Newton thought that light was made up of particles, but then it was discovered, as we have seen here, that it behaves like a wave. Later, however (in the beginning of the twentieth century) it was found that light did indeed sometimes behave like a particle. Historically, the electron, for example, was thought to behave like a particle, and then it was found that in many respects it behaved like a wave. So it really behaves like neither. Now we have given up. We say: “it is like neither.” ere is one lucky break, however-electrons behave like light. e quantum behaviour of atomic objects (electrons, protons, neutron, photons, and so on) is the same for all, they are all ‘particle waves’ or whatever you want to call them.
Newton thought that light was made up of particles, but then it was discovered, as we have seen here, that it behaves like a wave. Later, however (in the beginning of the twentieth century) it was found that light did indeed sometimes behave like a particle. Historically, the electron, for example, was thought to behave like a particle, and then it was found that in many respects it behaved like a wave. So it really behaves like neither. Now we have given up. We say: “it is like neither.” ere is one lucky break, however-electrons behave like light. e quantum behaviour of atomic objects (electrons, protons, neutron, photons, and so on) is the same for all, they are all ‘particle waves’ or whatever you want to call them.
Newton thought that light was made up of particles, but then it was discovered that it behaves like a wave. Later, however it was found that light did indeed sometimes behave like a particle. Historically, the electron, for example, was thought to behave like a particle, and then it was found that in many respects it behaved like a wave. At our current levels of experimental sensitivity, there is no evidence for any constituent objects within electrons, hence they are regarded as fundamental particles. They have an electrical charge which is negative and a very tiny mass. While thinking about experiments involving beams of atoms and magnetic fields, Otto Stern realized that passing a beam of specially selected atoms through a nonuniform external magnetic field would apply a force to the atomic magnets.
At the atomic scale, the distinction between particles and waves breaks down. The realization, early in the twentieth century, that light consists of discrete packages, or “photons,” prompted the converse suggestion that particles could behave like waves. Confirmation of this idea came in 1927, from an experiment involving the scattering of electrons from a crystal. Today, “wave-particle duality” is central to quantum mechanics, and the wave properties of subatomic particles are widely used in microscopy and crystallography. Electron diffraction techniques are widely used to characterize atomic arrangements on solid surfaces and inside thin films, and to investigate the structures of molecules in gases. The dual nature of waves and particles is part of the “spookiness” of quantum mechanics, which cannot be explained in any classical way. It used to be that one could only imagine an experiment that would simultaneously demonstrate the particle and wave nature of electrons.
The question ‘is light a ray, a wave or a particle?’ has long fascinated philosophers and has intensified since the concept of the photon first emerged at the beginning of the twentieth century. The pragmatic answer to the question is ‘it depends what you are looking for’ and is really about how best to conceptualise light in particular circumstances. We have already mentioned such distinctions briefly in Chapter 1. This chapter will extend these basic concepts to introduce the material which follows in later chapters.
Have you ever tried to define light? If so, your definition is probably related to vision, the ability to see things. The Merriam-Webster English dictionary defines light as “something that makes vision possible”. However, the definition of the “nature of light” is a complex term already discussed by philosophers of Ancient Greece. In the 17th century, the debate on the matter focused on whether light was a particle or a wave, based on the different properties of light that had been gradually discovered over time. Isaac Newton (1642−1727) was a defender of the corpuscular theory of light, which considered light to be formed by particles, i.e., small pieces of matter, like dust or grains of sand. He was the author of Opticks (1706), the front cover of which appears in Fig. 1.1. Christian Huygens (1629–1695), on the other hand, supported the theory that light is a wave. These are two completely different definitions of the same physical concept. A range of experiments were developed to attempt to clarify this dilemma, but it was only until 1900 when Max Planck (1858-1947) introduced the basis of a theory that would go on to revolutionize scientific thinking, marking the beginning of modern physics: quantum theory. Developed during the 20th century thanks to advances made by scientists such as Niels Bohr, Born, Heisenberg, Schrödinger, Pauli, Dirac, Einstein or de Broglie, quantum theory clarified that light is neither a particle nor a wave, but that it has a dual nature: it behaves like a wave as it spreads but like a particle in its interactions with matter. In this book, we will specify where necessary whether light behaves as a particle or as a wave, although in most cases we refer to rays of light, which always represent the direction of propagation of light.
Large-scale objects, such as trees, bushes, and cricket balls, are made up of small-scale things such as protons, neutrons, and electrons. The laws of physics that describe the large-scale world have been broadly understood since the 1700s. In 1665 Isaac Newton made some fundamental discoveries about light while taking leave from his studies at Cambridge, which was under threat from the plague. In one of his classic experiments, he allowed a thin shaft of sunlight to fall on a glass prism, producing a spectrum of colours. In twentieth century, the study of light was revolutionized by the ability to produce precisely controlled beams that are tightly collimated and made of light that is all the same colour: laser beams. A key aspect to the next series of experiments is the use of beam splitters. The mathematical machinery of quantum theory describes the photon leaving the mirror as being in a combination of two distinct sates, one for travelling each path.
[M]odern physics has definitely decided in favor of Plato. In fact the smallest units of matter are not physical objects in the ordinary sense; they are forms, ideas which can be expressed unambiguously only in mathematical language. Werner Heisenberg Basic framework Prerequisites: Appendix C, §1B(ii). Near the beginning of the twentieth century, physicists realized that electromagnetic waves sometimes exhibited particle-like properties, as if light were composed of discrete ‘photons’. In 1923, Louis de Broglie proposed that, conversely, particles of matter might have wave-like properties. This was confirmed in 1927 by C. J. Davisson and L. H. Germer and, independently, by G. P. Thompson, who showed that an electron beam exhibited an unmistakable diffraction pattern when scattered off a metal plate, as if the beam were composed of ‘electron waves’. Systems with many interacting particles exhibit even more curious phenomena. Quantum mechanics is a theory which explains these phenomena. We will not attempt here to provide a physical justification for quantum mechanics. Historically, quantum theory developed through a combination of vaguely implausible physical analogies and wild guesses motivated by inexplicable empirical phenomena. By now, these analogies and guesses have been overwhelmingly vindicated by experimental evidence. The best justification for quantum mechanics is that it ‘works’, by which we mean that its theoretical predictions match all available empirical data with astonishing accuracy.