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arXiv:2112.02019 · AVS Quantum Science

Quantum thermodynamics under continuous monitoring: A general framework

Gonzalo Manzano, Roberta Zambrini

Published May 31, 2022• 61 citations
arXivHTMLPDF

Abstract

The thermodynamics of quantum systems driven out of equilibrium has attracted increasing attention in the last decade, in connection with quantum information and statistical physics, and with a focus on non-classical signatures. While a first approach can deal with average thermodynamics quantities over ensembles, in order to establish the impact of quantum and environmental fluctuations during the evolution, a continuous quantum measurement of the open system is required. Here, we provide an introduction to the general theoretical framework to establish and interpret the thermodynamics for quantum systems whose nonequilibrium evolution is continuously monitored. We review the formalism of quantum trajectories and its consistent application to the thermodynamic scenario, where primary quantities such as work, heat, and entropy production can be defined at the stochastic level. The connection to irreversibility and fluctuation theorems is also discussed together with some recent developments, and we provide some simple examples to illustrate the general theoretical framework.

DOI
10.1116/5.0079886

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The thermodynamics of quantum systems driven out of equilibrium has attracted increasing attention in the last decade, in connection with quantum information and statistical physics, and with a focus on non-classical signatures. While a first approach can deal with average thermodynamics quantities over ensembles, in order to establish the impact of quantum and environmental fluctuations during the evolution, a continuous quantum measurement of the open system is required. Here, we provide an introduction to the general theoretical framework to establish and interpret the thermodynamics for quantum systems whose nonequilibrium evolution is continuously monitored. We review the formalism of quantum trajectories and its consistent application to the thermodynamic scenario, where primary quantities such as work, heat, and entropy production can be defined at the stochastic level. The connection to irreversibility and fluctuation theorems is also discussed together with some recent developments, and we provide some simple examples to illustrate the general theoretical framework.
This article sets up a formalism to describe stochastic thermodynamics for driven out-of-equilibrium open quantum systems. A stochastic Schrödinger equation allows to construct quantum trajectories describing the dynamics of the system state vector in presence of an eventually monitored environment. Thermodynamic quantities are defined at the single quantum trajectory level, independently of any energy measurement, at any time of the protocol. We thereby identify coherent contributions, without classical counterparts, leading to quantum fluctuations of thermodynamic quantities. This formalism eventually leads to central fluctuation theorems for entropy, extending in the quantum regime results obtained in classical stochastic thermodynamics. The thermal imprint of coherences on a simple implementation of Jarzynski equality is investigated, opening avenues for a thermodynamic approach to decoherence.
Abstract The entropy production rate is a key quantity in nonequilibrium thermodynamics of both classical and quantum processes. No universal theory of entropy production is available to date, which hinders progress toward its full grasping. By using a phase space-based approach, here we take the current framework for the assessment of thermodynamic irreversibility all the way to quantum regimes by characterizing entropy production—and its rate—resulting from the continuous monitoring of a Gaussian system. This allows us to formulate a sharpened second law of thermodynamics that accounts for the measurement back action and information gain from a continuously monitored system. We illustrate our framework in a series of physically relevant examples.
We build a framework for the thermodynamics of macroscopic quantum systems. In contrast with approaches requiring access to the full density matrix, our framework relies on a coarse-grained description, based on measurement statistics of a few observables. When these observables commute, the outcomes define classical macrostates whose entropy is quantified by observational entropy, accounting for uncertainty about both the macrostate and the microstate within it. We extend this notion to non-commuting observables forming a subalgebra of the operator space, and use Jaynes' principle to define an algebra-dependent entropy interpolating between von Neumann and observational entropies. Given initial and final measurement sets, connected by internal and/or environment-induced dynamics, we derive a second law for the coarse-grained dynamics. Unlike formulations based on von Neumann entropy, our inequality captures irreversibility from both non-unitary environment-induced dynamics and internal equilibration. It takes the usual form of a positive entropy production when the system is initially at internal equilibrium, while correction terms capture nonequilibrium resources ignored by the coarse-graining. We also derive fluctuation theorems for coarse-grained thermodynamic quantities. Along a quasi-static path of measurement schemes, we identify quantum macroscopic notions of work and heat fulfilling the first and second laws, including an additional work contribution from manipulating the algebra to which the system is confined, through external constraints or quantum measurement backaction. Finally, we apply our framework to examples illustrating the impact of varying the coarse-graining scheme. Our approach unifies macroscopic and stochastic thermodynamics in a genuinely quantum framework, laying the basis for a versatile, experimentally friendly toolbox to analyze complex quantum dynamics.
The thermodynamic behavior of Markovian open quantum systems can be described at the level of fluctuations by using continuous monitoring approaches. However, practical applications require assessing imperfect detection schemes, where the definition of main thermodynamic quantities becomes subtle and universal fluctuation relations are unknown. Here, we fill this gap by deriving a universal fluctuation relation that links thermodynamic entropy production and information-theoretical irreversibility along single trajectories in inefficient monitoring setups. This relation provides as a corollary an irreversibility estimator of dissipation using imperfect detection records that lower bounds the underlying entropy production at the level of visible trajectories. We illustrate our findings with a driven-dissipative two-level system following quantum jump trajectories and discuss the experimental applicability of our results for thermodynamic inference.
A central open question in quantum thermodynamics is the identification of thermodynamic entropy away from equilibrium. Although thermodynamic entropy coincides with the von Neumann entropy for a Gibbs state at equilibrium, the thermodynamic role of quantum coherence generated during nonequilibrium evolution remains unclear. Here, we show that von Neumann entropy does not, in general, represent the thermodynamic entropy governing heat exchange in coherent nonequilibrium quantum systems. By integrating the resource theory of quantum coherence with thermodynamic principles, we develop a general framework for nonequilibrium quantum thermodynamics. We identify thermodynamic entropy with the energy entropy derived from energy-measurement statistics and introduce a dynamical temperature extending the equilibrium concept to nonequilibrium states. Consequently, we obtain an exact entropy-balance relation separating the entropy flux associated with heat exchange from the coherence-loss contribution to entropy production, establishing an operational connection between quantum coherence, heat flow, and total entropy change. Unlike approaches relying on equilibrium reference states or stationary Gibbs ensembles, our framework uses instantaneous dynamical quantities and remains valid throughout transient nonequilibrium evolution. It provides consistent dynamical definitions of temperature, work, heat, and free energy. Applying the formalism to an exactly solvable open quantum system, we show that the first and second laws hold throughout transient evolution and that equilibrium thermodynamics emerges dynamically in the weak-coupling long-time limit. Our results establish a unified framework for coherent nonequilibrium quantum thermodynamics and suggest opportunities for controlling heat dissipation through coherence engineering in quantum thermal technologies.
We propose an operational framework to study the nonequilibrium thermodynamics of a quantum system SSS that is coupled to a detector DDD whose state is continuously monitored, allowing us to single out individual quantum trajectories of SSS. We focus on detailed fluctuation theorems and characterize the entropy production of the system. We establish fundamental differences with respect to the thermodynamics of unmonitored, unitarily evolved systems. We consider the paradigmatic example of circuit QED, where superconducting qubits can be coupled to a continuously monitored resonator and show numerical simulations using state-of-the-art experimental parameters.