Small weakly bound boson-fermion
4Hem3Hen clusters formed in a free jet expansion are identified using nondestructive transmission grating diffraction. The observations confirm the existence of more than 11 very tenuous complexes including the three-body halo molecule
4He23He and the pseudo-Borromean complex
4He23He2. Effective cluster formation temperatures, extracted from a sudden freeze model for cluster growth using theoretical binding energies, increase smoothly with cluster size, thereby confirming the calculations with the possible exception of
4He23He2.