A simple method is proposed to determine the quality of antirelaxation coatings of the walls of vacuum optical cells containing alkali metal vapors. The method involves recording the time dependence of the fluorescence intensity of alkali atoms during exposure of the cell by resonant radiation pulses. Theory predicts that to determine the coating quality, it is sufficient to know the fluorescence decay rate and the ratio of the fluorescence intensities at the beginning and end of the pulse laser.
It is important to evaluate the total spin angular momentum of alkali-metal atoms if the atoms serve as a reservoir of angular momenta. We use an absorption-monitoring technique to measure $\ensuremath{\langle}{F}_{z}\ensuremath{\rangle}$, i.e., the expectation values of the quantization (
z) axis components of the total angular momentum of Cs atoms in the electronic ground state in both uncoated and antirelaxation-coated vacuum cells at room temperature. Cs atoms are polarized via optical pumping and probed using their
D2 transitions. The probe laser frequency is varied across the Doppler-broadened
D2 transition; the $\ensuremath{\langle}{F}_{z}\ensuremath{\rangle}$ values are derived using the integrated absorption coefficients. The largest $\ensuremath{\langle}{F}_{z}\ensuremath{\rangle}$ is 2.5 for the coated cell. We then use a simple model of spin flow through vapor cells to estimate the atomic spin relaxation probabilities after a single surface collision.