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THERMODYNAMIC POTENTIAL OF THE BOSE GAS

Nizom Taylanov, S Kh Urinov, Bahodir Narimanov, Abduxoliq Urazov

Published Mar 15, 2021• 0 citations
OpenAlex

Abstract

In this paper we investigated and the dependence of the chemical potential on temperature in the vicinity of and below the transition Bose condensation. It should be noted that below the Bose condensation chemical potential has microscopic order. It was shown that below bose condensation point chemical potential is inversely proportional to the number of condensate particles.

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In this paper we investigated and the dependence of the chemical potential on temperature in the vicinity of and below the transition Bose condensation. It should be noted that below the Bose condensation chemical potential has microscopic order. It was shown that below bose condensation point chemical potential is inversely proportional to the number of condensate particles.
In this paper, first of all, we proved if the ideal Bose gas with a finite volume and number of particles has a non-degenerate single-particle energy level n, the chemical potential μ can take the value μn = n and there is a phase transition temperature Tp,n, where n = 0,1,2 Taking 0 ≤ n Tp,n+1. When the temperature T > Tp,n or T ≤ Tp,n+1, μ # n and the most probable occupation number Nn = 0. In the temperature interval Tp,n ≥ T > Tp,n+1, μ = n and 0 ≤ Nn = N - NjsupNn, where Nj is the most probable occupation number in the degenerate level j. Thus, if the finite ideal Bose gas has some non-degenerate single-particle levels, there exists a characteristic temperature Tp = Tp,0. The chemical potential μ is quantized when T ≤ Tp, and this leads to the creation of a macroscopic quantum state (pure state) or Bose-Einstein condensation phase. Tp = Tp,0 is a first-order phase transition point, Tp,n#0 is a zero-order phase transition point. Next, we obtained a new expression of the most probable distribution of the finite ideal Bose gas. In this expression Nj is directly proportional to gj - 1, where gj and Nj are, respectively, the degeneracy and the most probable occupation number in the degenerate level j. This property agrees with what chemical potential can be quantized if there is a non-degenerate level for the finite ideal Bose gas. Finally, using this expression, we defined a micro-partition function M, obtained the statistical expressions of some thermodynamical quantities.
The partition function of a dilute Bose gas with repulsive interaction, fixed number of particles and in the presence of a condensate is computed up to first order in the interactions. An equilibrium condition appears for the fraction of particles in the condensate and the chemical potential of the particles. We show that for a dilute gas the Bose–Einstein transition is not of second order. Moreover, the thermodynamical quantities obtained may look different from those in the literature, because the chemical potential enters in a nontrivial way in the quasi particle spectrum.
Bose system of zero spin particles is considered in the presence of the Bose–Einstein condensate in the vicinity of the phase transition point. The system is investigated in the framework of the Bogolyubov model with the separated condensate. In this model an effective Hamiltonian of the system is introduced by replacing condensate creation and annihilation operators in system Hamiltonian by n01/2 where n0 is occupation number of the condensate state. According to Bogolyubov, the grand canonical thermodynamic potential related to the effective Hamiltonian is considered as nonequilibrium thermodynamic potential. In the present paper this potential is investigated as a function of the small variable n0. With the help of the thermodynamic perturbation theory it is shown that it is expanded in a series over integer powers of n0. This corresponds to the basic idea of the Landau theory of the phase transitions of the second kind. Coefficients at terms of the first and second orders in n0 in the expansion are calculated for Bose gas in the main approximation in small interaction. Calculation of the coefficients at terms of the third and fourth orders needs accounting contributions of the thermodynamic perturbation theory at least of the 4th order and will be done elsewhere. It is established that the results obtained for Bose gas do not fit into the Landau theory of phase transitions of the second kind. Some comments that discuss the situation are given.
Abstract We study thermodynamic properties of weakly interacting Bose gases above the transition temperature of Bose–Einstein condensation in the framework of a thermodynamic perturbation theory. Cases of local and non-local interactions between particles are analyzed both analytically and numerically. We obtain and compare the temperature dependencies for the chemical potential, entropy, pressure, and specific heat to those of noninteracting gases. The results set reliable benchmarks for thermodynamic characteristics and their asymptotic behavior in dilute atomic and molecular Bose gases above the transition temperature.
The chemical potential and its differential coefficients as a function of temperature of an ideal system trapped in three dimensions isotropic harmonic traps with an finite number of particles were calcu- lated from the statistical theory.The results show that,there is no phase transition in a system with an finite number of particles,but the Bose-Einstein condensation occurs at a finite temperature.The critical temperatures were well defined by the minimum temperatures of the second derivative of chemical potential, which were in good agreement with the experimental results.