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CRC Press eBooks

Quantum Wonderland

Hasan S. Padamsee

Published Feb 7, 2020• 0 citations
Publisher

Abstract

At the turn of the 20th century, Max Planck and Albert Einstein introduced the quantum theory which revolutionized our understanding of the nature of energy, in particular the nature of light energy. According to Planck, energy is absorbed or emitted from hot objects in tiny discrete bundles called quanta, and each quantum carries a precise quantity of energy which is related to the frequency of light wave. Einstein generalized Planck’s quantum theory. Einstein’s quantum theory removed a grating asymmetry in nature, between energy and matter. Louis DeBroglie said proposed that if light waves behave as particles, electrons, normally thought of as particles, ought to reciprocally behave as waves. DeBroglie provided a crucial missing piece in the quantum puzzle of discrete Bohr orbitals. Erwin Schroedinger seized DeBroglie’s brain wave. He developed a “wave mechanics” to describe the quantum world. For Schroedinger, particles are just an “illusion” of many waves; he turned waves into particles.

DOI
10.1201/9780429424410-12

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At the turn of the 20th century, Max Planck and Albert Einstein introduced the quantum theory which revolutionized our understanding of the nature of energy, in particular the nature of light energy. According to Planck, energy is absorbed or emitted from hot objects in tiny discrete bundles called quanta, and each quantum carries a precise quantity of energy which is related to the frequency of light wave. Einstein generalized Planck’s quantum theory. Einstein’s quantum theory removed a grating asymmetry in nature, between energy and matter. Louis DeBroglie said proposed that if light waves behave as particles, electrons, normally thought of as particles, ought to reciprocally behave as waves. DeBroglie provided a crucial missing piece in the quantum puzzle of discrete Bohr orbitals. Erwin Schroedinger seized DeBroglie’s brain wave. He developed a “wave mechanics” to describe the quantum world. For Schroedinger, particles are just an “illusion” of many waves; he turned waves into particles.
At the beginning of the twentieth century, it became clear that microscopic particles do not obey Newton's laws of classical mechanics. The idea of light quanta was at odds with the established wisdom that light is a wave phenomenon, of course, but no other explanation of the photoelectric effect seemed possible. The next step in the development of quantum mechanics was taken by Niels Bohr, who introduced postulates about the discreteness of the energy of the bound electrons in an atom similar to the discreteness of the energy of light quanta. Modern quantum mechanics was founded by Werner Heisenberg, Max Born, Erwin Schroedinger, Paul Adrian Maurice Dirac, Wolfgang Pauli, Enrico Fermi, and others. In quantum mechanics, it is in general fundamentally impossible to determine the exact outcome of an experiment; one can only determine the probability of any given outcome.
Toward the end of the nineteenth century, it became clear that some experiments cannot be explained on the basis of known physics, now referred to as classical physics. In 1900, Max Planck was able to correctly describe the distribution of blackbody radiation energy as a function of wavelength λ or frequency ν = c/λ. He had to accept the existence of energy packets (quanta) with energy E = hν. A few years later, Albert Einstein found that this unexpected relation between energy and frequency is also necessary in order to understand photoemission from metallic surfaces. A decade later, Niels Bohr arrived at the correct equation for the electronic spectrum of the hydrogen atom by applying “quantum conditions” on the motion of the electron around the nucleus and the Planck’s relation E = hν on the energy difference between the energy levels (1916). A decade later, Heisenberg, Born, and Jordan introduced “quantum mechanics” and de Broglie and Schrödinger (1925-1926) introduced “wave mechanics.”
The beginning of the 20th century is marked by tremendous new scientific developments and specifically by the birth of quantum mechanics. It starts with Max Planck and Max Einstein, who introduce and apply the concept of quanta to characterize the energy of light. Quantum computers can considerably decrease the time it takes to complete calculations and solve extremely complex problems. Until the 18th century, very little is understood about light. According to the philosophers Euclid and Plato, light is produced by our eyes. Light is clearly capable of traveling through an interstellar void, while a wave needs a medium for material propagation to exist. However, because of Isaac Newton’s reputation, the corpuscular theory persists until the 19th century. When light is beamed on the top layer, it frees and pushes an electron that moves towards the bottom layer, creating a current. This current is then used to power engines for electric cars.
Quantum mechanics began in very early twentieth century when Max Planck found the expression for black body thermal radiation in which the emitted light was not a continuum as postulated by classical physics. Erwin Schrodinger applied his equation to solve the quantum harmonic oscillator, the quantum rigid rotor, and a hydrogen-like atom. Pertaining to the solution of the Schrodinger equation to hydrogen atoms are the quantum numbers. C. K. Ingold’s overview of Schrodinger wave mechanics: “What can be known about an electron, considered as a particle, is of a statistical nature, and is summarized in the behavior of a wave. When considering singlet substances, the normal Zeeman Effect occurs, providing the discrete values of the orbital angular momentum. In an attempt to rationalize the anomalous Zeeman effect, W. Pauli proposed the fourth degree of freedom of the electron which he called “two-valuedness not describable classically”.
The quantum revolution in physics of the 20th century has completely transformed the nature not only of physics and science in general, but also of philosophy and our worldview. Quantum revolution began in the early 19th century with the discovery of ‘quantum’ (plural ‘quanta’) principally by Max Planck, and with theories and discoveries in the field of relativity, linked inseparably with the name of Albert Einstein. Max Planck came across the quanta when he was studying what is known as the ‘blackbody radiation’. In classical physics in particular and the classical world in general, there was no serious problems with objects, objectivity and ontology. In classical physics, particles and fields have an existence independent of the observer. In broader view, everything, the world, exists independent of the observer and of the consciousness. The first quantum-mechanical theories on electron in mid-1920s did not take into account the effect of velocity of light, and were therefore non-relativistic.
Einstein’s 1905 paper on the photoelectric effect, in which he considered Planck’s idea of quanta of energy to be a universal characteristic of light, marks the beginning of quantum theory. Electrons and other quantum particles behave like particles and like waves, depending on the particular observation. An electron occupies a position in space only when an observation is made. Heisenberg decided that the problem of the actual orbits of the electrons inside the atom should be ignored; they have no meaning. Schrodinger reasoned that if an electron has a wave-like behavior, then it should be possible to describe this behavior in space and time by a wave equation. Soon after it was discovered that high-speed electrons had wavelengths that were much shorter than the wavelengths of light, physicists showed that magnetic fields could act as lenses by causing electron waves to converge to a focus.