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Oxford University Press eBooks

Basic Tools For Quantum Mechanics

Robert Alicki, M. Fannes

Published Jul 12, 2001• 0 citations
Publisher

Abstract

This chapter reminds, without entering into details, the main mathematical concepts and results relevant for finite system quantum mechanics. The basic postulates single out a Hilbert space of wave functions with self-adjoint linear operators corresponding to observables as was originally discovered by von Neumann. The chapter connects the contemporary terminology of linear Hilbert space operators with quantum physics. Important concepts like linear operators, measures, self-adjointness, spectral measures, density matrices, and tensor products are discussed and illustrated in the light of observables, probability for quantum systems and composite systems. A first example of a useful algebra of observables, the Weyl algebra, is described in detail and linked to the classical phase space of a point particle.

DOI
10.1093/acprof:oso/9780198504009.003.0002

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This chapter reminds, without entering into details, the main mathematical concepts and results relevant for finite system quantum mechanics. The basic postulates single out a Hilbert space of wave functions with self-adjoint linear operators corresponding to observables as was originally discovered by von Neumann. The chapter connects the contemporary terminology of linear Hilbert space operators with quantum physics. Important concepts like linear operators, measures, self-adjointness, spectral measures, density matrices, and tensor products are discussed and illustrated in the light of observables, probability for quantum systems and composite systems. A first example of a useful algebra of observables, the Weyl algebra, is described in detail and linked to the classical phase space of a point particle.
Abstract In this chapter we present the mathematical framework of describing wave functions as vectors in a Hilbert space and observables as Hermitian operators on such a vector space. We describe the mathematical formulation of these ideas for finite and infinite-dimensional cases via the Dirac notation, and discuss the example of the Hilbert space of photon polarization. Important classes of linear operators on Hilbert spaces are discussed, including projectors, Hermitian and self-adjoint operators, as well as unitary operators. As an important centre piece for the mathematical language of quantum mechanics we present the spectral theorem. We discuss the subtleties of this framework in infinite dimensions, giving a brief overview of the distributional aspects of quantum mechanics and the conceptually important problem of finding self-adjoint extensions via the Weyl-von Neumann theorem
Linear algebra is the natural mathematical language of quantum mechanics. For this reason, the present chapter starts with a review of Hilbert spaces for vectors and operators. We introduce vector and Hilbert spaces along with inner products and metrics. The Dirac notation is developed for the Euclidean vector spaces as a starting point for the concepts of complete orthonormal sets of vectors, closure, dual vector spaces, and adjoint operators. The Dirac delta function in various forms and the principal part is introduced in Appendix 5 as an essential tool. The chapter turns to the main use of Dirac notation for function spaces; the concepts of norm, inner product, and closure are discussed. Fourier, Cosine, and Sine series are discussed as examples of expansions in complete orthonormal sets of functions. Although Hilbert spaces are interesting mathematical objects with important physical applications, the study of linear algebra remains incomplete without a study of linear operators (i.e., linear transformations). In fact, the set of linear transformations itself forms a vector space and therefore has a basis set. The basis set for the operator is linked with the basis sets for the spaces that it operates between. The linear operator can be discussed as an abstract operator or through an isomorphism as a matrix or as a generalized expansion in operator space. A Hermitian (a.k.a., self-adjoint) operator produces a basis set within a Hilbert space. The basis set comes from the eigenvector equation for the particular operator. The fact that a Hermitian operator produces a complete set (of orthornomal vectors) has special importance for quantum mechanics. Observables such as energy or momentum correspond to Hermitian operators. Complete sets make it possible to represent every possible result of a measurement of the observable by an object (vector) in the theory. The Hermitian operators have real eigenvalues which represent the results of the measurement.
In this chapter the basic concepts of quantum theory are formulated via a self-consistent set of six postulates. These six postulates deal with the following: operator images of physical observables; properties of state vectors and wave functions; the connection with experimental measurements; coordinate-space forms of those operators having classical analogs; the primary dynamical equation of quantum mechanics; and the completeness of the eigenvectors of observables. The postulates are the framework on which the edifice of quantum mechanics is constructed. A separate section is devoted to the statement of each postulate and to a few examples chosen to illustrate or apply it. A comprehensive set of applications is presented in Chapters 6 and 7, where various 1-D systems are used as the vehicles for illustrating the postulates. The basic theory of this chapter is extended and developed in Chapters 8 and 9. Since probability is a key interpretational concept, a brief introduction to this topic is given in an appendix. We emphasize that our formulation of quantum theory (in this chapter and throughout this book) is restricted to the case of pure states. This is not a major restriction. It means that, when we consider ensembles of individual quantum systems (e.g., single particles, atoms, nuclei, etc.), all of the systems in the ensemble are assumed to be in the same quantum state, not necessarily an eigenstate of a quantal operator. Ensembles for which this assumption does not hold are described by a density operator or density matrix rather than by a pure state; treatments of such cases can be found in references cited later.
The authors present briefly the basic notions of the quantum formalism: pure and mixed states; quantum observables; quantum probability; Born’s rule, superposition, and ‘state collapse’; the projection postulate (von Neumann–Lüders postulate); Dirac’s ket and bra-vector notations; elements of quantum information theory and quantum logic; Schrödinger’s and von Neumann’s equations; unitary dynamics; and positive operator valued measures. They also define the basic mathematical notions related to the quantum formalism: Hilbert space; scalar product; norm; Hermitian operator (matrix); projector; and unitary operator and adjoint operator. This chapter may be useful for newcomers to the field, but for those readers who have preliminary knowledge about quantum mechanics (QM) they can proceed directly to advanced chapters. These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
In this chapter, we present the basic principles of the quantum mechanics of particle systems from a modern mathematical perspective. The proper study of quantum mechanics brings together several interesting mathematical ideas, ranging from group representations to the spectral theory of unbounded self-adjoint operators in Hilbert spaces and the theory of C * algebras. The facts from analysis of operators in Hilbert spaces and C * algebras needed in this chapter are presented in detail in the appendices at the end of the book. More on the mathematical foundations of quantum mechanics can be found in the books by L. Fadeev and O. Yakubovskii [FY], G. Mackey [M], and F. Strocchi [Str] listed in the bibliography. The birth of quantum theory The origins of quantum theory can be traced back to M. Planck's study, published in 1900, of so-called black-body radiation. It is well known that matter glows when heated, going from red-hot to white-hot as the temperature rises. The color (or frequency of radiation) of the radiating body is independent of its surface, and for a black body it is found to be a function of temperature alone. The behavior of the radiation energy as a function of temperature seemed quite different at high temperatures and low temperatures. In a desperate attempt to fit these different behaviors into a single law, Planck introduced the hypothesis that energy was not continuous, but came in discrete packets or quanta . At the beginning of the twentieth century, a number of experiments pointed to a breakdown of the laws of classical mechanics at very small (subatomic) scales.
This chapter provides a simple general introduction to some basic mathematics necessary for a subsequent discussion of Lie algebras, operator methods, and their applications to theoretical physics and chemistry. It also provides some useful mathematical tools to derive important theoretical results and expressions in a simple and elegant way. In quantum mechanics the state of a system is represented by an element of a particular vector space, in which one defines an appropriate scalar or inner product, known in mathematics as Hilbert space. Hermitian operators with a complete set of eigenvectors belonging to that state space represent physical observables. Moreover, in certain cases it proves useful to work with vector spaces formed by linear operators. Hermitian operators are particular cases of linear operators and physical observables are particular cases of Hermitian operators. In many physical applications of operator methods one needs to reorder products of exponential operators or to rewrite one such operator as a product of simpler ones.