Abstract In the previous six chapters, we focused on understanding the basic eigenstates of various Hamiltonians by solving the time independent Schrödinger equation. While the Hamiltonians seemed relatively simple, the solutions are frequently used. However, in practice, most of the important problems today do not make extensive use of the spatial solutions except when a specific number is needed. The focus on most problems today makes extensive use of operators where their behavior is governed by the new design rules that we must follow to do anything novel with quantum systems. The design rules are sometimes referred to as the postulates. Postulates are mathematical statements of specific rules. We will present five postulates in this chapter and then in later chapters augment them with three more. In the context of this math, we will continue to work with functions like ψ(r,t), but we will introduce Dirac notation such as ∣ψ(t)〉. The remaining chapters in this text work almost exclusively in Dirac notation and with operators.
Abstract In the previous six chapters, we focused on understanding the basic eigenstates of various Hamiltonians by solving the time independent Schrödinger equation. While the Hamiltonians seemed relatively simple, the solutions are frequently used. However, in practice, most of the important problems today do not make extensive use of the spatial solutions except when a specific number is needed. The focus on most problems today makes extensive use of operators where their behavior is governed by the new design rules that we must follow to do anything novel with quantum systems. The design rules are sometimes referred to as the postulates. Postulates are mathematical statements of specific rules. We will present five postulates in this chapter and then in later chapters augment them with three more. In the context of this math, we will continue to work with functions like ψ(r,t), but we will introduce Dirac notation such as ∣ψ(t)〉. The remaining chapters in this text work almost exclusively in Dirac notation and with operators.
We summarize below some of the postulates and definitions basic to our formalism, and present some important results based on these postulates. The formalism is purely mathematical in nature with very little physics input, but it provides the structure within which the physical concepts that will be discussed in the later chapters will be framed. State vectors It is important to realize that the Quantum Theory is a linear theory in which the physical state of a system is described by a vector in a complex, linear vector space. This vector may represent a free particle or a particle bound in an atom or a particle interacting with other particles or with external fields. It is much like a vector in ordinary three-dimensional space, following many of the same rules, except that it describes a very complicated physical system. We will be elaborating further on this in the following. The mathematical structure of a quantum mechanical system will be presented in terms of the notations developed by Dirac. A physical state in this notation is described by a “ket” vector, |〉, designated variously as |α〉 or |ψ〉 or a ket with other appropriate symbols depending on the specific problem at hand. The kets can be complex. Their complex conjugates, |〉 * , are designated by 〈| which are called “bra” vectors. Thus, corresponding to every ket vector there is a bra vector. These vectors are abstract quantities whose physical interpretation is derived through their so-called “representatives” in the coordinate or momentum space or in a space appropriate to the problem under consideration.
In this chapter the basic concepts of quantum theory are formulated via a self-consistent set of six postulates. These six postulates deal with the following: operator images of physical observables; properties of state vectors and wave functions; the connection with experimental measurements; coordinate-space forms of those operators having classical analogs; the primary dynamical equation of quantum mechanics; and the completeness of the eigenvectors of observables. The postulates are the framework on which the edifice of quantum mechanics is constructed. A separate section is devoted to the statement of each postulate and to a few examples chosen to illustrate or apply it. A comprehensive set of applications is presented in Chapters 6 and 7, where various 1-D systems are used as the vehicles for illustrating the postulates. The basic theory of this chapter is extended and developed in Chapters 8 and 9. Since probability is a key interpretational concept, a brief introduction to this topic is given in an appendix. We emphasize that our formulation of quantum theory (in this chapter and throughout this book) is restricted to the case of pure states. This is not a major restriction. It means that, when we consider ensembles of individual quantum systems (e.g., single particles, atoms, nuclei, etc.), all of the systems in the ensemble are assumed to be in the same quantum state, not necessarily an eigenstate of a quantal operator. Ensembles for which this assumption does not hold are described by a density operator or density matrix rather than by a pure state; treatments of such cases can be found in references cited later.
This chapter discusses the concept of a postulate and develops the basic structure of quantum mechanics using three postulates. Postulate 1 introduces the concept of a quantum state as a solution of the time-independent Schrödinger equation. Postulate 2 introduces observables, which are represented by Hermitian operators; the possible measurement values of an observable are the eigenvalues of the corresponding Hermitian operator. Postulate 3 introduces the concept of a superposition, and the association of the probability for obtaining some measurement result with the complex square of an expansion coefficient in a superposition. In discussing Postulate 3, state normalization, the distinction between discrete and continuous eigenvalues, and the Dirac delta are also introduced.
Basic scientific theories usually start with a set of hypotheses or “postulates.” There is generally no logical reason, apart from internal consistency, that can be given to justify such postulates absolutely. They come from ‘revelations’ in the minds of ‘geniuses,’ most likely with hints from Nature based on extensive careful observations. Their general validity can only be established through experimental verification. If numerous rigorously derived logical consequences of a very small set of postulates all agree with experimental observations without exception, one is inclined to accept these postulates as correct descriptions of the laws of Nature and use them confidently to explain and predict other natural phenomena. Quantum mechanics is no exception. It is based on a few postulates. For the purpose of the present discussion, we begin with three basic postulates involving: the “state functions,” “operators,” and “equations of motion.” In this chapter, this set of basic postulates and some of the corollaries and related definitions of terms are introduced and discussed. We will first simply state these postulates and introduce some of the related mathematical tools and concepts that are needed to arrive at their logical consequences later. To those who have not been exposed to the subject of quantum mechanics before, each of these postulates taken by itself may appear puzzling and meaningless at first. It should be borne in mind, however, that it is the collection of these postulates as a whole that forms the foundations of quantum mechanics.
Abstract This chapter reviews all the rules of quantum mechanics and their mathematical notation. It also considers quantum entanglement, a fundamental resource in quantum information. There are four basic postulates of quantum mechanics, that indicate how to represent physical systems, how to represent observations, how to carry out measurements, and how systems evolve when “not measured”. Before describing the laws of quantum mechanics, their mathematical background is first described, along with a Mach Zehnder interferometer experiment in which the (strange) readings on the detectors can be explained by quantum mechanics. This chapter also discusses the Dirac notation, qubits, Hilbert spaces, projective measurements and operations, unitary operations, eigenvectors and eigenvalues, spectral decomposition, applications of the spectral theorem, Dirac notation shorthands, and mixed states.
The goal of Quantum Mechanics I, A Problem Text, is to enable students to solve problems appropriate to their first course in quantum mechanics. Significantly detailed solutions to traditionally posed problems dominate. Theory and rationale are addressed in prescript and postscript narratives and/or within the solved problems to guide students; and clarify vocabulary, symbology, and terminology. Applications of the postulates are presented initially using arguments from linear algebra appropriate to discrete systems with low-dimensional vectors and matrix operators, introducing orthogonality, orthonormality, Hermiticity, eigenvectors, eigenvalues, probability, expectation value, and degeneracy. These arguments blend into infinite-dimensional vectors and operators, and calculus-based arguments for continuous systems where delta functions, theta functions, and Fourier transforms are initially discussed. Dirac notation is fully developed within these first five chapters. Chapter six discusses Ehrenfest’s theorem, the Heisenberg uncertainty relations, and Gaussian wave functions and wave packets. Increasingly sophisticated potential energy functions are then treated to include the free particle, the infinite square well, the one-dimensional scattering state, the simple harmonic oscillator, the finite square well, orbital angular momentum, and the hydrogen atom. Ladder operators are featured in the developments of the simple harmonic oscillator and orbital angular momentum. The diversity of narratives and detailed solutions intend