Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

The state dependence of integrated, instantaneous, and fluctuating entropy production in quantum and classical processes.

Artemy Kolchinsky, David H. Wolpert

Published Mar 9, 2021• 0 citations
OpenAlex

Abstract

Given a fixed physical process, we consider the entropy production (EP) incurred by some initial state $\rho$, additional to the minimal EP incurred by the least-dissipative state $\varphi$. We show that this additional EP has a universal information-theoretic form, given by the contraction of the relative entropy between $\rho$ and $\varphi$ over time. This result holds for total integrated EP, instantaneous EP rate, and fluctuating EP. We derive novel bounds on EP, analyze the thermodynamics of quantum error correction, and propose a thermodynamically-motivated measure of the logical irreversibility of a channel.

Related papers

Dependence of integrated, instantaneous, and fluctuating entropy production on the initial state in quantum and classical processes

Artemy Kolchinsky, David H. Wolpert

We consider the additional entropy production (EP) incurred by a fixed quantum or classical process on some initial state ρ, above the minimum EP incurred by the same process on any initial state. We show that this additional EP, which we term the "mismatch cost of ρ," has a universal information-theoretic form: it is given by the contraction of the relative entropy between ρ and the least-dissipative initial state φ over time. We derive versions of this result for integrated EP incurred over the course of a process, for trajectory-level fluctuating EP, and for instantaneous EP rate. We also show that mismatch cost for fluctuating EP obeys an integral fluctuation theorem. Our results demonstrate a fundamental relationship between thermodynamic irreversibility (generation of EP) and logical irreversibility (inability to know the initial state corresponding to a given final state). We use this relationship to derive quantitative bounds on the thermodynamics of quantum error correction and to propose a thermodynamically operationalized measure of the logical irreversibility of a quantum channel. Our results hold for both finite- and infinite-dimensional systems, and generalize beyond EP to many other thermodynamic costs, including nonadiabatic EP, free-energy loss, and entropy gain.

arXiv:2103.05734•Physical review. E•Nov 9, 2021•16 citations

Initial-state dependence of thermodynamic dissipation for any quantum process

Paul M. Riechers, Mile Gu

Exact results about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales are obtained by considering all possible variations of initial conditions of a system. First we obtain a quantum-information theoretic equality for entropy production, valid for an arbitrary initial joint state of system and environment. For any finite-time process with a fixed initial environment, we then show that the system's loss of distinction-relative to the minimally dissipative state-exactly quantifies its thermodynamic dissipation. The quantum component of this dissipation is the change in coherence relative to the minimally dissipative state. Implications for quantum state preparation and local control are explored. For nonunitary processes-like the preparation of any particular quantum state-we find that mismatched expectations lead to divergent dissipation as the actual initial state becomes orthogonal to the anticipated one.

arXiv:2002.11425•Physical review. E•Apr 30, 2021•29 citations

Joint statistics of work and entropy production along quantum trajectories

Harry J. D. Miller, Majid Mohammady, Martí Perarnau-Llobet +1 more

In thermodynamics, entropy production and work quantify irreversibility and the consumption of useful energy, respectively, when a system is driven out of equilibrium. For quantum systems, these quantities can be identified at the stochastic level by unravelling the system's evolution in terms of quantum jump trajectories. We here derive a general formula for computing the joint statistics of work and entropy production in Markovian driven quantum systems, whose instantaneous steady states are of Gibbs form. If the driven system remains close to the instantaneous Gibbs state at all times, then we show that the corresponding two-variable cumulant generating function implies a joint detailed fluctuation theorem so long as detailed balance is satisfied. As a corollary, we derive a modified fluctuation-dissipation relation (FDR) for the entropy production alone, applicable to transitions between arbitrary steady states, and for systems that violate detailed balance. This FDR contains a term arising from genuinely quantum fluctuations, and extends an analogous relation from classical thermodynamics to the quantum regime.

arXiv:2011.11589•Physical review. E•May 27, 2021•24 citations

Conditional fluctuation theorems and entropy production for monitored quantum systems under imperfect detection

Mar Ferri-Cortés, José A. Almanza-Marrero, Rosa López +2 more

The thermodynamic behavior of Markovian open quantum systems can be described at the level of fluctuations by using continuous monitoring approaches. However, practical applications require assessing imperfect detection schemes, where the definition of main thermodynamic quantities becomes subtle and universal fluctuation relations are unknown. Here, we fill this gap by deriving a universal fluctuation relation that links thermodynamic entropy production and information-theoretical irreversibility along single trajectories in inefficient monitoring setups. This relation provides as a corollary an irreversibility estimator of dissipation using imperfect detection records that lower bounds the underlying entropy production at the level of visible trajectories. We illustrate our findings with a driven-dissipative two-level system following quantum jump trajectories and discuss the experimental applicability of our results for thermodynamic inference.

arXiv:2308.08491•Physical Review Research•Jan 21, 2025•10 citations

Non-Markovianity and negative entropy production rates

Philipp Strasberg, Massimiliano Esposito

Entropy production plays a fundamental role in nonequilibrium thermodynamics to quantify the irreversibility of open systems. Its positivity can be ensured for a wide class of setups, but the entropy production rate can become negative sometimes. This is often taken as an indicator of non-Markovianity. We make this link precise by showing under which conditions a negative entropy production rate implies non-Markovianity and when it does not. For a system coupled to a single heat bath, this can be established within a unified language for two setups: (i) the dynamics resulting from a coarse-grained description of a Markovian master equation and (ii) the classical Hamiltonian dynamics of a system coupled to a bath. The quantum version of the latter result is shown not to hold despite the fact that the integrated thermodynamic description is formally equivalent to the classical case. The instantaneous fixed point of a non-Markovian dynamics plays an important role in our study. Our key contribution is to provide a consistent theoretical framework to study the finite-time thermodynamics of a large class of dynamics with a precise link to its non-Markovianity.

arXiv:1806.09101•Physical review. E•Jan 14, 2019•116 citations

Single-atom verification of the information-theoretical bound of irreversibility at the quantum level

Jiawei Zhang, K. Rehan, Menghan Li +6 more

The quantitative measure of disorder or randomness based on the entropy production characterizes thermodynamical irreversibility, which is relevant to the conventional second law of thermodynamics.Here we report, in a quantum mechanical fashion, the first theoretical prediction and experimental exploration of an information-theoretical bound on the entropy production.Our theoretical model consists of a simplest two-level dissipative system driven by a purely classical field, and under the Markovian dissipation, we find that such an information-theoretical bound, not fully validating quantum relaxation processes, strongly depends on the drive-to-decay ratio and the initial state.Furthermore, we carry out experimental verification of this informationtheoretical bound by means of a single spin embedded in an ultracold trapped 40 Ca + ion.Our finding, based on a two-level model, is fundamental to any quantum thermodynamical process and indicates much difference and complexity in quantum thermodynamics with respect to the conventionally classical counterpart.

arXiv:2007.02027•Physical Review Research•Jul 16, 2020•15 citations
Given a fixed physical process, we consider the entropy production (EP) incurred by some initial state ρ\rhoρ, additional to the minimal EP incurred by the least-dissipative state φ\varphiφ. We show that this additional EP has a universal information-theoretic form, given by the contraction of the relative entropy between ρ\rhoρ and φ\varphiφ over time. This result holds for total integrated EP, instantaneous EP rate, and fluctuating EP. We derive novel bounds on EP, analyze the thermodynamics of quantum error correction, and propose a thermodynamically-motivated measure of the logical irreversibility of a channel.
We consider the additional entropy production (EP) incurred by a fixed quantum or classical process on some initial state ρ, above the minimum EP incurred by the same process on any initial state. We show that this additional EP, which we term the "mismatch cost of ρ," has a universal information-theoretic form: it is given by the contraction of the relative entropy between ρ and the least-dissipative initial state φ over time. We derive versions of this result for integrated EP incurred over the course of a process, for trajectory-level fluctuating EP, and for instantaneous EP rate. We also show that mismatch cost for fluctuating EP obeys an integral fluctuation theorem. Our results demonstrate a fundamental relationship between thermodynamic irreversibility (generation of EP) and logical irreversibility (inability to know the initial state corresponding to a given final state). We use this relationship to derive quantitative bounds on the thermodynamics of quantum error correction and to propose a thermodynamically operationalized measure of the logical irreversibility of a quantum channel. Our results hold for both finite- and infinite-dimensional systems, and generalize beyond EP to many other thermodynamic costs, including nonadiabatic EP, free-energy loss, and entropy gain.
Exact results about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales are obtained by considering all possible variations of initial conditions of a system. First we obtain a quantum-information theoretic equality for entropy production, valid for an arbitrary initial joint state of system and environment. For any finite-time process with a fixed initial environment, we then show that the system's loss of distinction-relative to the minimally dissipative state-exactly quantifies its thermodynamic dissipation. The quantum component of this dissipation is the change in coherence relative to the minimally dissipative state. Implications for quantum state preparation and local control are explored. For nonunitary processes-like the preparation of any particular quantum state-we find that mismatched expectations lead to divergent dissipation as the actual initial state becomes orthogonal to the anticipated one.
In thermodynamics, entropy production and work quantify irreversibility and the consumption of useful energy, respectively, when a system is driven out of equilibrium. For quantum systems, these quantities can be identified at the stochastic level by unravelling the system's evolution in terms of quantum jump trajectories. We here derive a general formula for computing the joint statistics of work and entropy production in Markovian driven quantum systems, whose instantaneous steady states are of Gibbs form. If the driven system remains close to the instantaneous Gibbs state at all times, then we show that the corresponding two-variable cumulant generating function implies a joint detailed fluctuation theorem so long as detailed balance is satisfied. As a corollary, we derive a modified fluctuation-dissipation relation (FDR) for the entropy production alone, applicable to transitions between arbitrary steady states, and for systems that violate detailed balance. This FDR contains a term arising from genuinely quantum fluctuations, and extends an analogous relation from classical thermodynamics to the quantum regime.
The thermodynamic behavior of Markovian open quantum systems can be described at the level of fluctuations by using continuous monitoring approaches. However, practical applications require assessing imperfect detection schemes, where the definition of main thermodynamic quantities becomes subtle and universal fluctuation relations are unknown. Here, we fill this gap by deriving a universal fluctuation relation that links thermodynamic entropy production and information-theoretical irreversibility along single trajectories in inefficient monitoring setups. This relation provides as a corollary an irreversibility estimator of dissipation using imperfect detection records that lower bounds the underlying entropy production at the level of visible trajectories. We illustrate our findings with a driven-dissipative two-level system following quantum jump trajectories and discuss the experimental applicability of our results for thermodynamic inference.
Entropy production plays a fundamental role in nonequilibrium thermodynamics to quantify the irreversibility of open systems. Its positivity can be ensured for a wide class of setups, but the entropy production rate can become negative sometimes. This is often taken as an indicator of non-Markovianity. We make this link precise by showing under which conditions a negative entropy production rate implies non-Markovianity and when it does not. For a system coupled to a single heat bath, this can be established within a unified language for two setups: (i) the dynamics resulting from a coarse-grained description of a Markovian master equation and (ii) the classical Hamiltonian dynamics of a system coupled to a bath. The quantum version of the latter result is shown not to hold despite the fact that the integrated thermodynamic description is formally equivalent to the classical case. The instantaneous fixed point of a non-Markovian dynamics plays an important role in our study. Our key contribution is to provide a consistent theoretical framework to study the finite-time thermodynamics of a large class of dynamics with a precise link to its non-Markovianity.
The quantitative measure of disorder or randomness based on the entropy production characterizes thermodynamical irreversibility, which is relevant to the conventional second law of thermodynamics.Here we report, in a quantum mechanical fashion, the first theoretical prediction and experimental exploration of an information-theoretical bound on the entropy production.Our theoretical model consists of a simplest two-level dissipative system driven by a purely classical field, and under the Markovian dissipation, we find that such an information-theoretical bound, not fully validating quantum relaxation processes, strongly depends on the drive-to-decay ratio and the initial state.Furthermore, we carry out experimental verification of this informationtheoretical bound by means of a single spin embedded in an ultracold trapped 40 Ca + ion.Our finding, based on a two-level model, is fundamental to any quantum thermodynamical process and indicates much difference and complexity in quantum thermodynamics with respect to the conventionally classical counterpart.