the two-slit experiment in a bunch of different experimental contexts. This contextual structure leads to a violation of the law of total probability and non-Kolmogorovean probabilistic structure of this experiment.
Abstract Quantum mechanics is a more accurate description of the microscopic world than classical mechanics, and quantum information, which is governed by the laws of quantum mechanics, is a more accurate description of information theory. The quantum laws of physics are fundamentally different from the classical laws and so, therefore, is the resulting information processing. In one limit, quantum information reduces to classical information; otherwise, quantum information is a much more general concept that allows information-processing protocols that have no classical analogue whatsoever. This chapter discusses the basics of quantum information, some differences between bits and qubits, quantum cryptography, trace and partial-trace operations, extension of Hilbert spaces, Schmidt decomposition, generalised measurements, CP-maps and positive operator-valued measurements, and the postulates of quantum mechanics.
This chapter reminds, without entering into details, the main mathematical concepts and results relevant for finite system quantum mechanics. The basic postulates single out a Hilbert space of wave functions with self-adjoint linear operators corresponding to observables as was originally discovered by von Neumann. The chapter connects the contemporary terminology of linear Hilbert space operators with quantum physics. Important concepts like linear operators, measures, self-adjointness, spectral measures, density matrices, and tensor products are discussed and illustrated in the light of observables, probability for quantum systems and composite systems. A first example of a useful algebra of observables, the Weyl algebra, is described in detail and linked to the classical phase space of a point particle.
We summarize below some of the postulates and definitions basic to our formalism, and present some important results based on these postulates. The formalism is purely mathematical in nature with very little physics input, but it provides the structure within which the physical concepts that will be discussed in the later chapters will be framed. State vectors It is important to realize that the Quantum Theory is a linear theory in which the physical state of a system is described by a vector in a complex, linear vector space. This vector may represent a free particle or a particle bound in an atom or a particle interacting with other particles or with external fields. It is much like a vector in ordinary three-dimensional space, following many of the same rules, except that it describes a very complicated physical system. We will be elaborating further on this in the following. The mathematical structure of a quantum mechanical system will be presented in terms of the notations developed by Dirac. A physical state in this notation is described by a “ket” vector, |〉, designated variously as |α〉 or |ψ〉 or a ket with other appropriate symbols depending on the specific problem at hand. The kets can be complex. Their complex conjugates, |〉 * , are designated by 〈| which are called “bra” vectors. Thus, corresponding to every ket vector there is a bra vector. These vectors are abstract quantities whose physical interpretation is derived through their so-called “representatives” in the coordinate or momentum space or in a space appropriate to the problem under consideration.