Abstract In crystalline magnets, interaction randomness is usually thought as a negative factor preventing interesting quantum phenomena to occur. However, intriguing interplay between randomness and quantumness can also leads to unique phenomena in the strongly correlated materials. Among others, the random transverse-field Ising spin chain (RTIC) hosts a renowned quantum Griffiths phase. Although the RTIC model has been regarded as a toy model for long, here we materialize this model with the compound PrTiNbO6, which has a disordered ground state with pronounced quantum fluctuations and continuous spin excitations. The observed anomalous spin dynamics of PrTiNbO6 can be accounted by the RTIC model with a consistent set of parameters determined from fitting the thermodynamic data, and it is ascribed to the quantum Griffiths rare regions in the system. Our results provide a concrete example of quantum Griffiths magnet, and offer an ideal experimental platform for investigating the dynamical properties of random many-body system.
Abstract In crystalline magnets, interaction randomness is usually thought as a negative factor preventing interesting quantum phenomena to occur. However, intriguing interplay between randomness and quantumness can also leads to unique phenomena in the strongly correlated materials. Among others, the random transverse-field Ising spin chain (RTIC) hosts a renowned quantum Griffiths phase. Although the RTIC model has been regarded as a toy model for long, here we materialize this model with the compound PrTiNbO6, which has a disordered ground state with pronounced quantum fluctuations and continuous spin excitations. The observed anomalous spin dynamics of PrTiNbO6 can be accounted by the RTIC model with a consistent set of parameters determined from fitting the thermodynamic data, and it is ascribed to the quantum Griffiths rare regions in the system. Our results provide a concrete example of quantum Griffiths magnet, and offer an ideal experimental platform for investigating the dynamical properties of random many-body system.
In many-body systems with quenched disorder, dynamical observables can be singular not only at the critical point, but in an extended region of the paramagnetic phase as well. These Griffiths singularities are due to rare regions, which are locally in the ordered phase and contribute to a large susceptibility. Here, we study the geometrical properties of rare regions in the transverse Ising model with dilution or with random couplings and transverse fields. In diluted models, the rare regions are percolation clusters, while in random models the ground state consists of a set of spin clusters, which are calculated by the strong disorder renormalization method. We consider the so called energy cluster, which has the smallest excitation energy and calculate its mass and linear extension in one-, two- and three-dimensions. Both average quantities are found to grow logarithmically with the linear size of the sample. Consequently, the energy clusters are not compact: for the diluted model they are isotropic and tree-like, while for the random model they are quasi-one-dimensional.
In random quantum magnets, like the random transverse Ising chain, low energy excitations are localized in rare regions and there are only weak correlations between them. It is an open question whether these correlations are relevant in the sense of the renormalization group. To answer this question, we calculate the distribution of the excitation energy of the random transverse Ising chain in the disordered Griffiths phase with high numerical precision by the strong disorder renormalization group method and---for shorter chains---by free-fermion techniques. Asymptotically, the two methods give identical results, which are well fitted by the Fr\'echet limit law of the extremes of independent and identically distributed random numbers. Considering the finite size corrections, the two numerical methods give very similar results, but these differ from the correction term for uncorrelated random variables, indicating that the weak correlations between low-energy excitations in random quantum magnets are relevant.
Rare events can have major effects on quantum matter. Extremely unlikely events cause certain physical properties to diverge to infinity near the quantum phase transition of the disordered Ising antiferromagnet in a transverse field, but destroy criticality of the clean system completely when a longitudinal component of the field is present. Using a tree tensor network renormalization group method combined with a novel matrix product operator representation, the authors detect signatures of rare events and determine the zero-temperature phase diagram of the disordered antiferromagnetic Ising chain in the presence of both longitudinal and transverse magnetic fields. The numerical technique used in this paper is generalizable to more complicated many-body systems and higher dimensions.
We study quantum phase transitions in transverse-field Ising spin chains in which the couplings are random but hyperuniform, in the sense that their large-scale fluctuations are suppressed. We construct a one-parameter family of disorder models in which long-wavelength fluctuations are increasingly suppressed as a parameter $\ensuremath{\alpha}$ is tuned. For $\ensuremath{\alpha}=0$, one recovers the familiar infinite-randomness critical point. For $0<\ensuremath{\alpha}<1$, we find a line of infinite-randomness critical points with continuously varying critical exponents; however, the Griffiths phases that flank the critical point at $\ensuremath{\alpha}=0$ are absent at any $\ensuremath{\alpha}>0$. When $\ensuremath{\alpha}>1$, randomness is a dangerously irrelevant perturbation at the clean Ising critical point, leading to a state we call the critical Ising insulator. In this state, thermodynamics and equilibrium correlation functions behave as in the clean system. However, all finite-energy excitations are localized, thermal transport vanishes, and autocorrelation functions remain finite in the long-time limit. We characterize this line of hyperuniform critical points using a combination of perturbation theory, renormalization-group methods, and exact diagonalization.
The Ising model in transverse magnetic field is perhaps the simplest quantum spin model, yet the elements of site disorder, random magnetic fields, and tunable quantum fluctuations permit a rich array of ground states, and the rare ability to emphasize their classical or quantum character. We briefly review in this chapter experimental results from chains to crystals of spins, with magnetic, glassy, and spin liquid ground states. Singlet Ground State Magnets In a crystalline lattice, the crystal fields often take a form such that the ground states of magnetic ions are singlets separated from the higher lying spin multiplets. Sufficiently strong magnetic dipolar or exchange couplings between different sites can mix the singlets with the multiplets enough so as to induce non-zero expectation values for the magnetic dipoles at individual sites. Examples of this phenomenon are generally found among metals and insulators based on rare earths. Such metals were a subject of extensive research in the 1960's and 1970's, and the book by MacKintosh and Jensen [408] gives an excellent account of both the data as well as mean field approaches. With respect to insulating materials, LiTbF 4 emerged as a model system in the 1970's. It is an example of an ideal Ising dipolar coupled ferromagnet; here the long-range nature of the dipolar interactions leads to an upper critical dimension [149] (at which mean field theory with logarithmic corrections calculable using RG methods becomes an exact description of thermal phase transitions) of three rather than four. LiTbF 4 belongs to the LiREF 4 isostructural series of ionic salts. Li and F carry valences +1 and −1 respectively, leaving RE, which can be any rare earth atom or the nonmagnetic element Y, with a valence of +3. Figure 14.1 shows the body-centered tetragonal crystal structure for the family.
The magnetic analog of the Grüneisen parameter, i.e., the magnetocaloric effect, is a valuable tool for studying field-tuned quantum phase transitions. We determine the magnetic Grüneisen parameter of the one-dimensional random transverse-field Ising model, focusing on its lowtemperature behavior at the exotic infinite-randomness quantum critical point and in the associated quantum Griffiths phases. 1 Introduction Zero-temperature quantum phase transitions are characterized by a competition between different quantum ground states. The resulting quantum fluctuations often cause unconventional behavior of thermodynamic and transport properties in the vicinity of the