Efficient extraction of photons coming from solid-state spin systems is one of the main challenges when aiming to increase the size and complexity of quantum information protocols using these type of systems. An example of this is the read-out of photoluminescence from an NV centres in plain bulk diamond. Due to the refractive index contrast, only a fraction of the light coming from the defect can be collected. Several top-down fabrication strategies have been used in the past decade to fabricate structures such as lenses and cavities around NV centres in order to increase the extraction efficiency using bulk optics [1] . However to fully exploit the potential of color centres in diamond, integration with on-chip waveguides and cavities is necessary. Remarkable effort has been made to fabricate photonic structures on bulk diamond [2] yet the laborious diamond undercut methods and the reduced versatility of these top-down approaches limit the scope for scalability and integration.
Efficient extraction of photons coming from solid-state spin systems is one of the main challenges when aiming to increase the size and complexity of quantum information protocols using these type of systems. An example of this is the read-out of photoluminescence from an NV centres in plain bulk diamond. Due to the refractive index contrast, only a fraction of the light coming from the defect can be collected. Several top-down fabrication strategies have been used in the past decade to fabricate structures such as lenses and cavities around NV centres in order to increase the extraction efficiency using bulk optics [1] . However to fully exploit the potential of color centres in diamond, integration with on-chip waveguides and cavities is necessary. Remarkable effort has been made to fabricate photonic structures on bulk diamond [2] yet the laborious diamond undercut methods and the reduced versatility of these top-down approaches limit the scope for scalability and integration.
Luminescent lattice defects (so called “color centers”) in diamond provide a robust, solid-state architecture for exploring quantum optics, with many facilitating direct access to highly coherent electron and nuclear spins. The past two decades have seen tremendous advances in our ability to prepare and control the quantum states of these atom-like systems. For instance, demonstrations that leverage the diamond nitrogen vacancy (NV–) center as a spin-photon interface have included the generation of indistinguishable photons, a quantum bit memory exceeding 1 second, entanglement of two distance solid-state qubits, and deterministic long distance quantum teleportation. While diamond color centers are an attractive platform for scalable quantum information processing, the diamond solid-state matrix, by its very nature, inhibits efficient photon collection into either free-space or fiber-optical systems. Due to its large refractive index, emitted photons are inevitably trapped within the diamond crystal by total internal reflection, limiting count rates and overall scalability of information processing via quantum optical protocols. To this end, there has been significant progress towards integrating individual diamond color centers within well-defined radiation channels: namely, those provided by monolithic diamond nanophotonic networks. Currently, on-chip low loss (~ few db/cm) diamond waveguide networks are available, as well as key passive photonic elements like micron scale ring and disk resonators and photonic crystal cavities, with high optical quality (Q) factors. Specifically, we recently demonstrated a scalable ‘angled-etching’ nanofabrication method for realizing nanophotonic networks starting from bulk single-crystal diamond substrates (MJ Burek et al., Nano Letters 2012, MJ Burek et al., Nat Comm. 2014). Angled-etching employs anisotropic oxygen-based plasma etching at an oblique angle to the substrate surface, resulting in suspended optical structures with triangular cross-sections. Using this approach, we demonstrated high Q-factor (> 10^5) optical nanocavities fabricated in bulk single-crystal diamond, operating over a wide wavelength range (visible to telecom). Beyond isolated photonic devices, we have further developed free-standing angled-etched waveguides which efficiently route photons between diamond optical nanocavities, while maintaining physical support through attachment to the bulk substrate. Although on-chip diamond nanophotonics realized by angled-etching continue to mature, efficient off-chip optical coupling schemes which provide near seamless transition of photons on-chip into commercial optical fibers remain an outstanding challenge. This is especially pertinent in applications involving single photons, such as quantum optics with diamond color centers. Herein, we demonstrate a high efficiency fiber-optical interface with aforementioned on-chip diamond nanophotonic networks, achieving > 90% power coupling at both telecom and visible wavelengths. The coupling scheme utilizes a single mode optical fiber, with one end fabricated into a conical taper, to adiabatically transition guided light between on-chip tapered diamond waveguides and off-chip optical fiber networks. Additionally, we develop techniques to robustly pigtail single-mode fibers with diamond waveguide couplers, yielding a packaged technology that may potentially enable deployment in harsh environments, including vacuum, sub-Kelvin cryogenics, or even liquid/biological environments. With these newly developed optical integration schemes, single-crystal diamond is now a viable integrated nanophotonics platform, servicing a range of applications, from non-linear optics and chemical sensing, to quantum science and cavity optomechanics.
Very recently, the interest for quantum technologies by the scientific community and industry has strongly increased. Different types of implementations have been proposed as a practical implementation for a quantum bit. In particular, quantum photonics is a strong candidate for such applications. We are interested in using single photons and single spins in diamond as a solid state host matrix (nanodiamonds or membranes). Integration of nanosources of light is currently a major bottleneck preventing the realisation of all-photonic chips for quantum technologies and nanophotonics applications. Ideally, one needs optical circuitry, on-chip photodetection and on-chip generation of quantum states of light (single photons, entangled photons…). Our recent work on a new platform for quantum photonics using integrated optics can offer an easier and robust way to create compact quantum circuits that can be on chip and scalable. In this context, the coupling between waveguides and single photon emitters is critical. The goal of our research is to efficiently couple single photon emitters with a new platform made of optical glass waveguides. These waveguides are based on the so-called ion-exchange glass technology and is know in the photonics industry for quite some time but has never been used in the context of quantum technologies. Efficient light-matter interface is of primordial importance in this system. To achieve this goal, several paths are undertaken such as the use of dielectric and plasmonic structuration in order to increase the light interaction with the waveguide or to develop fabrication techniques to insert the emitters directly inside the guide (for nanodiamonds). We will show what is our current state of the art for placing single emitters at the right place on our optical waveguides made of ion-exchange in glass and in particular what can be done to improve our first promising results in order to get near unity coupling between the optical bus and single photon emitters. We will show first results with semiconductor nanocrystals (NCs) but also using nitrogen-vacancy and silicon-vacancy defects in nanodiamond. The very first step in of our approach consists in the design of the structured waveguide using electromagnetic FDTD. We demonstrated that it is possible to achieve more than 90% coupling. In practice, before using coloured centres in diamond, we started working with CdSe/ZnS semiconductor nanocrystals. So far, we use straight waveguides defined to be single modes at the nominal wavelength of the emission line of the nanoemitters. The positioning of nanoemitters is still a challenge to be achieved. We developed an original technique based on photopolymerisation of light where the nanocrystals are grafted into a light sensitive polymer and can be placed at adequate positions.
Nitrogen-vacancy (NV) centres are exceptional solid-state quantum sensors with optically addressable spins. With room-temperature operability and biocompatibility, functionalised NV centres in nanodiamonds facilitate atomic-scale tracking and real-time monitoring of physical and chemical properties within living systems [1]. Conventionally, these systems work by addressing stochastically-positioned defects with a complex bulk-optic microscope [2] or using a single scanning probe, limited in scalability and the ability to capture spatial and temporal information simultaneously.
Very recently, the interest for quantum technologies by the scientific community and industry has strongly increased. Different types of implementations have been proposed as a practical implementation for a quantum bit as trapped atoms, superconducting qubits and single photons. In particular, we are interested in using single photons and single spins in solid state host matrices such as diamond (nanodiamonds or membranes). Integration of nanosources of light is currently a major bottleneck preventing the realisation of all-photonic chips for quantum technologies and nanophotonics applications. Nanophotonics and integrated optics are vast growing fields with huge market potentials in particular for quantum technologies. Ideally, one needs optical circuitry, on-chip photodetection and on-chip generation of quantum states of light (single photons, entangled photons…). We want to present our recent work on using integrated optics that can offer an easier and robust way to create fixed and compact quantum circuits that can be on chip and scalable. In this context, the coupling between waveguides and single photon emitters is critical. The goal of our research is to efficiently couple single photon emitters with a new platform made of optical glass waveguides. To achieve this goal, several paths are undertaken such as the use of dielectric and plasmonic structuration in order to increase the light interaction with the waveguide or to develop fabrication techniques to insert the emitters directly inside the guide (for nanodiamonds). We will show what is our current state of the art for placing single emitters at the right place on our optical waveguides made of ion-exchange in glass and in particular what can be done to improve our first promising results in order to get near unity coupling between the optical bus and single photon emitters. We will show first results with semiconductor nanocrystals (NCs) but also using nitrogen-vacancy defects in diamond either under nanodiamond form or in thin membranes.
A quantumnetwork would allow the distribution of a quantum state over many spatially separated quantum nodes which individually possess the ability to generate, process and store quantum information. Connecting these nodes through quantum communication channels would enable sending quantum information over arbitrarily long distances, secret key distribution with guaranteed secure communication and distributed quantum computing. An appealing platform for implementation of quantum networks is the nitrogen-vacancy (NV) center in diamond. An NV center is an optically active defect in diamond created by the substitution of two adjacent carbon atoms in the diamond crystal matrix by a nitrogen atom and a neighboring vacancy. The NV center fits remarkably well in the described quantum network framework. Its electronic spin can be optically initialized, read out in a single shot, coherently manipulated and coupled to the nearby carbon-13 nuclear spins. These properties represent necessary ingredients of a multi-qubit quantum node. The possibility of the entanglement between the state of the NV center spin and a photon establishes a photonic quantum link which can enable the entanglement of the quantum nodes, forming a quantum network. First building blocks of the proposed quantum networks based on NV centers were demonstrated by performing entanglement between two distant NV centers separated by more than a kilometer. However, the current success rate of the entangling protocols is greatly reduced due to the low emission probability of the NV center photons into the resonant zero phonon line (ZPL) and the inefficient photon extraction from the diamond. This is the central problem which prevents promoting our experiments beyond proof-of-principle demonstration towards practical implementation of the proposed quantumnetworks. The goal of this thesis is tackling these issues by coupling NV centers to optical cavities which would greatly increase the rate of generation and collection of the ZPL photons through themechanism of Purcell enhancement. The design and the fabrication of the components constituting a diamond-basedFabry-Perot microcavity, as used in this thesis, are described in Chapter 4. For large enhancement of the NV center resonant emission, a low cavity mode volume is necessary. This is achieved by inserting a micrometers thin diamond slab into the cavity architecture; we present the fabrication details of such samples. Chapter 5 describes the fabrication of an integrated platform for microwave signal delivery to the NV centers within a diamond membrane in the cavity architecture. Microwave striplines and arrays of unique markers are embedded in the mirror onto which the diamond is bonded. We investigate the mirror optical properties post fabrication and find that the fabrication method preserves the mirror optical performance. We describe the diamond bonding method and demonstrate addressing of the NV center spin. In Chapter 6 we probe the properties of the cavity with the embedded diamond membrane through measurements of the cavity finesse. We investigate the cavity finesse dependence on length, mode structure and temperature. We further explore the operation at cryogenic temperatures by probing the effect of cryostation vibration on the cavity linewidth. Finally, in Chapter 7 we discuss ways of improving the existing experimental capabilities, outline the first steps for demonstrating enhancement of the NV center resonant emission and suggest future experiments that can be performed with this system. We conclude that coupling of the NV centers to the cavities developed in this research could lead to an increase of remote entanglement success rates by more than three orders of magnitude.
The nitrogen-vacancy defect in diamond (NV centre) is a leading candidate for solid-state implementations of quantum information technologies. Among other useful properties, it is a bright source of single photons. It is difficult, though, to collect the emitted photons in a single spatial and spectral mode which is often needed for quantum information applications. One way to improve the single-mode collection efficiency is to embed an NV centre in a high-finesse cavity. The coupling of the NV centre dipole to the cavity mode gives rise to the Purcell enhancement -- an increase of the emission into the cavity's spectral and spatial mode.
The goal of this project will be to develop a fibre-based microcavity and to use it for the observation of enhanced single-photon emission from a diamond nanocrystal. It will involve a wide range of experimental techniques, for example basic optics (particularly Gaussian beam propagation), CO2 laser ablation, surface analysis by optical and atomic force microscopes, interferometry, photon counting, etc. There will also be a certain amount of data analysis, simulations and theoretical calculations.