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Physical Review A

Effect of a finite number of particles in the Bose-Einstein condensation of a trapped gas

Reginaldo de Jesus Napolitano, Jayme De Luca, Vanderlei Salvador Bagnato, Gil C. Marques

Published May 1, 1997• 43 citations
Publisher

Abstract

We consider a finite number of noninteracting bosons trapped in an isotropic three-dimensional harmonic oscillator. Using the grand canonical ensemble, we calculate the heat capacity of the system as a function of temperature, for several values of the number of particles. We find that a new definition of critical temperature is necessary for a finite number of trapped particles, and present a definition that is experimentally convenient and in good agreement with a recent definition given by W. Ketterle and N. J. van Druten [Phys. Rev. A 54, 656 (1996)].

DOI
10.1103/physreva.55.3954

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We consider a finite number of noninteracting bosons trapped in an isotropic three-dimensional harmonic oscillator. Using the grand canonical ensemble, we calculate the heat capacity of the system as a function of temperature, for several values of the number of particles. We find that a new definition of critical temperature is necessary for a finite number of trapped particles, and present a definition that is experimentally convenient and in good agreement with a recent definition given by W. Ketterle and N. J. van Druten [Phys. Rev. A 54, 656 (1996)].
We study the thermodynamic behavior of an ideal gas of bosons trapped in a three-dimensional anisotropic harmonic-oscillator potential. The condensate fraction as well as the specific heat is calculated using the Euler-Maclaurin approximation. For a finite number of particles there is no phase transition, but there is a well-defined temperature at which the condensation starts. We also consider condensation in lower dimensions, and, for one-dimensional systems, we discuss the dependence of the condensate fraction and heat capacity on the ensemble used.
The chemical potential and its differential coefficients as a function of temperature of an ideal system trapped in three dimensions isotropic harmonic traps with an finite number of particles were calcu- lated from the statistical theory.The results show that,there is no phase transition in a system with an finite number of particles,but the Bose-Einstein condensation occurs at a finite temperature.The critical temperatures were well defined by the minimum temperatures of the second derivative of chemical potential, which were in good agreement with the experimental results.
Abstract We study Bose-Einstein condensation of comparatively small numbers of atoms trapped by a three-dimensional harmonic oscillator potential. Under the assumption that grand canonical statis­tics applies, we derive analytical expressions for the condensation temperature, the ground state occupation, and the specific heat capacity. For a gas of TV atoms the condensation temperature is proportional to N1/3, apart from a downward shift of order N-1/3. A signature of the condensation is a pronounced peak of the heat capacity. For not too small N the heat capacity is nearly discon­tinuous at the onset of condensation; the magnitude of the jump is about 6.6 N k. Our continuum approximations are derived with the help of the proper density of states which allows us to calculate finite-AT-corrections, and checked against numerical computations.
The onset of Bose-Einstein condensation in a sample of N atoms confined to harmonic traps is critically examined. The monotonic growth of the condensate fraction f and the nonmonotic variation of the specific heat C of the sample are studied in fine detail. While no temperature is truly critical, our analysis does provide a strong theoretical basis for recognizing a temperature T∗,{T}^{*},T∗, that has been identified and advocated by previous authors, as the transition temperature of the system. The specific-heat maximum Tm{T}_{m}Tm​ (which happens to be another important ``marker'' in this transition), the value of the specific heat at T=Tm,{T=T}_{m},T=Tm​, and the ``jump'' in the specific heat of the system when the number N becomes very large are all explicitly evaluated. Wherever comparison is possible, our analytical results are found to be in perfect agreement with the ones obtained numerically by Kirsten and Toms [Phys. Rev. A 54, 4188 (1996)] and by Haugerud, Haugest, and Ravndal [Phys. Lett. A 225, 18 (1997)].
This paper presents a study of the grand canonical Bose-Einstein (BE) statistics for a finite number of particles in an arbitrary quantum system. The thermodynamical quantities that identify BE condensation---namely, the fraction of particles in the ground state and the specific heat---are calculated here exactly in terms of temperature and fugacity. These calculations are complemented by a numerical calculation of fugacity in terms of the number of particles, without taking the thermodynamic limit. The main advantage of this approach is that it does not rely on approximations made in the vicinity of the usually defined critical temperature, rather it makes calculations with arbitrary precision possible, irrespective of temperature. Graphs for the calculated thermodynamical quantities are presented in comparison to the results previously obtained in the thermodynamic limit. In particular, it is observed that for the gas trapped in a three-dimensional box, the derivative of specific heat reaches smaller values than what was expected in the thermodynamic limit---here, this result is also verified with analytical calculations. This is an important result for understanding the role of the thermodynamic limit in phase transitions and makes possible to further study BE statistics without relying neither on the thermodynamic limit nor on approximations near critical temperature.
By defining the characteristic length, the boundary effects of Bose-Einstein condensation in a three-dimensional harmonic trap are investigated using the Euler-MacLaurin formula. Results show that the condensed fraction of particles reduces due to the finite-size effects and the effects of finite particle number; the corrections of the condensation fraction and the condensation temperature have, respectively, a maximum value due to the boundary effect, hence it is very effective to optimize the parameters of the harmonic traps for improving the condensation fraction and the condensation temperature. In the jump of heat capacity exist the boundary effects and the effects of finite particle number, and the jump of heat capacity has a minimum because the parameters of harmonic traps are selected to be reasonable. The equation of state is derived for a finite ideal Bose gas system in a three-dimensional harmonic trap; the anisotropy (or isotropy) of the pressure is determined by the anisotropy (or isotropy) of the frequency of the harmonic potential.