An ``amplitude model'' of the laser-rf double-resonance process has been quantitatively verified, providing a complete explanation of the anomalous line shapes observed in studies of
Na2 hyperfine structure. We find excellent agreement with new laser-rf double-resonance measurements in low-J'' rotational levels of the
X1${\ensuremath{\Sigma}}_{g}^{+}$(v''=0) ground state of
Na2 as well as with earlier data for J''=28. These results confirm the idea that absorption and stimulated-emission Rabi cycles in the presence of the laser field create coherence between the ground-state hyperfine levels when these levels are optically unresolved. A novel ground-state ``quantum beat'' experiment is proposed.
The lowest Rb metastable autoionizing level has been identified by a rf resonance measurement of the g factors of the various hyperfine sublevels. Of the two lowest-lying metastable state assignments,
4p5(2P)5s5p(3P)4D27 and
4p54d(3F)5s4F29, only components of the
4D27 were observed in the metastable beam. The atomic-beam resonance method employed resembles traditional methods except that it exploits the differential metastability of the fine-structure levels instead of magnetic deflection for state selection.