Abstract This chapter develops the fundamental notions and concepts of the probabilistic and statistical interpretation of quantum mechanics. It begins with a brief review of the mathematical structure given by a Hilbert space of state vectors and an algebra of observables represented by selfadjoint operators. Special emphasis is laid on the connection between the spectral representation of a selfadjoint operator and a corresponding random variable that describes the possible measurement outcomes. The chapter further introduces the concepts of a composite quantum system, of the reduced density matrix, and of entangled quantum states. A section on quantum entropies is included, as well as the mathematical formulation of the generalized theory of quantum measurements in terms of completely positive quantum operations and effects.
Abstract This chapter develops the fundamental notions and concepts of the probabilistic and statistical interpretation of quantum mechanics. It begins with a brief review of the mathematical structure given by a Hilbert space of state vectors and an algebra of observables represented by selfadjoint operators. Special emphasis is laid on the connection between the spectral representation of a selfadjoint operator and a corresponding random variable that describes the possible measurement outcomes. The chapter further introduces the concepts of a composite quantum system, of the reduced density matrix, and of entangled quantum states. A section on quantum entropies is included, as well as the mathematical formulation of the generalized theory of quantum measurements in terms of completely positive quantum operations and effects.
This chapter contains a brief introduction to mathematical formalism and QM axiomatics. It is oriented to non-physicists. Since QM is a statistical theory it is natural to start with the classical probability model (Kolmogorov [ 191 ], 1933). Then we present the basics of the theory of Hilbert spaces and Hermitian operators and the representation of pure and mixed states by normalized vectors and density operators. This introduction is sufficient to formulate the axiomatics of QM in the form of five postulates. The projection postulate (the most questionable postulate of QM) is presented in a separate section. We sharply distinguish between the cases of quantum observables represented by Hermitian operators with nondegenerate and degenerate spectra, von Neumann’s and Ltiders’s forms of the projection postulate. The axiomatics is completed by a short section on the main interpretations of QM. The projection postulate (LUders’s form) plays a crucial role in the definition of quantum conditional (transition) probability. By operating with the latter we consider interference of probabilities for two incompatible observables as a modification of the formula of total probability by adding the interference term. This viewpoint to interference of probabilities was elaborated in a series of works by Khrennikov. Since classical probability theory is based on the 142 Boolean algebra of events, a violation of the law of total probability can be treated as the probabilistic sign of a violation of the laws of the Boolean logics. From this viewpoint, quantum theory can be considered as representing a new kind of logic, so-called quantum logic. The latter is also briefly presented in a separate section. We continue this review with a new portion of quantum mathematics, namely the notion of the tensor product of Hilbert spaces and the tensor product of operators. After the section on Dirac’s notation with ket and bra vector, we discuss briefly the notion of qubit and entanglement of a few qubits. This chapter concludes with a presentation of the detailed analysis of the probabilistic structure of the two-slit experiment in a bunch of different experimental contexts. This contextual structure leads to a violation of the law of total probability and non-Kolmogorovean probabilistic structure of this experiment.
Abstract Chapter 9 begins laying a foundation for quantum statistical mechanics with a discussion of relevant topics in quantum mechanics. The fundamental postulates of quantum mechanics are reviewed, beginning with the definition of a quantum state and the introduction of the concept of a state vector in a Hilbert space. The representation of observables as Hermitian operators on Hilbert space vectors is described; it is shown that the eigenvalues of Hermitian operators are real and, therefore, constitute possible outcomes of measurements made on these observables. The notions compatible and non-compatible observables and implication for the measurement problem are presented. The time-dependent Schrödinger equation is introduced as generating the time-evolution of the state vector, and it is shown how to cast the Schrödinger equation into a coordinate basis to yield the wave equation of quantum mechanics. Coordinate and momentum bases and their properties are desribed. Several analytically solvable quantum systems are presented as illustrative examples. The chapter concludes with a discussion of spin and the treatment identical particles
Abstract This book treats the central physical concepts and mathematical techniques used to investigate the dynamics of open quantum systems. To provide a self-contained presentation, the text begins with a survey of classical probability theory and with an introduction to the foundations of quantum mechanics, with particular emphasis on its statistical interpretation and on the formulation of generalized measurement theory through quantum operations and effects. The fundamentals of density matrix theory, quantum Markov processes, and completely positive dynamical semigroups are developed. The most important master equations used in quantum optics and condensed matter theory are derived and applied to the study of many examples. Special attention is paid to the Markovian and non-Markovian theory of environment induced decoherence, its role in the dynamical description of the measurement process, and to the experimental observation of decohering electromagnetic field states. The book includes the modern formulation of open quantum systems in terms of stochastic processes in Hilbert space. Stochastic wave function methods and Monte Carlo algorithms are designed and applied to important examples from quantum optics and atomic physics. The fundamentals of the treatment of non-Markovian quantum processes in open systems are developed on the basis of various mathematical techniques, such as projection superoperator methods and influence functional techniques. In addition, the book expounds the relativistic theory of quantum measurements and the density matrix theory of relativistic quantum electrodynamics.
From the outset statistical mechanics will be framed in the language of quantum theory. The typical macroscopic system is composed of multiple constituents, and hence described in some many-particle Hilbert space. In general, not much is known about such a system, certainly not the precise preparation of all its microscopic details. Thus, its description requires a more general notion of a quantum state, a so-called mixed state. This chapter begins with a brief review of the basic axioms of quantum theory regarding observables, pure states, measurements, and time evolution. Particular attention is paid to the use of projection operators and to the most elementary quantum system, a two-level system. The chapter then motivates the introduction of mixed states and examines in detail their mathematical representation and properties. It also dwells on the description of composite systems, introducing, in particular, the notions of statistical independence and correlations.
This chapter introduces the mathematical framework, basic rules, and some key results of quantum theory. After a succinct overview of linear algebra and an introduction to complex Hilbert space, it investigates the correspondence between subspaces of Hilbert space and propositions, their logical structure, and how the pertinent probabilities are calculated. It discusses the mathematical representation of states, observables, and transformations, as well as the rules for calculating expectation values and uncertainties, and for updating states after a measurement. Particular attention is paid to two-level systems, or ‘qubits’, and the connection is made with experimental evidence about binary measurements. The properties of composite systems are discussed in detail, notably the phenomenon of entanglement. The chapter concludes with an investigation of conceptual issues regarding realism, non-contextuality, and locality, as well as the classical limit.
In this chapter, we consider the way quantum theory represents deterministic, statistical, and probabilistic aspects of Nature. After a discussion in Section 3.1 of uncertainty in general, we discuss in Sections 3.2-3.4 several formal notions of classical probability, their relation to the probability concept used in applied statistics, and their dependence on the description used. Section 3.5 briefly discusses various examples, where probabilistic features emerge from fully deterministic situations-a theme to be taken up in much more detail in Chapter 11. Section 3.6 then shows how the statistical aspects of the quantum formalism naturally follow from the weak law of large numbers. The notions of c-probability in the classical case and of q-probability in the quantum case are formally defined in Section 3.7. Historically, the concept of classical probability (including its use in stochastic processes) was given an undisputed formal mathematical foundation in 1933 in terms of the measure-theoretic setting of Kolmogorov [164]. Apart from this traditional axiomatic foundation of classical probability theory, there is a less well-known equivalent axiomatic treatment by Whittle [302] in terms of expectations. Here probabilities appear as the expectations of statements, {0, 1}-valued random variables. von Plato [240] discusses the history of the concept of probability. Krüger et al. [169] discuss the history of probability in the various fields of application. Sklar [275] discusses the philosophical problems of the probability concept, with an emphasis on statistical mechanics.