In its beginning, quantum mechanics was approached in two completely different ways. Schrodinger, reasoning that electronic motions could be treated as waves, developed wave mechanics. The stationary states that an electron or molecule might have were analogues to standing waves set up by applying appropriate boundary conditions. Bohr’s theory could not explain the Stark and Zeeman effect, and the spectra of atoms more complex than alkali metals. In 1927, Heisenberg added one more dimension to the problem through the uncertainty principle. The postulates of any theory are a set of fundamental statements that are asked to be believed and draw conclusions from them. In classical mechanics, all dynamical variables are observables, but there are certain fundamental restrictions placed upon simultaneously measurable quantities in quantum mechanics.
In its beginning, quantum mechanics was approached in two completely different ways. Schrodinger, reasoning that electronic motions could be treated as waves, developed wave mechanics. The stationary states that an electron or molecule might have were analogues to standing waves set up by applying appropriate boundary conditions. Bohr’s theory could not explain the Stark and Zeeman effect, and the spectra of atoms more complex than alkali metals. In 1927, Heisenberg added one more dimension to the problem through the uncertainty principle. The postulates of any theory are a set of fundamental statements that are asked to be believed and draw conclusions from them. In classical mechanics, all dynamical variables are observables, but there are certain fundamental restrictions placed upon simultaneously measurable quantities in quantum mechanics.
The uncertainty principle, formulated by Heisenberg in 1927, is a fundamental principle in quantum mechanics. It forces us to review key concepts of classical physics, and from this analysis are born the concepts of quantum physics. Consequences of the Uncertainty principle also introduces the concept of incompatible sizes, a completely new concept compared to classical physics. A state of the system, which we call a quantum state, will be determined from the knowledge of a set maximum of certain quantities that are independent and compatible with each other. A measurable physical quantity is called an observable. If at a given moment a measurement is performed by one or more compatible observables it is said they are performing an observation of the system. The basic principles of quantum mechanics are expressed by a number of postulates. Their numbers and can vary from one text to another.
Quantum mechanics is introduced here as a fundamental theory that must treat particles equally often as waves. Here, classical waves are introduced in some detail, with discussions of the important concepts of waves: medium, amplitude, frequency, wavelength, period, harmonics, interference, standing waves, etc. Waves can be oscillatory waves with a repeating pattern, or pulse waves, which are localized in space. All of the elements of waves are important in understanding how the Schrödinger equation describes particles. Classical standing waves must have wave lengths that fit between boundaries giving them discrete allowed frequencies, a harbinger of quantized energies in quantum mechanics. Complicated waves can be analyzed in terms of their component frequencies, the fundamental idea of Fourier analysis. This discussion shows that a classical wave has a limit in how accurately one can specify simultaneously the wave’s position and frequency, in analogy with Heisenberg uncertainty principle of quantum mechanics.
The behavior of classical macroscopic particles – from baseballs to planets – is governed by Newtonian mechanics as we have described in the first chapters of this book. The behavior of very small particles, on the other hand, is governed by an entirely different collection of equations and rules that go under the name of “quantum mechanics” and these particles are referred to as quantum particles. These rules have analogies to classical mechanics, but are fundamentally different and somewhat mysterious as we discussed in Chapter 8. The fundamental principles of quantum mechanics cannot be proven to be correct. They were developed based on the results of experimental observation, by analogy with classical mechanics, and through the consideration of logical implications of the formalisms used. There is no way to derive the fundamental elements of quantum mechanics, any more than one could predict from first principles that Newtonian forces should add as vectors. On the other hand, quantum mechanics is among the most rigorously tested theories in science, and the predictions of quantum mechanics have, so far, always been in agreement with experiment. In this chapter, we will present quantum mechanics as a series of postulates and examine their implications in application to simple one-dimensional systems. In the next chapter we will examine quantum effects in real systems including atoms, molecules, crystals, and artificially engineered nano-structures. Postulates of quantum mechanics QM Postulate 1: A quantum particle is described by a wave function Ψ( x , y , z , t ) which is a function of spatial coordinates and time. All physically determinable quantities can be derived from the wave function Ψ( x , y , z , t ) ; quantities which cannot be found from the wave function are not physically meaningful. Note that some things that one could ask about a quantum particle, for example the exact position and simultaneous exact momentum of a particle, are not derivable from the wave function and are therefore considered indeterminate (or uncertain ). These are things which cannot ever be known about a particle, and, as such, they are meaningless to contemplate.
Abstract The events that led to the formulation of the laws of quantum mechanics are presented. Quantum revolution took place in two phases. In the first phase, three important developments took place. Max Planck explained the radiation emitted by heated objects via a quantum postulate, Albert Einstein explained the emission of electrons when light shines on metals by treating light as consisting of photons, and Niels Bohr developed a model for the hydrogen atom by invoking a quantum postulate. In the second phase, Heisenberg and Schrödinger formulated the laws of quantum mechanics that could not only explain all the known phenomena but predict many others.
From the outset, Heisenberg had resolved to eliminate classical space-time pictures involving particles and waves from the quantum mechanics of the atom. He had wanted to focus instead on the properties actually observed and recorded in laboratory experiments, such as the positions and intensities of spectral lines. Alone in Copenhagen in February 1927, he now pondered on the significance and meaning of such experimental observables. Feeling the need to introduce at least some form of ‘visualizability’, he asked himself some fundamental questions, such as: What do we actually mean when we talk about the position of an electron? He went on to discover the uncertainty principle: the product of the ‘uncertainties’ in certain pairs of variables—called complementary variables—such as position and momentum cannot be smaller than Planck’s constant h (now h / 4π).
We have seen in the previous chapter how useful wave mechanics can be in solving physical problems. But wave mechanics has several limitations. It describes physical states by means of wave functions, which are functions of the positions of the particles of the system, but why should we single out position as the fundamental physical observable? For instance, we might want to describe states in terms of probability amplitudes for particles to have certain values of the momentum or energy rather than the position. A more fundamental limitation is that there are attributes of physical systems that cannot be described at all in terms of the positions and momenta of a set of particles. One of these attributes is spin , which will be a chief subject of Chapter 4. Another is the value of the electric or magnetic field at some point in space, treated in Chapter 11. This chapter will describe the principles of quantum mechanics in a formalism which is essentially the “transformation theory” of Dirac, mentioned briefly in Section 1.4. This formalism generalizes both the wave mechanics of Schrödinger and the matrix mechanics of Heisenberg, and is sufficiently comprehensive to apply to any sort of physical system. States The first postulate of quantum mechanics is that physical states can be represented as vectors in a sort of abstract space known as Hilbert space . Before getting into Hilbert space, I need to say a bit about vectors in general. In kindergarten we learn that vectors are quantities with both magnitude and direction. Later, when we study analytic geometry, we learn instead to describe a vector in d dimensions as a string of d numbers, the components of the vector. The latter approach lends itself well to calculation, but in some respects the kindergarten version is better, because it allows us to describe relations among vectors without specifying a coordinate system. For instance, a statement that one vector is parallel to a second vector, or perpendicular to a third, has nothing to do with how we choose our coordinate system. Here we will formulate what we mean by vector spaces in general, and Hilbert space in particular, in a way that is independent of the coordinates we use to describe directions in these spaces.