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Gapless excitations in Kitaev materials with defects

Lucas R. D. Freitas

Published Mar 26, 2021• 0 citations
OpenAlex

Abstract

A quantum spin liquid is a magnetic phase of matter that is remarkable for its ground state long-range entanglement and fractional excitations. A quantum spin liquid appears in the well-known Kitaev honeycomb spin-half model. In a magnetic field, there is a phase transition to a topological phase with an energy gap in the bulk and chiral Majorana fermions at the edge. However, recent nuclear magnetic resonance experiments suggest excitations without a gap in this phase, signalled by the cubic temperature dependence of the spin-lattice relaxation rate at low temperatures. In this work, I propose a mechanism to account for this experimental result. I use the localization of chiral Majorana modes in defects to explain the presence of gapless modes in the bulk. Treating the weak interaction between the chiral modes in the defects within a mean-field approximation, I find that these modes remain gapless when the interaction is below a critical value that depends on the magnetic field strength. I used the effective low-energy theory to calculate the spin-lattice relaxation rate and found a behavior that agrees with the experimental result.

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arXiv:2511.19409•Physical Review Letters•Apr 28, 2026•0 citations
A quantum spin liquid is a magnetic phase of matter that is remarkable for its ground state long-range entanglement and fractional excitations. A quantum spin liquid appears in the well-known Kitaev honeycomb spin-half model. In a magnetic field, there is a phase transition to a topological phase with an energy gap in the bulk and chiral Majorana fermions at the edge. However, recent nuclear magnetic resonance experiments suggest excitations without a gap in this phase, signalled by the cubic temperature dependence of the spin-lattice relaxation rate at low temperatures. In this work, I propose a mechanism to account for this experimental result. I use the localization of chiral Majorana modes in defects to explain the presence of gapless modes in the bulk. Treating the weak interaction between the chiral modes in the defects within a mean-field approximation, I find that these modes remain gapless when the interaction is below a critical value that depends on the magnetic field strength. I used the effective low-energy theory to calculate the spin-lattice relaxation rate and found a behavior that agrees with the experimental result.
We show that line defects in a non-Abelian Kitaev spin liquid harbor gapless one-dimensional Majorana modes if the interaction across the defect falls below a critical value. Treating the weak interaction at the line defect within a mean-field approximation, we determine the critical interaction strength as a function of the external magnetic field. In the gapless regime, we use the low-energy effective field theory to calculate the spin-lattice relaxation rate for a nuclear spin near the defect and find a cubic temperature dependence that agrees with experiments in the Kitaev material $\ensuremath{\alpha}{\text{-RuCl}}_{3}$.
We show that line defects in a non-Abelian Kitaev spin liquid harbor gapless one-dimensional Majorana modes if the interaction across the defect falls below a critical value. Treating the weak interaction at the line defect within a mean-field approximation, we determine the critical interaction strength as a function of the external magnetic field. In the gapless regime, we use the low-energy effective field theory to calculate the spin-lattice relaxation rate for a nuclear spin near the defect and find a cubic temperature dependence that agrees with experiments in the Kitaev material α-RuCl3\alpha\text{-RuCl}_3α-RuCl3​.
A Kitaev quantum spin liquid involves fractionalized quasiparticles called itinerant Majorana fermions and localized gauge fluxes. The topological character with chiral excitations under a magnetic field is currently in an active debate. For a candidate spin liquid $\ensuremath{\alpha}\text{\ensuremath{-}}{\mathrm{RuCl}}_{3}$, we report low-energy spin excitations through nuclear magnetic and quadrupole resonance measurements down to temperatures three orders of magnitude lower than the exchange energy. In a field-driven disordered state, we found the evolution of two kinds of gapped spin excitations with distinct field dependences. The result is indicative of a field-induced hybridization between fractionalized quasiparticles, as inferred by the perturbation theory for the Kitaev model. The detailed field dependence of spin dynamics across the quantum critical region shows the emergence of a gapless intermediate phase between the gapped zigzag order phase and spin-disordered phases.
Kitaev's model of spins interacting on a honeycomb lattice describes a quantum spin liquid, where an emergent static Z2{\mathbb{Z}}_{2}Z2​ gauge field is coupled to Majorana fermions. In the presence of an external magnetic field and for a range of interaction strengths, the system behaves as a gapped, non-Abelian quantum spin liquid. In this phase, the vortex excitations of the emergent Z2{\mathbb{Z}}_{2}Z2​ gauge field have Majorana zero modes bound to them. Motivated by recent experimental progress in measuring and characterizing real materials that could exhibit spin-liquid behavior, we analytically calculate the dynamical spin structure factor in the non-Abelian phase of the Kitaev's honeycomb model. In particular, we treat the case of quenched disorder in the vortex configurations. Our calculations reveal a peak in the low-energy dynamical structure factor that is a signature of the spin-liquid behavior. We map the effective Hamiltonian to that of a chiral ppp-wave superconductor by using the Jordan-Wigner transformation. Subsequently, we analytically calculate the wave functions of the Majorana zero modes, the energy splitting for finite separation of the vortices and, finally, the dynamical structure factor in presence of quenched disorder.
We study quantum phase transitions in the honeycomb Kitaev model under a magnetic field, focusing on the topological nature of Majorana fermion excitations. We find a gapless phase between the low-field gapless quantum spin liquid and the high-field gapped forced-ferromagnetic state for the antiferromagnetic Kitaev model in the [001] field by using the Majorana mean-field theory, in conjunction with the exact diagonalization and the spin-wave theory supporting the validity of this approach. The transition between the two gapless phases is driven by a topological change of the Majorana spectrum---line node formation interconnecting two Majorana cones. The peculiar change of the Majorana band topology is rationalized by a sign change of the effective Kitaev coupling by the magnetic field, which does not occur in the ferromagnetic Kitaev case. Upon tilting the magnetic field away from [001], the two gapless phases become gapped and topologically nontrivial, characterized by nonzero Chern numbers with different signs. The sign change of the Chern number leads to a reversal of the thermal edge current in the half-quantized thermal Hall effect.
We study the spin-1/2 Kitaev honeycomb gapless spin liquid in the presence of Stone-Wales-type local lattice defects with odd-sided plaquettes. While the clean Kitaev model has no finite-temperature phase transitions, we find that introducing a finite defect density n_{d}≈10^{-4}-10^{-2} produces a true phase transition with a sizeable T_{c}≈2n_{d} in units of the Kitaev exchange. The resulting non-Abelian chiral quantum spin liquid exhibits scalar spin chirality and electron orbital magnetization which peak near lattice defects. This disorder-driven instability relies on an emergent long range ferromagnetic interaction r^{-γ} (γ≈2.7) between defect chiralities, mediated by the nearly gapless fermions, with implications for topology generation in Dirac cones with fluctuating mass terms.