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Institute of Physics eBooks

Introduction

Konstantin K Likharev

Published May 1, 2019• 0 citations
Publisher

Abstract

This introductory chapter briefly reviews the major experimental motivations for quantum mechanics, and then discusses its simplest formalism—the Schrödinger’s wave mechanics. Much of this material (perhaps besides the last section) may be found in undergraduate textbooks, so that the discussion is rather brief, and focused on the most important conceptual issues.

DOI
10.1088/2053-2563/aaf3a3ch1

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This introductory chapter briefly reviews the major experimental motivations for quantum mechanics, and then discusses its simplest formalism—the Schrödinger’s wave mechanics. Much of this material (perhaps besides the last section) may be found in undergraduate textbooks, so that the discussion is rather brief, and focused on the most important conceptual issues.
Our modern understanding of atoms, molecules, solids, atomic nuclei, and elementary particles is largely based on quantum mechanics. Quantum mechanics grew in the mid-1920s out of two independent developments: the matrix mechanics of Werner and the wave mechanics of Erwin Schrödinger. For the most part this chapter follows the path of wave mechanics, which is more convenient for all but the simplest calculations. The general principles of the wave mechanical formulation of quantum mechanics are laid out and provide a basis for the discussion of spin, identical particles. and scattering processes. The general principles are supplemented with the canonical formalism to work out the Schrödinger equation for charged particles in a general electromagnetic field. The chapter ends with the unification of the approaches of wave and matrix mechanics by Paul Dirac, and a modern approach, known as Hilbert space, is briefly described.
This book presents the basic concepts and methods of quantum mechanics for upper level undergraduate students, allowing them to master its application to real physical situations. A postulate-based treatment is adopted together with a gradual development of the quantum formalism of wave functions, operators, measurement and temporal evolution. Standard topics of one-dimensional and atomic motion, angular momentum and approximation methods are presented in addition to detailed discussions of many-particle systems, atomic and nuclear radiation. Appropriate mathematical tools and techniques are provided wherever necessary. The core text is supplemented by 77 worked examples, some of which address more complex issues and aspects of present-day research. The aim is to make this textbook a realistic introduction to more advanced and specialized texts. The material provides full coverage of the subject matter, 94 problems with solutions and a further 93 with answers only
Although there are many textbooks that deal with the formal apparatus of quantum mechanics (QM) and its application to standard problems, none take into account the developments in the foundations of the subject which have taken place in the last few decades. There are specialized treatises on various aspects of the foundations of QM, but none that integrate those topics with the standard material. This book aims to remove that unfortunate dichotomy, which has divorced the practical aspects of the subject from the interpretation and broader implications of the theory.The book is intended primarily as a graduate level textbook, but it will also be of interest to physicists and philosophers who study the foundations of QM. Parts of it could be used by senior undergraduates too.
Based on years of teaching experience, this book provides a clearly structured and accessible introduction to the fundamental principles of quantum mechanics, tailored for undergraduate students. The text builds a strong conceptual and mathematical foundation while promoting intuitive understanding and critical thinking. Students progress from basic concepts such as wave mechanics to more advanced topics within matrix mechanics. Complex concepts are presented in a diligent and understandable way, achieving a balance between conceptual insight and mathematical rigor without oversimplifying the subject. Thoroughly class-tested, this book is designed to support both classroom instruction and independent study. It will serve as a great tool for undergraduates studying introductory and intermediate quantum mechanics, as well as modern physics and quantum systems for engineers.
The introductory basics of quantum mechanics were said to arise from the changes from classical mechanics in the first chapter. In some sense, these changes are brought to an observable level by the smallness of some parameter, such as the size scale. In another sense, however, quantum mechanics introduces some fundamental changes, that are not at all present in classical mechanics. Perhaps the most important effect is the appearance of operators in place of dynamical variables and the non-commuting nature of these operators. While these properties are present in normal mathematics, they are not usually associated with discussions of classical mechanics.
In most textbooks, measurement does not receive the full attention it deserves and sometimes is even not treated at all, apart a brief and cryptic mention of the “reduction of the wave packet.” However, in the last decades, the situation has profoundly changed and it is time to consider measurement a fundamental part of quantum mechanics, even, to a certain extent, an important generalization of the traditional theory (see also Chs. 14–15). This chapter consists of three major parts. In the first block (Secs. 9.1–9.4) we develop the main physical features of the measurement process: the heart of the argument is here represented by the aspects related to the interpretation. In the second part (Secs. 9.5–9.8) we discuss several special (and partly interdependent) topics of measurement: the heart here is represented by experimental aspects. In the third part (Secs. 9.9–9.12) we deal with the measurement process on a more formal plane, making use, in particular, of the generalization represented by the concepts of effect and positive operator valued measure (POVM). As we have said, the measurement problem is one of the most fundamental issues in the conceptual structure of quantum mechanics (as described in Sec. 9.1) and has a long history that will be examined in Sec. 9.2. In this context, the existence of apparently paradoxical quantum states comes about: the so-called Schrödinger cat states (see Sec. 9.3).