‘Quantum mechanics’ shows how Bohr's old quantum theory was superseded by a newer theory of quantum mechanics. Bohr's quantum theory worked well in single electron sytems, but not in multi-electron systems. Quantum mechanics allowed the development of Schrödinger's equation, which could theoretically predict the determination of electron energy levels in any system. The advantage of quantum mechanics over quantum theory lies in its treatment of electrons as waves. This allowed Schrödinger to apply mathematical boundary conditions to his equation and quantise the energy levels of electrons. Further work by Heisenberg showed that electrons can be thought of as being spread around a shell rather than being in one place.
‘Quantum mechanics’ shows how Bohr's old quantum theory was superseded by a newer theory of quantum mechanics. Bohr's quantum theory worked well in single electron sytems, but not in multi-electron systems. Quantum mechanics allowed the development of Schrödinger's equation, which could theoretically predict the determination of electron energy levels in any system. The advantage of quantum mechanics over quantum theory lies in its treatment of electrons as waves. This allowed Schrödinger to apply mathematical boundary conditions to his equation and quantise the energy levels of electrons. Further work by Heisenberg showed that electrons can be thought of as being spread around a shell rather than being in one place.
‘Quantum mechanics’ shows how Bohr’s quantum theory was a stepping stone for the development of quantum mechanics. Bohr’s quantum theory worked well in single electron systems, but not in multi-electron systems. Quantum mechanics allowed the development of Schrödinger’s equation, which could theoretically predict the determination of electron energy levels in any system. The advantage of quantum mechanics over quantum theory lies in its treatment of electrons as waves. This allowed Schrödinger to apply mathematical boundary conditions to his equation and quantize the energy levels of electrons. Further work by Heisenberg showed that electrons are spread around a spherical shell. New developments on atomic configurations by Eugen Schwarz are also discussed.
In the 1920s, the old quantum theory was gradually being superseded by the new quantum theory. The cornerstone of the old theory was Bohr’s model of the hydrogen atom, which predicted that an electron cannot orbit the proton in the hydrogen atom in any arbitrary fashion. Orbits are “quantized,” meaning that only certain sizes, shapes, and magnetic properties are allowed. The principal quantum number n determined the allowed radii of the orbits, the orbital quantum number l determined the allowed shapes, and the magnetic quantum number m determined the magnetic behavior. Additionally, there is a fourth quantum number s which denotes the fact that the electron has an additional angular momentum, loosely associated with self rotation about its own axis, and that is quantized in units of (1/2)~. The old quantum theory was useful to infer the existence of discrete energy levels in atoms, calculate energy spacings between these levels, and therefore allowed one to interpret atomic spectra. The new quantum theory appeared to be more revolutionary and more powerful. It was triggered by Heisenberg’s discovery of matrix mechanics and Schro¨dinger’s discovery of wave mechanics. These two formalisms would not only predict the quantization of energy and provide a prescription to determine the energy difference between the levels (and thus explain the multiplicity of atomic spectra), but also allow one to calculate easily probabilities of transitions between different quantized energy states. At first, matrix mechanics and wave mechanics looked entirely different in their mathematical appearance and physical meaning. However, Schro¨dinger and Eckart [1] independently showed that the two theories are mathematically equivalent. Toward the end of 1926, Dirac unified the two theories using the concept of state vector and thus established the transformation theory of quantum mechanics. This ultimately had a profound implication for the quantum mechanical (mathematical) recipe to treat spin, as we will show in this chapter. The transformation theory is the mathematical recipe to handle modern quantum mechanics. In Heisenberg’s matrix mechanics, a physical quantity is expressed by a matrix, whereas in Schro¨dinger’s wave mechanics, a physical quantity is expressed by a linear operator. In the unified transformation theory, physical quantities are represented by abstract linear operators called Dirac’s q-numbers, which are linear operators in an infinite-dimensional linear space. Depending upon which types of orthogonal coordinate systems are used in this linear space, either matrix mechanics or wave mechanics emerges.
In 1926, Schrödinger [365] recognized that the variational theory of elliptical differential equations with fixed boundary conditions could produce a discrete eigenvalue spectrum in agreement with the energy levels of Bohr's model of the hydrogen atom. This conceptually startling amalgam of classical ideas of particle and field turned out to be correct. Within a few years, the new wave mechanics almost completely replaced the ad hoc quantization of classical mechanics that characterized the “old” quantum theory initiated by Bohr. Although the matrix mechanics of Heisenberg was soon shown to be logically equivalent, the variational wave theory became the standard basis of methodology in the physics of electrons. The nonrelativistic Schrödinger theory is readily extended to systems of N interacting electrons. The variational theory of finite N -electron systems (atoms and molecules) is presented here. In this context, several important theorems that follow from the variational formalism are also derived.
In its beginning, quantum mechanics was approached in two completely different ways. Schrodinger, reasoning that electronic motions could be treated as waves, developed wave mechanics. The stationary states that an electron or molecule might have were analogues to standing waves set up by applying appropriate boundary conditions. Bohr’s theory could not explain the Stark and Zeeman effect, and the spectra of atoms more complex than alkali metals. In 1927, Heisenberg added one more dimension to the problem through the uncertainty principle. The postulates of any theory are a set of fundamental statements that are asked to be believed and draw conclusions from them. In classical mechanics, all dynamical variables are observables, but there are certain fundamental restrictions placed upon simultaneously measurable quantities in quantum mechanics.
In the 1920s, the old quantum theory was gradually being superseded by the new quantum theory. The cornerstone of the old theory was Bohr’s model of the hydrogen atom which predicted that an electron cannot orbit the proton in the hydrogen atom in any arbitrary fashion. Orbits are “quantized”, meaning that only certain sizes, shapes and magnetic properties are allowed. The principal quantum number n determined the allowed radii of the orbits, the orbital quantum number l determined the allowed shapes, and the magnetic quantum number m determined the magnetic behavior. Additionally, there is a fourth quantum number s which denotes the fact that the electron has an additional angular momentum, loosely associated with self rotation about its own axis, and that is quantized in units of (1/2). The old quantum theory was useful to infer the existence of discrete energy levels in atoms, calculate energy spacings between these levels, and therefore allowed one to interpret atomic spectra.
Quantum mechanics is the newest science and should therefore be the most precise, but unfortunately, it's quite the opposite. If you don't understand quantum mechanics, ask yourself if I'm right, because others don't either. The field of experimental quantum mechanics is so vast and confusing that its theoretical practitioners will always have to adopt new explanations from their own context to conform to the facts of quantum mechanics. Quantum mechanics was created in the early 20th century to establish mathematical and physical laws or rules for subatomic objects subject to an external potential field in order to explain so-called quantum systems. Studying the spatiotemporal evolution of a quantum system, defined as a microscopic subatomic system of low energy density subjected to a potential field, external or internal, is a rather complex subject. However, in 1927, the well-known Schrödinger PDE, valid for infinite free space subject to Dirichlet boundary conditions, was introduced. Schrödinger's PDE must be complemented by the Bohr/Copenhagen interpretation of the wave function Ψ involving the rules of quantum systems of instantaneous entanglement and superposition. We all know that the Schrödinger equation is incomplete because it lives and operates in the incomplete space R^4 and therefore the wave function Ψ is incomplete in itself and cannot be defined as scalar, a vector, nor a tensor. The complex wave function Ψ has never been properly defined. Moreover, the Schrödinger PDE is not Lorentz invariant and is not compatible with the special theory of relativity, and is obviously even less so with the general theory of relativity. However, quantum mechanics has come a long way, both in theory and practice, since 1927, nearly a century ago. This long journey has added even more illogical and confusing properties to the Ψ wave function, such as causality and wave function collapse. Many attempts have been made over the last century to reform the Schrödinger equation, the most notable being to combine it with the general theory of relativity, but all these attempts have been in vain. The breakthrough came in 2020-2024 [2,3,4], when the author of this article claimed to replace the classical Schrödinger equation Ψ with the PDE for its square Ψ^2, which is logical and physical. Ψ^2 is needed to express the quantum energy density flux (U(x,y,z,t) = Ψ^2 (x,y,z,t)) and we therefore propose a new Schrödinger equation for Ψ^2 which should have the form of the energy density diffusion PDE such as that of thermal conduction. Equation 3 should be supplemented by the advanced artificial intelligence proposed by the author [5,6]. Comparing Schrödinger's classical PDE of 1927 with the PDE proposed for Ψ^2 in 2020 shows that we currently have two different or distinct theories of quantum mechanics! Which one is more theoretically true and more practically useful? This is the purpose of this article.