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Journal of Lanzhou University

Numerical calculation of finite Bose-Einstein condensation in harmonic potentials

Zhan Liu

Published Jan 1, 2008• 0 citations
OpenAlex

Abstract

The chemical potential and its differential coefficients as a function of temperature of an ideal system trapped in three dimensions isotropic harmonic traps with an finite number of particles were calcu- lated from the statistical theory.The results show that,there is no phase transition in a system with an finite number of particles,but the Bose-Einstein condensation occurs at a finite temperature.The critical temperatures were well defined by the minimum temperatures of the second derivative of chemical potential, which were in good agreement with the experimental results.

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The chemical potential and its differential coefficients as a function of temperature of an ideal system trapped in three dimensions isotropic harmonic traps with an finite number of particles were calcu- lated from the statistical theory.The results show that,there is no phase transition in a system with an finite number of particles,but the Bose-Einstein condensation occurs at a finite temperature.The critical temperatures were well defined by the minimum temperatures of the second derivative of chemical potential, which were in good agreement with the experimental results.
We study the thermodynamic behavior of an ideal gas of bosons trapped in a three-dimensional anisotropic harmonic-oscillator potential. The condensate fraction as well as the specific heat is calculated using the Euler-Maclaurin approximation. For a finite number of particles there is no phase transition, but there is a well-defined temperature at which the condensation starts. We also consider condensation in lower dimensions, and, for one-dimensional systems, we discuss the dependence of the condensate fraction and heat capacity on the ensemble used.
We consider a finite number of noninteracting bosons trapped in an isotropic three-dimensional harmonic oscillator. Using the grand canonical ensemble, we calculate the heat capacity of the system as a function of temperature, for several values of the number of particles. We find that a new definition of critical temperature is necessary for a finite number of trapped particles, and present a definition that is experimentally convenient and in good agreement with a recent definition given by W. Ketterle and N. J. van Druten [Phys. Rev. A 54, 656 (1996)].
Bose-Einstein condensation (BEC) of an ideal gas is investigated for a finite number of particles. In three dimensions, we find a transition temperature which is lower than in the thermodynamic limit. Lowering the dimension increases the transition temperature and is therefore favorable for BEC. This is in contrast to the standard result obtained in the thermodynamic limit which states that BEC is not possible in, e.g., a one-dimensional (1D) harmonic potential. As a result, 1D atom traps, such as radially tightly confining magnetic traps or optical dipole traps, are promising for studying BEC. \textcopyright{} 1996 The American Physical Society.
Abstract We have proposed an analytical solution to the problem of Bose–Einstein condensation (BEC) of harmonically trapped, two-dimensional, and ideal atoms. It is found that the number of atoms in vapor is characterized by an analytical function, which involves a series of q -digamma functions in mathematics. We employ the analytical solution to calculate the internal energy E , the entropy S , the Helmholtz free energy F , and the heat capacity at constant number C N of ideal Bose atoms in a two-dimensional isotropic harmonic trap. The first main finding in this paper is that the variation with temperature of the internal energy of a finite number of ideal Bose atoms has an inflection point, which occurs at the transition temperature T c . The second main finding is that the internal energy of a finite number of ideal Bose atoms has a classic limit E = 2 N k B T as T ≫ T c . The third main finding is that the variation with temperature of the heat capacity of a finite number of ideal Bose atoms has a maximal value, which occurs at T c . The fourth main finding is that the heat capacity of a finite number of ideal Bose atoms has a classic limit C N / k B = 2 N as T ≫ T c . The fifth main finding is that in the thermodynamic limit, at critical temperature T c the heat capacity at constant number shows a cusp singularity, which is analogous to the λ -transition of liquid helium. Consequently, the transition between normal and condensed states is a second-order phase transition.
We have investigated the thermodynamic behaviour of ideal Bose gases with an arbitrary number of particles confined in a harmonic potential. By taking into account the conservation of the total number N of particles and using a saddle-point approximation, we derive analytically the simple explicit expression of mean occupation number in any state of the finite system. The temperature dependence of the chemical potential, specific heat, and condensate fraction for the trapped finite-size Bose system is obtained numerically. We compare our results with the usual treatment which is based on the grand canonical ensemble. It is shown that there exists a considerable difference between them at sufficiently low temperatures, especially for the relative small numbers of Bose atoms. The finite-size scaling at the transition temperature for the harmonically trapped systems is also discussed. We find that the scaled condensate fractions for various system sizes and temperatures collapse onto a single scaled form.
By defining the characteristic length, the boundary effects of Bose-Einstein condensation in a three-dimensional harmonic trap are investigated using the Euler-MacLaurin formula. Results show that the condensed fraction of particles reduces due to the finite-size effects and the effects of finite particle number; the corrections of the condensation fraction and the condensation temperature have, respectively, a maximum value due to the boundary effect, hence it is very effective to optimize the parameters of the harmonic traps for improving the condensation fraction and the condensation temperature. In the jump of heat capacity exist the boundary effects and the effects of finite particle number, and the jump of heat capacity has a minimum because the parameters of harmonic traps are selected to be reasonable. The equation of state is derived for a finite ideal Bose gas system in a three-dimensional harmonic trap; the anisotropy (or isotropy) of the pressure is determined by the anisotropy (or isotropy) of the frequency of the harmonic potential.