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Journal of Experimental and Theoretical Physics

Direct observation of nuclear magnetic resonance in a rotating coordinate system

Anatoly E. Mefed, Vadim A. Atsarkin

Published Feb 1, 1978• 2 citations
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Composite Pulses (CPs) are widely used in Nuclear Magnetic Resonance (NMR), optical spectroscopy, optimal control experiments and quantum computing to manipulate systems that are well-described by a two-level Hamiltonian. A careful design of these pulses can allow the refocusing of an ensemble at a desired state, even if the ensemble experiences imperfections in the magnitude of the external field or resonance offsets. Since the introduction of CPs, several theoretical justifications for their robustness have been suggested. In this work, we suggest another justification based on the classical mechanical concept of a stability matrix. The motion on the Bloch Sphere is mapped to a canonical system of coordinates and the focusing of an ensemble corresponds to caustics, or the vanishing of an appropriate stability matrix element in the canonical coordinates. Our approach highlights the directionality of the refocusing of the ensemble on the Bloch Sphere, revealing how different ensembles refocus along different directions. The approach also clarifies when CPs can induce a change in the width of the ensemble as opposed to simply a rotation of the axes. As a case study, we investigate the $90(x)180(y)90(x)$ CP introduced by Levitt, where the approach provides a new perspective into why this CP is effective.

arXiv:2507.01364•Jul 2, 2025•0 citations
A model of an optical pumping nuclear magnetic resonance system rotating in a plane parallel to the quantization axis is presented. Different coordinate frames for nuclear spin polarization vector are introduced, and theoretical calculation is conducted to analyze this model. We demonstrate that when the optical pumping nuclear magnetic resonance system rotates in a plane parallel to the quantization axis, it will maintain a steady state with respect to the quantization axis which is independent of rotational speed and direction.
The components of spinors corresponding to half integral spin value transform under rotation of the spatial coordinate system with a matrix of even dimensionality. This leads to a state function phase factor with period 4π rad in the rotation angle. A spectroscopic interference experiment to observe such phase factors is described in analogy with double-beam interferometry. The experiment is performed with the techniques of high resolution nuclear magnetic resonance spectroscopy and the rotational symmetry of composite spin [Formula: see text], 1, and [Formula: see text] particles is explored by calculation and observation. Side effects relating to inhomogeneity dephasing and relaxation are evident in the experimental recordings, but they are discussed only briefly. A relation is established between the spectroscopic interference experiment and earlier "spin tickling" experiments.
Composite Pulses (CPs) are widely used in Nuclear Magnetic Resonance (NMR), optical spectroscopy, optimal control experiments and quantum computing to manipulate systems that are well-described by a two-level Hamiltonian. A careful design of these pulses can allow the refocusing of an ensemble at a desired state, even if the ensemble experiences imperfections in the magnitude of the external field or resonance offsets. Since the introduction of CPs, several theoretical justifications for their robustness have been suggested. In this work, we suggest another justification based on the classical mechanical concept of a stability matrix. The motion on the Bloch Sphere is mapped to a canonical system of coordinates and the focusing of an ensemble corresponds to caustics, or the vanishing of an appropriate stability matrix element in the canonical coordinates. Our approach highlights the directionality of the refocusing of the ensemble on the Bloch Sphere, revealing how different ensembles refocus along different directions. The approach also clarifies when CPs can induce a change in the width of the ensemble as opposed to simply a rotation of the axes. As a case study, we investigate the 90(x)180(y)90(x)90(x)180(y)90(x)90(x)180(y)90(x) CP introduced by Levitt, where the approach provides a new perspective into why this CP is effective.