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Symmetry

An Application of the Madelung Formalism for Dissipating and Decaying Systems

Maedeh Mollai, Seyed Majid Saberi Fathi

Published May 6, 2021• 11 citations
Publisher

Abstract

This paper is concerned with the modeling and analysis of quantum dissipation and diffusion phenomena in the Schrödinger picture. We derive and investigate in detail the Schrödinger-type equations accounting for dissipation and diffusion effects. From a mathematical viewpoint, this equation allows one to achieve and analyze all aspects of the quantum dissipative systems, regarding the wave equation, Hamilton–Jacobi and continuity equations. This simplification requires the performance of “the Madelung decomposition” of “the wave function”, which is rigorously attained under the general Lagrangian justification for this modification of quantum mechanics. It is proved that most of the important equations of dissipative quantum physics, such as convection-diffusion, Fokker–Planck and quantum Boltzmann, have a common origin and can be unified in one equation.

DOI
10.3390/sym13050812

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This paper is concerned with the modeling and analysis of quantum dissipation and diffusion phenomena in the Schrödinger picture. We derive and investigate in detail the Schrödinger-type equations accounting for dissipation and diffusion effects. From a mathematical viewpoint, this equation allows one to achieve and analyze all aspects of the quantum dissipative systems, regarding the wave equation, Hamilton–Jacobi and continuity equations. This simplification requires the performance of “the Madelung decomposition” of “the wave function”, which is rigorously attained under the general Lagrangian justification for this modification of quantum mechanics. It is proved that most of the important equations of dissipative quantum physics, such as convection-diffusion, Fokker–Planck and quantum Boltzmann, have a common origin and can be unified in one equation.
This paper is intended to provide the reader with a review of the authors’ latest results dealing with the modeling of quantum dissipation/diffusion effects at the level of Schrodinger systems, in connection with the corresponding phase space and fluid formulations of such kind of phenomena, especially in what concerns the role of the Fokker–Planck mechanism in the description of open quantum systems and the macroscopic dynamics associated with some viscous hydrodynamic models of Euler and Navier–Stokes type.
We formally derive two nonlinear Ginzburg-Landau type models starting from the Wigner-Fokker-Planck system, which rules the evolution of a quantum electron gas interacting with a heat bath in thermodynamic equilibrium. These models mainly consist of a quantum, dissipative O(Planck 3) hydrodynamic/O(Planck 4) stochastic correction to the frictional (Caldeira-Leggett-)Schrödinger equation. The main ingredient lies in the use of the hydrodynamic/stochastic fluid model approach associated with the quantum Fokker-Planck equation and the identification of the associated pressure field. Then, Madelung transformations set the problem in the Schrödinger picture of dissipative quantum mechanics. We also describe the stationary dynamics associated with both systems.
We give an example of a mathematical model describing quantum mechanical processes interacting with medium. As a model, we consider the process of heat scattering of a wave function defined on the phase space. We consider the case when the heat diffusion takes place only with respect to momenta. We state and study the corresponding modified Kramers equation for this process. We consider the consequent approximations to this equation in powers of the quantity inverse to the medium resistance per unit of mass of the particle in the process. The approximations are constructed similarly to statistical physics, where from the usual Kramers equation for the evolution of probability density of the Brownian motion of a particle in the phase space, one deduces an approximate description of this process by the Fokker--Planck equation for the density of probability distribution in the configuration space. We prove that the zero (invertible) approximation to our model with respect to the large parameter of the medium resistance, yields the usual quantum mechanical description by the Schrödinger equation with the standard Hamilton operator. We deduce the next approximation to the model with respect to the negative power of the medium resistance coefficient. As a result we obtain the modified Schrödinger equation taking into account dissipation of the process in the initial model.
It has been long known that a year after Schrodinger published his equation, Madelung also published a hydrodynamics version of Schrodinger equation. Quantum diffusion is studied via dissipative Madelung hydrodynamics. Initially the wave packet spreads ballistically, than passes for an instant through normal diffusion and later tends asymptotically to a sub‐diffusive law. In this paper we will review two different approaches, including Madelung hydrodynamics and also Bohm potential. Madelung formulation leads to diffusion interpretation, which after a generalization yields to Ermakov equation. Since Ermakov equation cannot be solved analytically, then we try to find out its solution with Mathematica package. It is our hope that these methods can be verified and compared with experimental data. But we admit that more researches are needed to fill all the missing details.
Following the method of classical mechanics, we calculate the action for Fourier heat conduction from the classical Hamilton-Jacobi equation. We can write a Schrödinger-type equation and we obtain its solution, the kernel by which we may introduce a kind of wave function. Mathematically, we follow Bohm's method introduced to quantum mechanics. The generalized Hamilton-Jacobi equation-which may be handled as a quantum-thermodynamical form-can be calculated. Irreversibility and dissipation are included in a natural way in the field theory of nonequilibrium thermodynamics, so in this way we obtain a quantum-thermodynamical approach of simple dissipative processes.
BACKGROUND: Sequel to the work on the quantization of nonconservative systems using fractional calculus and quantization of a system with Brownian motion, which aims to consider the dissipation effects in quantum-mechanical description of microscale systems. RESULTS: The canonical quantization of a system represented classically by one-dimensional Fick's law, and the diffusion equation is carried out according to the Dirac method. A suitable Lagrangian, and Hamiltonian, describing the diffusive system, are constructed and the Hamiltonian is transformed to Schrodinger's equation which is solved. An application regarding implementation of the developed mathematical method to the analysis of diffusion, osmosis, which is a biological application of the diffusion process, is carried out. Schrödinger's equation is solved. CONCLUSIONS: The plot of the probability function represents clearly the dissipative and drift forces and hence the osmosis, which agrees totally with the macro-scale view, or the classical-version osmosis.