We illustrate the mathematical theory of entropy production in repeated quantum measurement processes developed in a previous work by studying examples of quantum instruments displaying various interesting phenomena and singularities. We emphasize the role of the thermodynamic formalism, and give many examples of quantum instruments whose resulting probability measures on the space of infinite sequences of outcomes (shift space) do not have the (weak) Gibbs property. We also discuss physically relevant examples where the entropy production rate satisfies a large deviation principle but fails to obey the central limit theorem and the fluctuation-dissipation theorem. Throughout the analysis, we explore the connections with other, a priori unrelated topics like functions of Markov chains, hidden Markov models, matrix products and number theory.
We illustrate the mathematical theory of entropy production in repeated quantum measurement processes developed in a previous work by studying examples of quantum instruments displaying various interesting phenomena and singularities. We emphasize the role of the thermodynamic formalism, and give many examples of quantum instruments whose resulting probability measures on the space of infinite sequences of outcomes (shift space) do not have the (weak) Gibbs property. We also discuss physically relevant examples where the entropy production rate satisfies a large deviation principle but fails to obey the central limit theorem and the fluctuation-dissipation theorem. Throughout the analysis, we explore the connections with other, a priori unrelated topics like functions of Markov chains, hidden Markov models, matrix products and number theory.
We analyze the production of entropy along nonequilibrium processes in quantum systems coupled to generic environments.First, we show that the entropy production due to final measurements and the loss of correlations obeys a fluctuation theorem in detailed and integral forms.Second, we discuss the decomposition of the entropy production into two positive contributions, adiabatic and nonadiabatic, based on the existence of invariant states of the local dynamics.Fluctuation theorems for both contributions hold only for evolutions verifying a specific condition of quantum origin.We illustrate our results with three relevant examples of quantum thermodynamic processes far from equilibrium.
Abstract The entropy production rate is a key quantity in nonequilibrium thermodynamics of both classical and quantum processes. No universal theory of entropy production is available to date, which hinders progress toward its full grasping. By using a phase space-based approach, here we take the current framework for the assessment of thermodynamic irreversibility all the way to quantum regimes by characterizing entropy production—and its rate—resulting from the continuous monitoring of a Gaussian system. This allows us to formulate a sharpened second law of thermodynamics that accounts for the measurement back action and information gain from a continuously monitored system. We illustrate our framework in a series of physically relevant examples.
Entropy production and the detailed fluctuation theorem are of fundamental importance for thermodynamic processes. In this paper we study the multiple entropy production for multitime quantum processes in a unified framework. For closed quantum systems and Markovian open quantum systems, the given entropy productions all satisfy the detailed fluctuation relation. This also shows that the entropy production rate under these processes is non-negative. For non-Markovian open quantum systems, the memory effect can lead to a negative-entropy production rate. Thus, in general, the entropy production of the marginal distribution does not satisfy the detailed fluctuation theorem relation. Our framework can be applied to a wide range of physical systems and dynamics. It provides a systematic tool for studying entropy production and its rate under arbitrary quantum processes.
Thermodynamics is a phenomenological theory describing the energy conversion of work and heat. At its origins thermodynamics was developed in order to understand and improve heat engines. In conventional thermodynamics, however, only such processes are completely describable which are slow enough to keep the system of interest in an equilibrium state with its thermal environment at all times. On the contrary, all real physical processes are accompanied by non-equilibrium phenomena. These are mathematically described with the help of the irreversible entropy production, i.e. the dissipated work divided by the temperature of the bath. The second law of thermodynamics merely states that the irreversible entropy production is on average always positive. The modern trend of miniaturization, however, leads to smaller and smaller devices. On short length scales thermal noise as well as quantum fluctuations become important. Thus, usual thermodynamic quantities as work and heat acquire stochastic nature. Moreover, in the quantum regime a completely new theory had to be invented, since classical notions of work and heat are no longer valid. The present dissertation contributes to this prevailing field by the derivation of analytical expressions for the entropy production in open and closed quantum system far from thermal equilibrium. The theoretical treatment is motivated by an experimental point of view. The obtained results were derived from the reduced dynamics of the quantum mechanical system, which may be coupled to a thermal bath. To this end, it was dealt with methods and approaches of statistical physics, conventional thermodynamics, quantum information theory and the theory of open quantum systems. In this dissertation the most important physical systems are treated. First, an isolated system is considered before later on a heat bath is included. The limit of weak as well as of strong coupling are analyzed in detail. For isolated systems it turns out that a geometric approach is able to capture the thermodynamic properties, completely. To this end, the irreversible entropy production is sharply estimated from below by the angle between the real non-equilibrium state and the corresponding equilibrium one. Further, it is shown that the Heisenberg uncertainty relation for energy and time can be formulated more precisely in terms of that angle. As experimental system cold ion traps are introduced, in which the theoretical predictions can be verified. For weakly coupled systems, then, the irreversible entropy production is identified and a fluctuation theorem is derived by merely thermodynamic arguments. As experimental system we, again, propose the cold ion traps, where the heat bath can be simulated with the help of LASER light. In the limit of strong coupling a semiclassical description of the reduced quantum system is discussed. Again, an analytically exact expression for the entropy production and the corresponding fluctuation theorem is derived. A physical system, in which strong coupling to the environment can be analyzed, is given by Josephson junctions. This dissertation discusses the entropy production for isolated, weakly coupled, and overdamped quantum systems. For these physical regimes analytical relation are derived and experimental systems proposed, with which the predictions can be verified.
The thermodynamics of quantum systems driven out of equilibrium has attracted increasing attention in the last decade, in connection with quantum information and statistical physics, and with a focus on non-classical signatures. While a first approach can deal with average thermodynamics quantities over ensembles, in order to establish the impact of quantum and environmental fluctuations during the evolution, a continuous quantum measurement of the open system is required. Here, we provide an introduction to the general theoretical framework to establish and interpret the thermodynamics for quantum systems whose nonequilibrium evolution is continuously monitored. We review the formalism of quantum trajectories and its consistent application to the thermodynamic scenario, where primary quantities such as work, heat, and entropy production can be defined at the stochastic level. The connection to irreversibility and fluctuation theorems is also discussed together with some recent developments, and we provide some simple examples to illustrate the general theoretical framework.
We continue the analysis of nontrivial examples of quantum Markov processes. This is done by applying the construction of entangled Markov chains obtained from classical Markov chains with infinite state–space. The formula giving the joint correlations arises from the corresponding classical formula by replacing the usual matrix multiplication by the Schur multiplication. In this way, we provide nontrivial examples of entangled Markov chains on , F being any infinite dimensional type I factor, J a finite interval of , and the bar the von Neumann tensor product between von Neumann algebras. We then have new nontrivial examples of quantum random walks which could play a rôle in quantum information theory. In view of applications to quantum statistical mechanics too, we see that the ergodic type of an entangled Markov chain is completely determined by the corresponding ergodic type of the underlying classical chain, provided that the latter admits an invariant probability distribution. This result parallels the corresponding one relative to the finite dimensional case. Finally, starting from random walks on discrete ICC groups, we exhibit examples of quantum Markov processes based on type II 1 von Neumann factors.