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Acta Physica Sinica

Diamond spin quantum sensing under extreme conditions

Gang‐Qin Liu

Published Jan 1, 2022• 3 citations
Publisher

Abstract

Extreme conditions, such as ultra-low temperatures, high pressures, and strong magnetic fields, are critical to producing and studying exotic states of matter. To measure physical properties under extreme conditions, the advanced sensing schemes are required. As a promising quantum sensor, the diamond nitrogen-vacancy (NV) center can detect magnetic field, electronic field, pressure, and temperature with high sensitivity. Considering its nanoscale spatial resolution and ultra-wide working range, the diamond quantum sensing can play an important role in frontier studies involving extreme conditions. This paper reviews the spin and optical properties of diamond NV center under extreme conditions, including low temperature, high temperature, zero field, strong magnetic fields, and high pressures. The opportunities and challenges of diamond quantum sensing under extreme conditions are discussed. The basic knowledge of spin-based quantum sensing and its applications under extreme conditions are also covered.

DOI
10.7498/aps.71.20212072

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Extreme conditions, such as ultra-low temperatures, high pressures, and strong magnetic fields, are critical to producing and studying exotic states of matter. To measure physical properties under extreme conditions, the advanced sensing schemes are required. As a promising quantum sensor, the diamond nitrogen-vacancy (NV) center can detect magnetic field, electronic field, pressure, and temperature with high sensitivity. Considering its nanoscale spatial resolution and ultra-wide working range, the diamond quantum sensing can play an important role in frontier studies involving extreme conditions. This paper reviews the spin and optical properties of diamond NV center under extreme conditions, including low temperature, high temperature, zero field, strong magnetic fields, and high pressures. The opportunities and challenges of diamond quantum sensing under extreme conditions are discussed. The basic knowledge of spin-based quantum sensing and its applications under extreme conditions are also covered.
Quantum sensing is a quantum technology for ultrasensitive detection, which is particularly useful for sensing weak signals at the nanoscale. Nitrogen vacancy centers in diamond, thanks to their superb quantum coherence under ambient conditions and the stability of the material in extreme and complicated environments, have been demonstrated as promising quantum probes in multi-parameter sensing. Their spin properties make them particularly sensitive to magnetic fields, but they are insensitive to temperature, electric field, pressure, etc., and even immune to some bio-parameters (e.g., pH and glucose concentration). Recently, hybrid quantum sensing has emerged as a promising avenue for further enhancing the capabilities of diamond sensors. Different techniques can potentially improve the sensitivity, range of detectable parameters, and sensing frequencies of diamond sensors. This review provides an overview of hybrid quantum sensing using diamond. We first give a brief introduction to quantum sensing using diamond, and then review various hybrid sensing schemes that have been developed to enhance the sensing capabilities of diamond sensors. Finally, the potential applications and challenges associated with hybrid quantum sensing in diamond are discussed.
Pressure has been established as a powerful way of tuning material properties and studying various exotic quantum phases. Nonetheless, measurements under pressure are no trivial matter. To ensure a stable pressure environment, several experimental restrictions must be imposed including the limited size of a sample chamber. These have created difficulties in assembling high-pressure devices and conducting measurements. Hence, novel sensing methods that are robust and compatible with high-pressure devices under pressure are highly in demand. In this review, we discuss the nitrogen-vacancy (NV) center in diamond as a versatile quantum sensor under pressure. The excellent sensitivity and superior resolution of the NV center enable exciting developments in recent years. The NV center has great potential in sensing under pressure, especially beneficial to magnetic-related measurements.
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Single qubit in solid-state materials recently emerges as a versatile platform for quantum information. Among them, the nitrogen vacancy (NV) centre in diamond has become a powerful tool in quantum sensing for detecting various physics parameters, including electric and magnetic fields, temperature, force, strain, with ultimate precision and resolutions. It has been widely used in different conditions, from samples in ambient to samples in ultra-high pressure and low temperature. It can detect quantum phase transitions as well as neuron activities. Here we give a general review on both the physics of the sensing mechanism and protocols and applications.
In modern-day quantum metrology, quantum sensors are widely employed to detect weak magnetic fields or nanoscale signals. Quantum devices, exploiting quantum coherence, are inevitably connected to physical constants and can achieve accuracy, repeatability, and precision approaching fundamental limits. As a result, these sensors have shown utility in a wide range of research domains spanning both science and technology. A rapidly emerging quantum sensing platform employs atomic-scale defects in crystals. In particular, magnetometry using nitrogen-vacancy (NV) color centers in diamond has garnered increasing interest. NV systems possess a combination of remarkable properties, optical addressability, long coherence times, and biocompatibility. Sensors based on NV centers excel in spatial resolution and magnetic sensitivity. These diamond-based sensors promise comparable combination of high spatial resolution and magnetic sensitivity without cryogenic operation. The above properties of NV magnetometers promise increasingly integrated quantum measurement technology, as a result, they have been extensively developed with various protocols and find use in numerous applications spanning materials characterization, nuclear magnetic resonance (NMR), condensed matter physics, paleomagnetism, neuroscience and living systems biology, and industrial vector magnetometry. In this chapter, NV centers are explored for magnetic sensing in a number of contexts. In general, we introduce novel regimes for magnetic-field probes with NV ensembles. Specifically, NV centers are developed for sensitive magnetometers for applications where microwaves (MWs) are prohibitively invasive and operations need to be carried out under zero ambient magnetic field. The primary goal of our discussion is to improve the utility of these NV center-based magnetometers.
Quantum sensors encompass a diverse class of devices that exploit quantum coherence to detect weak or nanoscale signals. As their behavior is tied to physical constants, quantum sensors can achieve accuracy, repeatability, and precision approaching fundamental limits [1, 2]. As a result, these sensors have shown utility in a wide range of applications in both science and engineering leading to innovations. Among many solid-state spin systems, nitrogen-vacancy (NV) centers in diamonds have attracted considerable attention as a leading platform in many fields of quantum technologies, from quantum sensing to information processing and communication applications. They have superior physical properties, and their quantum coherence is preserved even at room temperature. The energy levels of NV centers are sensitive to magnetic fields, electric fields, strain, and temperature, and the spatial resolution is scalable from nanometers to millimeters. Therefore, diamond quantum sensors are distinctive sensors with multimodality and span scalable application fields. To realize an ideal quantum sensor for applications, the technical challenges in the sensor materials and the quantum control techniques, such as coherent microwave spin manipulation, effective optical spin-state initialization, and readout, have been developed. This chapter briefly explains the sensing principle using NV centers and then introduces sensor systems for biomedical applications, and monitoring of batteries for electric vehicles and internal power devices.