Modern physicists incorporate into their statistical analyses additional degrees of freedom, parameters that were unknown to the nineteenth-century scientists. The true black body intensity distribution is continuous, but the model of discrete radiators provides a good approximation for the observed wavelengths of light and stimulated a paradigm shift in the thinking of physicists about microphysics. Niels Bohr model was a source of consternation to the contemporary physics community. As with thermodynamics, quantum theory is extraordinarily useful and has been applied with tremendous ingenuity by solid-state physicists, engineers, and others who are able to harness its guidance for technological innovation. The disconcerting quantum jumps were explained away by re-envisioning the localized planetary electron as a distributed cloud surrounding the atomic nucleus. The technique of Fourier analysis was Werner Heisenberg’s path to the development of a quantum theory, which he ultimately expressed in the mathematical form of matrices.
Modern physicists incorporate into their statistical analyses additional degrees of freedom, parameters that were unknown to the nineteenth-century scientists. The true black body intensity distribution is continuous, but the model of discrete radiators provides a good approximation for the observed wavelengths of light and stimulated a paradigm shift in the thinking of physicists about microphysics. Niels Bohr model was a source of consternation to the contemporary physics community. As with thermodynamics, quantum theory is extraordinarily useful and has been applied with tremendous ingenuity by solid-state physicists, engineers, and others who are able to harness its guidance for technological innovation. The disconcerting quantum jumps were explained away by re-envisioning the localized planetary electron as a distributed cloud surrounding the atomic nucleus. The technique of Fourier analysis was Werner Heisenberg’s path to the development of a quantum theory, which he ultimately expressed in the mathematical form of matrices.
Toward the end of the nineteenth century, it became clear that some experiments cannot be explained on the basis of known physics, now referred to as classical physics. In 1900, Max Planck was able to correctly describe the distribution of blackbody radiation energy as a function of wavelength λ or frequency ν = c/λ. He had to accept the existence of energy packets (quanta) with energy E = hν. A few years later, Albert Einstein found that this unexpected relation between energy and frequency is also necessary in order to understand photoemission from metallic surfaces. A decade later, Niels Bohr arrived at the correct equation for the electronic spectrum of the hydrogen atom by applying “quantum conditions” on the motion of the electron around the nucleus and the Planck’s relation E = hν on the energy difference between the energy levels (1916). A decade later, Heisenberg, Born, and Jordan introduced “quantum mechanics” and de Broglie and Schrödinger (1925-1926) introduced “wave mechanics.”
At the beginning of the twentieth century, it became clear that microscopic particles do not obey Newton's laws of classical mechanics. The idea of light quanta was at odds with the established wisdom that light is a wave phenomenon, of course, but no other explanation of the photoelectric effect seemed possible. The next step in the development of quantum mechanics was taken by Niels Bohr, who introduced postulates about the discreteness of the energy of the bound electrons in an atom similar to the discreteness of the energy of light quanta. Modern quantum mechanics was founded by Werner Heisenberg, Max Born, Erwin Schroedinger, Paul Adrian Maurice Dirac, Wolfgang Pauli, Enrico Fermi, and others. In quantum mechanics, it is in general fundamentally impossible to determine the exact outcome of an experiment; one can only determine the probability of any given outcome.
The beginning of the twentieth century brought surprising nonclas- sical phenomena. Max Planck’s explanation of black-body radiation [1], the work of Albert Einstein on the photoelectric effect [2], and Niels Bohr’s model to account for the electron orbits around the nuclei [3] established what is now known as the old quantum theory. To describe and explain these effects, phenomenological models and theories were first developed, without any rigorous and global justification. In order to provide a complete explanation for the underlying physics of such new nonclassical phenomena, physicists were forced to abandon classical mechanics to develop novel, abstract, and imaginative formalisms.
By the end of the nineteenth century all the important elements of classical physics were fully mature. Newton's Laws had been applied with success to everything from industrial machines to planetary orbits. Classical thermodynamics had extended energy conservation arguments into thermal processes, and scientists including J. Willard Gibbs and Ludwig Boltzmann had developed the statistical interpretation of entropy. James Clerk Maxwell had explained all electromagnetic phenomena, from AC generators/motors to light, with the four Maxwell's equations and three material-dependent constitutive relations. There was serious discussion that physics was on the verge of being “finished” – becoming a closed system of knowledge like classical geometry with only essentially routine tasks left of determining how the known laws could be applied to engineering problems. Yet by 1930 the foundations of mechanics, electromagnetics, and atomic-scale systems had been shaken to the core by the new revolutions in the Theory of Relativity, the photon picture of light, and quantum physics. We are still reaping the benefits of the application of these new scientific paradigms in our technology today, including semiconductor electronic devices, lasers, and GPS systems. But the description of reality that these theories provide is still deeply anti-intuitive and disturbing. Nevertheless, quantum physics is one of the most extensively experimentally verified theories that we know. Even when quantum theory and common sense seem to diverge, quantum theory gives the right answers when tested by experiment. In the next chapter we will develop the framework of quantum theory that has been so successful when people “shut up and calculate,” as one scientist suggested as the way through the philosophical thicket of quantum physics. But in this chapter, we will spend a brief time considering the historical development and continuing paradoxical implications of quantum theory. The photoelectric effect and photons In 1905, Albert Einstein, who was a key figure in the revolution of modern physics, was working as a clerk in the patent office in Zurich, Switzerland. Einstein had finished his studies in physics, but had not obtained a coveted position as a university professor. He was intensely interested in the latest developments in classical physics and was aware of a few of the remaining loose ends that were resisting explanation in the classical model.
[M]odern physics has definitely decided in favor of Plato. In fact the smallest units of matter are not physical objects in the ordinary sense; they are forms, ideas which can be expressed unambiguously only in mathematical language. Werner Heisenberg Basic framework Prerequisites: Appendix C, §1B(ii). Near the beginning of the twentieth century, physicists realized that electromagnetic waves sometimes exhibited particle-like properties, as if light were composed of discrete ‘photons’. In 1923, Louis de Broglie proposed that, conversely, particles of matter might have wave-like properties. This was confirmed in 1927 by C. J. Davisson and L. H. Germer and, independently, by G. P. Thompson, who showed that an electron beam exhibited an unmistakable diffraction pattern when scattered off a metal plate, as if the beam were composed of ‘electron waves’. Systems with many interacting particles exhibit even more curious phenomena. Quantum mechanics is a theory which explains these phenomena. We will not attempt here to provide a physical justification for quantum mechanics. Historically, quantum theory developed through a combination of vaguely implausible physical analogies and wild guesses motivated by inexplicable empirical phenomena. By now, these analogies and guesses have been overwhelmingly vindicated by experimental evidence. The best justification for quantum mechanics is that it ‘works’, by which we mean that its theoretical predictions match all available empirical data with astonishing accuracy.
Quantum physics is well known for being counter-intuitive, or even bizarre. Quantum correlations have no equivalence in classical physics. This was all well known for years. But several discoveries in the 1990's changed the world. First, in 1991 Artur Ekert, from Oxford University, discovered that quantum correlations could be used to distribute cryptographic keys. Suddenly physicists realized that quantum correlations and its associated bizarre non-locality, could be exploited to achieve a useful task that would be impossible without quantum physics. What a revolution! And this was not the end. Three years later, Peter Shor, from the AT&T Laboratories, discovered an algorithm that breaks the most used public key crypto-systems. Shor's algorithm requires a quantum computer, yet another bizarre quantum device, a kind of computer that heavily exploits the quantum superposition principle. The following year, in 1995, a collaboration between six physicists and computer scientists from three continents led to the discovery of quantum teleportation, a process with a science-fiction flavour. These discoveries and others led to the emergence of a new science, marrying quantum physics and theoretical computer science, called quantum information science. Today, a steadily growing community of physicists, mathematicians and computer scientists develop the tools of this new science. This leads to new experiments and new insights into physics and information theory. It is a fascinating time. Quantum information is still a very young science. In particular, the technology required to build a quantum computer is still unknown. Only quantum key distribution has reached a certain level of maturity, with a few start-ups already offering complete systems. Nevertheless, quantum information has been widely recognised as a source for truly innovative ideas and disruptive technologies.