The direction of time and the microcanonical ensemble

Starting from the quantum mechanics for $N$ particles, we show that we can directly derive the microcanonical ensemble average of the physical quantity $A$ by using only the long time average and the equal probability assumption for the equal energy states. The system is considered to be embedded in the outer world and we describe them in terms of the density matrix method.Starting from the quantum mechanics for $N$ particles, we show that we can directly derive the microcanonical ensemble average of the physical quantity $A$ by using only the long time average and the equal probability assumption for the equal energy states. The system is considered to be embedded in the outer world and we describe them in terms of the density matrix method.

arXiv:1307.0610Jul 2, 20130 citations

Derivation and improvements of the quantum canonical ensemble from a regularized microcanonical ensemble

Jani Lukkarinen

We develop a regularization of the quantum microcanonical ensemble, called a Gaussian ensemble, which can be used for derivation of the canonical ensemble from microcanonical principles. The derivation differs from the usual methods by giving an explanation for the, at the first sight unreasonable, effectiveness of the canonical ensemble when applied to certain small, isolated, systems. This method also allows a direct identification between the parameters of the microcanonical and the canonical ensemble and it yields simple indicators and rigorous bounds for the effectiveness of the approximation. Finally, we derive an asymptotic expansion of the microcanonical corrections to the canonical ensemble for those systems, which are near, but not quite, at the thermodynamical limit and show how and why the canonical ensemble can be applied also for systems with an exponentially increasing density of states. The aim throughout the paper is to keep mathematical rigour intact while attempting to produce results which are both physically and practically interesting.We develop a regularization of the quantum microcanonical ensemble, called a Gaussian ensemble, which can be used for derivation of the canonical ensemble from microcanonical principles. The derivation differs from the usual methods by giving an explanation for the, at the first sight unreasonable, effectiveness of the canonical ensemble when applied to certain small, isolated, systems. This method also allows a direct identification between the parameters of the microcanonical and the canonical ensemble and it yields simple indicators and rigorous bounds for the effectiveness of the approximation. Finally, we derive an asymptotic expansion of the microcanonical corrections to the canonical ensemble for those systems, which are near, but not quite, at the thermodynamical limit and show how and why the canonical ensemble can be applied also for systems with an exponentially increasing density of states. The aim throughout the paper is to keep mathematical rigour intact while attempting to produce results which are both physically and practically interesting.

arXiv:cond-mat/9809102Journal of Physics A Mathematical and GeneralJan 1, 19998 citations

The Constrained Origin of Canonical and Microcanonical Ensembles in Quantum Theory

Loris Di Cairano

In quantum theory, equilibrium statistical mechanics is usually formulated through the canonical ensemble, whose privileged status is tied to the Euclidean continuation of time evolution. The microcanonical ensemble, by contrast, is commonly introduced as a separate spectral construction. In this work we show that this asymmetry is representational rather than structural. We formulate the system in an extended Hilbert space in which time is promoted to an auxiliary clock degree of freedom and physical states are selected by a reparametrization-invariant constraint operator $\hat C = \hat P_T + \hat H$ . The corresponding projector $δ(\hat C)$ provides a single unified object from which both canonical and microcanonical ensembles emerge as complementary projections in the clock sector. In the clock-time representation, a purely imaginary clock separation yields the Euclidean kernel and the canonical partition function. In the conjugate clock-energy representation, the same projector reduces to the spectral operator $δ(\hat H-E)$ and hence to the microcanonical density of states. The main consequence is structural: canonical and microcanonical statistics need not be introduced as independent constructions, since both are already encoded in the same constrained quantum dynamics.In quantum theory, equilibrium statistical mechanics is usually formulated through the canonical ensemble, whose privileged status is tied to the Euclidean continuation of time evolution. The microcanonical ensemble, by contrast, is commonly introduced as a separate spectral construction. In this work we show that this asymmetry is representational rather than structural. We formulate the system in an extended Hilbert space in which time is promoted to an auxiliary clock degree of freedom and physical states are selected by a reparametrization-invariant constraint operator $\hat C = \hat P_T + \hat H$. The corresponding projector $δ(\hat C)$ provides a single unified object from which both canonical and microcanonical ensembles emerge as complementary projections in the clock sector. In the clock-time representation, a purely imaginary clock separation yields the Euclidean kernel and the canonical partition function. In the conjugate clock-energy representation, the same projector reduces to the spectral operator $δ(\hat H-E)$ and hence to the microcanonical density of states. The main consequence is structural: canonical and microcanonical statistics need not be introduced as independent constructions, since both are already encoded in the same constrained quantum dynamics.

quant-pharXiv:2603.12148Mar 13, 20260 citations

The Nature and Structure of Time

J. G. Cramer

Springer eBooksDec 23, 20153 citations

The Direction of Time

O. Penrose

Lecture notes in physicsJan 1, 20013 citations

Starting from the quantum mechanics for

N

particles, we show that we can directly derive the microcanonical ensemble average of the physical quantity

A

by using only the long time average and the equal probability assumption for the equal energy states. The system is considered to be embedded in the outer world and we describe them in terms of the density matrix method.

\hat C = \hat P_T + \hat H

. The corresponding projector

δ(\hat C)

provides a single unified object from which both canonical and microcanonical ensembles emerge as complementary projections in the clock sector. In the clock-time representation, a purely imaginary clock separation yields the Euclidean kernel and the canonical partition function. In the conjugate clock-energy representation, the same projector reduces to the spectral operator

δ(\hat H-E)

and hence to the microcanonical density of states. The main consequence is structural: canonical and microcanonical statistics need not be introduced as independent constructions, since both are already encoded in the same constrained quantum dynamics.