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Chapman & Hall/CRC eBooks

Quantum Mechanics

Domenico D'Alessandro

Published Aug 3, 2007• 0 citations
Publisher

Abstract

We present some of the main notions of quantum mechanics and introduce some of the notation that will be used in the book. Some more concepts of interest in general quantum mechanics will also be introduced in other parts of the book as needed. There are several introductions to quantum mechanics at various levels. Some of the most popular are [49], [80], [84], [88], [145], [185].

DOI
10.1201/9781584888833-5

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Cambridge University Press eBooks•Nov 29, 2001•0 citations
We present some of the main notions of quantum mechanics and introduce some of the notation that will be used in the book. Some more concepts of interest in general quantum mechanics will also be introduced in other parts of the book as needed. There are several introductions to quantum mechanics at various levels. Some of the most popular are [49], [80], [84], [88], [145], [185].
Abstract This book provides the reader with a contemporary and comprehensive introduction to Quantum Mechanics. It is suitable for beginners as well as for more advanced university students. Quantum mechanics is presented in a pedagogical fashion, with a clear logical organization. The various concepts and methods are introduced first in elementary terms, and later developed into more precise formulations. Systematic studies of approximation methods and the discussion of a wide class of physical applications follow. Part I of the book, together with the opening sections of Part II, provide adequate material for an introductory course of one semester at most universities. The rest of the book might be used in an advanced course on Quantum Mechanics. The basic material is fairly standard, even though some discussions such as those on general systems with time-dependent Hamiltonians, on metastable systems, as well as the discussions in some of the Complement sections, may not be found in other textbooks. The book also contains many original observations or new ways of illustrating even well-known subjects. In fact, the authors wish to convey in this book the sense of wonder in the logical simplicity and at the same time the beauty of subtle and far-reaching consequences of Quantum Mechanics, to young physics students in particular. Problem sets are provided at the end of each chapter, to be solved either analytically or by numerical methods. The solutions to both types of problems are given as separate pdf files or as Mathematica notebooks (there are 88 of them), all together on a CD accompanying the textbook. The presence of such a collection of numerical analyses enriches the main text and is one of the characteristic features of the book. With the many interesting systems discussed, the book will also be a useful reference for researchers and teachers. It provides the reader with a unique, enjoyable and rather complete textbook of Quantum Mechanics, destined to set a new standard for many years to come.
Quantum mechanics — central not only to physics, but also to chemistry, materials science, and other fields — is notoriously abstract and difficult. This book is a concise, explanatory book that focuses on the fundamental structure, concepts, and methods of quantum mechanics, filling the gap between introductory and advanced studies, between popularizations and technical treatises. Although physical understanding is emphasized, the mathematical sophistication necessary to achieve that understanding is also developed. A modern perspective is adopted throughout, the goal being to gain entry into quantum mechanics as used by practicing scientists. This perspective includes a focus on quantum states generally, not just wavefunctions, and a strong emphasis on Dirac notation. Many standard topics are developed, such as the Schrödinger equation, quantum states, operators, and matrix mechanics. Some non-standard topics are also discussed, such as the complex nature of quantum states, and various interpretations of the uncertainty relations. Discussion of applications is limited, and focuses on elucidating the structure of quantum mechanics.
I start by briefly overviewing quantum mechanics as it is standardly formulated and by discussing the question of whether this standard formulation needs to be supplemented by an interpretation. The overview is based mainly on Von Neumann (1932, 1955) and its aim is not to give the reader a crash course in quantum mechanics, but to present those parts of the standard formalism which I use in this book. For a more complete treatment, the reader may consult the standard textbooks on quantum mechanics or, for instance, Sudbery (1986) or Redhead (1987). The standard formulation The standard formulation of quantum mechanics can be introduced in four steps. The first step is that in quantum mechanics one describesthe physics of a system by means of a Hilbert space ℋ. This Hilbert space is a complex linear vector space on which an inner product is defined. Let's adopt the convention (please consult the Glossary at the end of the book for notational conventions) that α refers to a system and that is the Hilbert space that is associated with this system. Let ∣ℋ α 〉 denote a vector in ℋ α and let 〈ψ α ∣φ α 〉 be the inner product between the vectors ∣ψ α 〉 and ∣φ α 〉.
The mathematical formalism of quantum theory in terms of vectors and operators in infinite-dimensional complex vector spaces is very abstract. The definitions of many mathematical quantities used do not seem to have an intuitive meaning, which makes it difficult to appreciate the mathematical formalism and understand quantum mechanics. This book provides intuition and motivation to the mathematics of quantum theory, introducing the mathematics in its simplest and familiar form, for instance, with three-dimensional vectors and operators, which can be readily understood. Feeling confident about and comfortable with the mathematics used helps readers appreciate and understand the concepts and formalism of quantum mechanics. This book is divided into four parts. Part I is a brief review of the general properties of classical and quantum systems. A general discussion of probability theory is also included which aims to help in understanding the probability theories relevant to quantum mechanics. Part II is a detailed study of the mathematics for quantum mechanics. Part III presents quantum mechanics in a series of postulates. Six groups of postulates are presented to describe orthodox quantum systems. Each statement of a postulate is supplemented with a detailed discussion. To make them easier to understand, the postulates for discrete observables are presented before those for continuous observables. Part IV presents several illustrative applications, which include harmonic and isotropic oscillators, charged particle in external magnetic fields and the Aharonov–Bohm effect. For easy reference, definitions, theorems, examples, comments, properties and results are labelled with section numbers. Various symbols and notations are adopted to distinguish different quantities explicitly and to avoid misrepresentation. Self-contained both mathematically and physically, the book is accessible to a wide readership, including astrophysicists, mathematicians and philosophers of science who are interested in the foundations of quantum mechanics.
The book is an introduction to quantum mechanics at a level suitable for the second year in a European university (junior or senior year in an American college). The matrix formulation of quantum mechanics is emphasized throughout, and the student is introduced to Dirac notation from the start. A number of major examples illustrate the workings of quantum mechanics. Several of these examples are taken from solid state physics, with the purpose of showing that quantum mechanics forms the common basis for understanding atoms, molecules and condensed matter. The book contains an introductory chapter which puts the concepts of quantum mechanics into a historical framework. The solid-state applications discussed in this text include the quantum Hall effect, spin waves, quantum wells and energy bands. Other examples feature the two-dimensional harmonic oscillator, coherent states, two-electron atoms, the ammonia molecule and the chemical bond. A large number of homework problems are included.
Scope of this book Quantum mechanics is a difficult subject, and this book is intended to help the reader overcome the main difficulties in the way to understanding it. The first part of the book, Chs. 2–16, contains a systematic presentation of the basic principles of quantum theory, along with a number of examples which illustrate how these principles apply to particular quantum systems. The applications are, for the most part, limited to toy models whose simple structure allows one to see what is going on without using complicated mathematics or lengthy formulas. The principles themselves, however, are formulated in such a way that they can be applied to (almost) any nonrelativistic quantum system. In the second part of the book, Chs. 17–25, these principles are applied to quantum measurements and various quantum paradoxes, subjects which give rise to serious conceptual problems when they are not treated in a fully consistent manner. The final chapters are of a somewhat different character. Chapter 26 on decoherence and the classical limit of quantum theory is a very sketchy introduction to these important topics along with some indication as to how the basic principles presented in the first part of the book can be used for understanding them. Chapter 27 on quantum theory and reality belongs to the interface between physics and philosophy and indicates why quantum theory is compatible with a real world whose existence is not dependent on what scientists think and believe, or the experiments they choose to carry out. The Bibliography contains references for those interested in further reading or in tracing the origin of some of the ideas presented in earlier chapters.