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PERIÓDICO TCHÊ QUÍMICA

EFFECT OF A BARRIER ON ENERGY EIGENVALUE OF THE NONRELATIVISTIC (SCHRÖDINGER EQUATION) AND SOME EXPECTATION VALUES OF COMBINED POTENTIALS

C. A. Onate, M. C. Onyeaju, Abimbola Abolarinwa, Joshua Otonritse OKORO

Published Dec 20, 2020• 0 citations
Publisher

Abstract

Schrödinger equation was proposed in theoretical physics to provide information and the behavior of a system of particles. The Schrödinger equation was recently solved for a combination of different potentials using different traditional methodologies. The studies do not consider the effect of a barrier between the potentials. In reality, the barrier between the potentials has an effect on the energy eigenvalues. In the present work, a Kratzer-Mie-type potential, a combination of Kratzer and Mie-type-constant potentials, was proposed as the interacting potential. The solutions of the radial Schrödinger equation was obtained in the presence of the combined potentials by considering a barrier between the potentials. The energy equation and the corresponding wave functions were explicitly calculated. The calculations were performed by using the methodology of supersymmetric quantum mechanics. This method involves the proposition of superpotential function as a solution to its Riccati differential equation. Numerical results were generated for some diatomic molecules using the energy equation and the diatomic model parameters. Some expectation values for the combined potential were calculated using Hellmann Feynman Theorem, and the effect of the barrier on the expectation values were numerically studied. It was observed that when a particle moves from the lower end to a higher end of a barrier, it absorbs energy from the system for some time. This same behavior was also noted when the particle penetrates through a barrier. Thus, its vibration will only depend on the initial energy, which is absorbed. It was equally seen that as the width of the barrier becomes larger than the height, the energy of the system decreases drastically.

DOI
10.52571/ptq.v17.n36.2020.661_periodico36_pgs_646_661.pdf

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Schrödinger equation was proposed in theoretical physics to provide information and the behavior of a system of particles. The Schrödinger equation was recently solved for a combination of different potentials using different traditional methodologies. The studies do not consider the effect of a barrier between the potentials. In reality, the barrier between the potentials has an effect on the energy eigenvalues. In the present work, a Kratzer-Mie-type potential, a combination of Kratzer and Mie-type-constant potentials, was proposed as the interacting potential. The solutions of the radial Schrödinger equation was obtained in the presence of the combined potentials by considering a barrier between the potentials. The energy equation and the corresponding wave functions were explicitly calculated. The calculations were performed by using the methodology of supersymmetric quantum mechanics. This method involves the proposition of superpotential function as a solution to its Riccati differential equation. Numerical results were generated for some diatomic molecules using the energy equation and the diatomic model parameters. Some expectation values for the combined potential were calculated using Hellmann Feynman Theorem, and the effect of the barrier on the expectation values were numerically studied. It was observed that when a particle moves from the lower end to a higher end of a barrier, it absorbs energy from the system for some time. This same behavior was also noted when the particle penetrates through a barrier. Thus, its vibration will only depend on the initial energy, which is absorbed. It was equally seen that as the width of the barrier becomes larger than the height, the energy of the system decreases drastically.
The solutions of the radial Schrödinger equation for a pseudoharmonic potential and Kratzer potentials has been studied separately in the past. The Kratzer potential despite different reports, the basic theoretic quantity such as Fisher information has not been reported. In this study, the solution of the radial Schrödinger equation for the combination of the pseudoharmonic and Kratzer potentials in the presence of a constant-dependent potential is obtained using the concepts and formalism of the supersymmetric and shape invariance approach. The position expectation value and momentum expectation value are calculated employing the Hellmann-Feynman Theory. The expectation values are used to calculate the Fisher information for both the position and momentum spaces in both the absence and presence of the constant-dependent potential. The obtained results revealed that the presence of the constant-dependent potential leads to an increase in the energy eigenvalue, as well as in the position and momentum expectation values. The presence of the constant-dependent potential also increases the Fisher information for both position and momentum spaces. Furthermore, the product of the position expectation value and the momentum expectation value along with the product of the Fisher information, satisfies both the Fisher’s inequality and the Cramer-Rao’s inequality.
Abstract The equation of Schrodinger is a fundamental mathematical framework used to clarify the motion of the wave form, which is a phenomenon in the field of quantum physics. A method's wave function contains the complete description of its particles. The computational solution of the Schrodinger problem is a multifaceted problem. The eigenvalues and typical functions of the modified Kratzer plus Hulthen potential were ascertained analytically in this study. This study used an estimating approach that Nikiforov-Uvarov functional analysis had suggested for dealing with the problem. Estimating energy spectra and applying the results to certain specific diatomic molecules was the aim. The excellent results obtained from this strategy were confirmed by comparing our eigenvalue data with additional numerical data that was gathered by other researchers.
The solutions of the Schrodinger equation was investigated in space-times with nonspherical topology in the presence of the linear combination of modified Woods–Saxon and Eckart potentials. The variable mass and Supersymmetric Quantum Mechanics method were used to solve the Schrodinger equation in toroidal coordinate. This solution was used to obtain the nonrelativistic energy eigenvalue and the wave function of the system. Using the proper super potential to deal with the hyperbolic form of the effective potential, the Schrodinger equation in the radial direction part was solved analytically for modified Woods–Saxon plus Eckart potentials. The energy eigenvalue and the un-normalised ground state wave function equations were obtained. The results showed that the energy value depends on the quantum number, the parameters of potentials, and variable separation constants.
Abstract The equation of Schrodinger is a fundamental mathematical framework used to clarify the motion of the wave form, which is a phenomenon in the field of quantum physics. A method's wave function contains the complete description of its particles. The computational solution of the Schrodinger problem is a multifaceted problem. The eigenvalues and typical functions of the modified Kratzer plus Hulthen potential were ascertained analytically in this study. This study used an estimating approach that Nikiforov-Uvarov functional analysis had suggested for dealing with the problem. Estimating energy spectra and applying the results to certain specific diatomic molecules was the aim. The excellent results obtained from this strategy were confirmed by comparing our eigenvalue data with additional numerical data that was gathered by other researchers.
In some molecules such as ammonia, double vibrations are observed at small energies. These small vibrations are thought to arise from double well potentials. To explain these small energy gaps, double potential wells are investigated, and complex calculations are made. Until recently, since the exact solution of the Schrödinger equation was not known, approximate solutions were always obtained. The exact solution of the Schrödinger equation is now known. In previous studies, a simple procedure for the general solution of the radial Schrödinger Equation has been found for spherical symmetric potentials without making any approximation. In this article, the Schrodinger equation was solved with this new solution method. It has been applied to the oscillations through a barrier tunneling potential for a particle in a central quadratic deformed potential well (double potential well). It is seen that there is no need to look for complex potentials to explain the double wells observed in small vibrations in ammonia and similar molecules, they were compared with experimentally measured energies. The results were found to be fully compatible. It has been seen that there can always be double well potentials at small energies for all molecules, atomic nuclei, and similar particles with angular momentum other than zero.