A path integral approach has been generalized for the non-relativistic electron charge transfer processes. The charge transfer - the capture of an electron by an ion passing another atom or more generally the problem of rearrangement collisions is formulated in terms of influence functionals. It has been shown that the electron charge transfer process can be treated either as electron transition problem or as elastic scattering of ion and atom in the some effective potential field. The first-order Born approximation for the electron charge transfer cross section has been reproduced to prove the adequacy of the path integral approach for this problem.
A path integral approach has been generalized for the non-relativistic electron charge transfer processes. The charge transfer- the capture of an electron by an ion passing another atom, or more generally the problem of rearrangement collisions is formulated in terms of influence functionals. It has been shown that the electron charge transfer process can be treated either as electron transition problem or as elastic scattering of ion and atom in the some effective potential field. The first-order Born approximation for the electron charge transfer cross section has been reproduced to prove the adequacy of the path integral approach for this problem. PACS number(s): 03.65.Db, 03.65.Nk, 34.70.+e 1
With reference to recent progress in preparing slow and intense Rb beams (rubidium atomic funnel and low-velocity intense source of atoms from a magneto-optical trap) we have calculated total and differential elastic scattering cross sections and scattering lengths for ground-state collisions of
85Rb as well as
87Rb. Our results are based on the state of the art ${X}^{1}{\ensuremath{\Sigma}}_{g}^{+}$ and $a{}^{3}{\ensuremath{\Sigma}}_{u}^{+}$ potentials. Pronounced resonances in the total scattering cross sections occur for collision velocities below 15 m/s. We propose scattering experiments with slow Rb beams in order to check the currently known singlet and triplet potential-energy curves.