From a theoretical point of view, one of the appealing features of clouds of alkali atom vapours is that particle separations, which are typically of order 10 2 nm, are large compared with the scattering length a which characterizes the strength of interactions. Scattering lengths for alkali atoms are of the order of 100 a 0 , where a 0 , is the Bohr radius, and therefore alkali atom vapours are dilute, in the sense that the dominant effects of interaction are due to two-body encounters. It is therefore possible to calculate properties of the gas reliably from a knowledge of two-body scattering at low energies, which implies that information about atomic scattering is a key ingredient in work on Bose–Einstein condensates. An alkali atom in its electronic ground state has several different hyperfine states, as we have seen in Secs. 3.1 and 3.2. Interatomic interactions give rise to transitions between these states and, as we described in Sec. 4.6, such processes are a major mechanism for loss of trapped atoms. In a scattering process, the internal states of the particles in the initial or final states are described by a set of quantum numbers, such as those for the spin, the atomic species, and their state of excitation. We shall refer to a possible choice of these quantum numbers as a channel.1 At the temperatures of interest for Bose-Einstein condensation, atoms are in their electronic ground states, and the only relevant internal states are therefore the hyperfine states. Because of the existence of several hyperfine states for a single atom, the scattering of cold alkali atoms is a multi-channel problem.
From a theoretical point of view, one of the appealing features of clouds of alkali atom vapours is that particle separations, which are typically of order 10 2 nm, are large compared with the scattering length a which characterizes the strength of interactions. Scattering lengths for alkali atoms are of the order of 100 a 0 , where a 0 , is the Bohr radius, and therefore alkali atom vapours are dilute, in the sense that the dominant effects of interaction are due to two-body encounters. It is therefore possible to calculate properties of the gas reliably from a knowledge of two-body scattering at low energies, which implies that information about atomic scattering is a key ingredient in work on Bose–Einstein condensates. An alkali atom in its electronic ground state has several different hyperfine states, as we have seen in Secs. 3.1 and 3.2. Interatomic interactions give rise to transitions between these states and, as we described in Sec. 4.6, such processes are a major mechanism for loss of trapped atoms. In a scattering process, the internal states of the particles in the initial or final states are described by a set of quantum numbers, such as those for the spin, the atomic species, and their state of excitation. We shall refer to a possible choice of these quantum numbers as a channel.1 At the temperatures of interest for Bose-Einstein condensation, atoms are in their electronic ground states, and the only relevant internal states are therefore the hyperfine states. Because of the existence of several hyperfine states for a single atom, the scattering of cold alkali atoms is a multi-channel problem.
An important feature of cold atomic vapours is that particle separations, which are typically of order 10 2 nm, are usually an order of magnitude larger than the length scales associated with the atom–atom interaction. Consequently, the two-body interaction between atoms dominates, and three-and higher-body interactions are unimportant. Moreover, since the atoms have low velocities, many properties of these systems may be calculated in terms of a single parameter, the scattering length. An alkali atom in its electronic ground state has several different hyperfine states, as we have seen in Secs. 3.1 and 3.2. Interatomic interactions give rise to transitions between these states and, as we described in Sec. 4.6, such processes are a major mechanism for loss of trapped atoms. In a scattering process, the internal states of the particles in the initial or final states are described by a set of quantum numbers, such as those for the spin, the atomic species, and their state of excitation. We shall refer to a possible choice of these quantum numbers as a channel . At the temperatures of interest for Bose–Einstein condensation, atoms are in their electronic ground states, and the only relevant internal states are therefore the hyperfine states. Because of the existence of several hyperfine states for a single atom, the scattering of cold alkali atoms is a multi-channel problem.
Collision physics plays a key role in understanding the properties of ultracold gases. First, collisions ensure thermalization in trapped atomic samples, which is essential for the success of evaporative cooling. Second, interactions between atoms determine the equilibrium shape and the dynamics of the condensate once it is formed. Finally collisions limit the achievable spatial densities via inelastic processes, which ultimately determine whether a given atomic species may lead to Bose-Einstein condensation. The purpose of the following lectures is to give a basic introduction to collision physics with a special emphasis on the low temperature aspect of these interactions. We will consider here only binary interactions between atoms since one of the remarkable prop-erties of the physics of ultra-cold dilute gases is that all the macroscopic properties of the system can be directly deduced from the two-body interaction potential. In particular the essential concept of scattering length will be introduced and developped for some simple potentials, using as practical examples experimental results obtained on atomic cesium and rubidium. The present lectures are complementary to the ones given by D. Heinzen where a detailed comparison between the collisional properties of the various alkali atoms will be found, together with explanations of the spectroscopic approaches used in the precise determination of interatomic potentials. 1. – Scattering theory: a brief reminder 1.1. Collision between two particles. – We consider here an elementary collision process between two particles 1 and 2 with the same mass M, interacting through the potential
A new facet was added to the study of dilute gases by the production and subsequent Bose–Einstein condensation of diatomic molecules from a gas of fermionic atoms. Feshbach resonances which, as we have seen in Sec. 5.4, make it possible to tune the atom–atom interaction, play a crucial role in the experiments. At the magnetic field strength for which the binding energy of the molecule vanishes, the inverse of the scattering length, which determines the low-energy effective interaction between atoms, passes through zero. In the experiments to produce molecules, one starts with a mixture of two species of fermion, most commonly different hyperfine states of the same isotope, in a magnetic field of such a strength that the molecular state has an energy higher than that of two zero-momentum atoms in the open channel. The magnetic field is then altered to a value at which the molecular state is bound with respect to two atoms in the open channel, and in this process, many of the atoms combine to form molecules. These molecules have binding energies in the 10 −9 eV range, and are thus extremely weakly bound by the standards of conventional molecular physics. In addition, they are very extended, with atomic separations as large as one micron. These molecules, being bosons, can undergo Bose–Einstein condensation, just as bosonic atoms do.
Introduction Interactions between separated atoms are complicated by the large number of degrees of freedom of a many-atom system, and are very difficult to describe quantitatively. Although the Hamiltonian for such systems can be written down easily, finding the eigenfunctions requires a sophisticated effort and large computer resources. This area of quantum chemistry, with all its intricacies, is a complex subfield of science that cannot be adequately described in a single book chapter. Therefore the student is referred to specialized books in this field for further reading [165, 170]. In the 1990s a new field of chemistry emerged that considered such interactions between atoms at ultra-cold temperatures. The field focuses strongly on atomic interactions at large internuclear distances where the atoms are well separated and their electronic clouds do not strongly overlap. In such circumstances the interactions are dominated by the properties of the states of the atoms and they can be understood from an atomic point of view. In this chapter the basic features of this field will be described. The interaction energy (electronic potential energy) between two colliding partners separated by a large distance is called the dissociation limit. Light interactions with the particles can occur with the total energy above or below this limit. The relative kinetic energy does not contribute because it is so very small at such low temperatures. In the presence of a light field tuned below this limit for a pair that has one of the atoms in an excited state, two unbound atoms can be associated into a bound molecular state (for example, an S–P collision of two alkali atoms). Such photo-association is more likely at a large interatomic separation because there is good radial overlap between the incoming, low-energy scattering state and the outer turning point of the bound excited state, so it usually produces a molecule in a high vibrational state. Studying these states provides important information about interatomic interactions near the dissociation limit. The long-range part of the potential is dominated by atomic parameters and in Sec. 18.2 it is shown how these potentials can be constructed. The LeRoy–Bernstein method, which was developed long before the advent of cold-atom photo-association, is described in Sec. 18.3 and can be used to extract these parameters from measurements of the bound states.
We present a theoretical analysis of excitation modes in Bose-Einstein condensates of ultracold alkali-metal gases for large scattering lengths, showing clear deviations from the Bogoliubov prediction as seen by Papp et al. [Phys. Rev. Lett. 101, 135301 (2008)]. We construct the atom-atom interaction by deriving the T matrix of such systems from two coupled (open and closed) channels assuming that the Feshbach resonance dominates the latter. We calculate molecular bound-state energies as a function of the magnetic field and compare with available experiments. The s-wave phase shifts determine the local effective interaction with long-ranged repulsion and short-ranged attraction. We show that it becomes a universal function at large scattering lengths. Finally, we use this interaction to characterize the ground-state and elementary excitations of 85Rb, 87Rb, and 23Na gases. Good agreement with line shift experiments in 85Rb is achieved. We find that, at large scattering lengths, Bragg scattering experiments could directly measure the momentum dependence of the effective two-body potential.
The control afforded by Feshbach resonance phenomena has enabled the exploration of strongly interacting degenerate regimes in dilute ultracold atomic alkali-gases. In these dilute systems, interactions are characterized by a single parameter, the s-wave scattering length. In this dissertation, we review the physics of quantum degenerate atomic gases from a theoretical perspective and present the applications of non-perturbative numerical methods ranging from exact diagonalization to quantum Monte Carlo techniques. Emphasis is given to the effect of interactions. A major goal of this work is to compare theoretical predictions with available experimental results. We begin by introducing the effective interactions in the many-body alkali-gas system. As simplifications of the real interaction between two alkali atoms, the resonance properties of various short range models, the zero-range model and the two-channel model are investigated. The fundamental result is that under appropriate conditions, the true interaction potential V(r) of two atoms may be replaced by a regularized delta-function. In collaboration with experimentalists in our department, we developed a unique method to construct localized single-particle wave functions using imaginary time projection and thereby determine lattice Hamiltonian parameters. Our method enables an efficient coarse-grained mapping from a continuum system to a lattice model. We apply the method to a specific disordered potential generated by an optical lattice experiment and calculate for each instance of disorder the equivalent lattice model parameters. Detailed statistical analysis is performed on the resulting probability distributions of the Hubbard parameters. In the final part, we study the pairing and ferromagnetic instabilities in systems of spin-1/2 fermions. To interpret a recent experimental study of the possibility of itinerant ferromagnetism in cold atom systems, we investigate the energy spectrum of a system of four spin-1/2 fermions with short range attractive interactions both exactly and within the scattering length approximation. The formation of molecular bound states and the ferromagnetic transition of the excited scattering state are examined systematically as a function of the two-body scattering length. We show that an adiabatic ferromagnetic transition occurs, but at a critical transition point k_{F}a much higher than predictions from the scattering length approximations. The exact critical interaction strength calculated in the four-particle system is consistent with that reported by experiment. Finally, by constructing a many-body wavefunction satisfying the Bethe-Peierls boundary conditions, we attempted the first variational Monte Carlo calculations of the zero-range model of unitary Fermion gases, eliminating the need for short-range approximations employed by existing QMC calculations.