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Physics Essays

Alternative approach to time evolution of quantum systems

Mustafa Erol

Published Dec 3, 2020• 2 citations
Publisher

Abstract

This study focuses on the temporal evolution of quantum systems based on epistemological and ontological arguments and reconsiders some fundamental concepts of quantum theory. Initially, the time dependent Schrödinger wave equation (TDSWE) is criticized for the lack of a potential energy term and thereafter, a novel time dependent momentum operator is defined which eventually leads to an alternative TDSWE, including a potential energy term that remains in harmony with current theory. The wave nature is then generally examined by comparing time evolutions of classical and Schrödinger waves, dissimilarities then carefully inspected and ultimately a novel second order TDSWE is suggested. Finally, time evolution of the probability density is discussed in light of this new approach, and additionally some further insights and conclusions are briefly outlined that conform with the standard theory.

DOI
10.4006/0836-1398-33.4.358

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This study focuses on the temporal evolution of quantum systems based on epistemological and ontological arguments and reconsiders some fundamental concepts of quantum theory. Initially, the time dependent Schrödinger wave equation (TDSWE) is criticized for the lack of a potential energy term and thereafter, a novel time dependent momentum operator is defined which eventually leads to an alternative TDSWE, including a potential energy term that remains in harmony with current theory. The wave nature is then generally examined by comparing time evolutions of classical and Schrödinger waves, dissimilarities then carefully inspected and ultimately a novel second order TDSWE is suggested. Finally, time evolution of the probability density is discussed in light of this new approach, and additionally some further insights and conclusions are briefly outlined that conform with the standard theory.
In spite of outstanding achievement of the quantum theory, the theory is under never-ending judgment due to probabilistic character and certain unresolved paradoxes arising from the very fundamentals. Additionally, it is debated that a more sophisticated theory beyond the quantum theory emerges as a need for a better understanding of the atomic and sub atomic worlds. This paper, for that reason, focuses on the very fundamental structure of the quantum theory such as the physical and philosophical meanings of the wave functions, the probability and the Schrödinger Wave Equation (SWE). Specifically deals with the time evolution of the free quantum particles. The work just arises from the difference of the classical and quantum waves, specifically the comparison of the time and space dependence of classical waves and Schrödinger waves, for the free space, indicates that time dependence shows a clear dissimilarity. In order to tackle the problem, a time dependent momentum operator, for the first time, is defined and consequently an alternative TDSWE is straightforwardly derived and its philosophical implications have been discussed. Additionally, time and position dependence of the probability functions, relating free particles, have been physically and philosophically discussed and some alternative approaches and comments are forwarded. Finally, the approaches, comments and mathematical equations are in good agreement with the standard quantum theory and interestingly go further possibly tracing some signs of new pathways to resolve the mysterious quantum world. Keywords: Schrödinger wave equation, fundamentals of quantum mechanics, momentum operator, quantum probabilities, time evolution of quantum systems.
Time evaluation of wave functions for any quantum mechanical system/particle is essential nevertheless quantum mechanical counterpart of the time dependant classical wave equation does simply not appear. Epistemologically and ontologically considered time dependant momentum operator is initially defined and an Alternative Time Dependant Schrodinger Wave Equation (ATDSWE) is plainly derived. Consequent equation is primarily solved for the free particles, in a closed system, signifying a good agreement with the outcomes of the ordinary TDSWE. Free particle solution interestingly goes further possibly tracing some signs of new pathways to resolve the mysterious quantum world.
Present study focuses on some foundational problems of quantum theory specifically deals with the concept of probability density and relating introductory problems. In this sense, the work initially investigates the origins of the general probability theory and re-examines the concepts of spatial and temporal probability densities based on genuine epistemological and ontological arguments. In order to tackle the foundational problems, standard theory is primarily memorised and criticized scientifically and philosophically in terms of foundationally disappearing term of time dependent potential energy within the time and space dependent Schrödinger wave equation. Based on those arguments, the problematic inconsistency between the spatial and temporal probability density functions is underlined. Given the problem, an original approach previously suggested, is concisely described and extended to resolve the existing problem. The novel approach, based on a novel time dependent Schrödinger wave equation, resolves the discrepancy with the classical wave equation and also leads to time dependent temporal probability densities even for the time free potential energies. Novel temporal probability density function is also normalized and has a fluctuation period of around 10-16 s which is very short compared to the atomic time scales.
Abstract The second chapter introduces the notion of wave functions and their equation of motion proposed by Erwin Schrödinger. The interpretation and normalization of the wave function are discussed, leading to the continuity equation. The chapter also introduces basic mathematical operations that can be carried out for wave functions and operators, describing e.g., how to calculate scalar products and commutators, as well as expectation values and variances of observables. With these tools at hand, Heisenberg’s uncertainty principle is re-examined, focusing on the example of a Gaussian wave packet, which is studied both in position space and momentum space. We also discuss the time evolution of general states and of the exemplary wave packet. Finally, we will see how classical physics is recovered as a limiting case of the quantum-mechanical description
In this treatise I introduce the time dependent Generalized Born's Rule for the probabilities of quantum events, including conditional and consecutive probabilities, as the unique fundamental time evolution equation of quantum theory. Then these probabilities, computed from states and events, are to be compared with relative frequencies of observations. Schrodinger's equation still is valid in one model of the axioms of quantum theory, which I call the Schrodinger model. However, the role of Schrodinger's equation is auxiliary, since it serves to help compute the continuous temporal evolution of the probabilities given by the Generalized Born's Rule. In other models, such as the Heisenberg model, the auxiliary equations are quite different, but the Generalized Born's Rule is the same formula (covariance) and gives the same results (invariance). Also some aspects of the Schrodinger model are not found in the isomorphic Heisenberg model, and they therefore do not have any physical significance. One example of this is the infamous collapse of the quantum state. Other quantum phenomena, such as entanglement, are easy to analyze in terms of the Generalized Born's Rule without any reference to the unnecessary concept of collapse. Finally, this leads to the possibility of quantum theory with other sorts of auxiliary equations instead of Schrodinger's equation, and examples of this are given. Throughout this treatise the leit motif is the central importance of quantum probability and most especially of the simplifying role of the time dependent Generalized Born's Rule in quantum theory.
Explicitly time-dependent Hamiltonians are ubiquitous in applications of quantum theory. It is therefore necessary to solve the time-dependent Schrödinger equation directly. The system’s dynamics is associated with a unitary time-evolution operator (a propagator), formally given as an infinite Dyson series. Time-dependent observables are invariant under unitary time-dependent transformations, where it is sometimes useful to transform the time-evolution from the states into the corresponding operators. This is carried out in part (in full) by transforming to the interaction (Heisenberg) picture. The corresponding equations of motion for the time-dependent operators are introduced. For quadratic potential energy functions, the time evolution of quantum expectation values coincides with the corresponding classical dynamics. This is demonstrated and analyzed in detail for Gaussian wave packets and a coherent state. Finally, we derive exact and approximate expressions for time-dependent transition probabilities and transition rates between quantum states. The validity of time-dependent perturbation theory is analyzed by comparison to exact dynamics.