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Equilibration of isolated macroscopic quantum systems

Peter Reimann, Michael Kästner

Published Jan 1, 2012• 107 citations
OpenAlex

Abstract

We investigate the equilibration of an isolated macroscopic quantum system in the sense that deviations from a steady state become unmeasurably small for the overwhelming majority of times within any sufficiently large time interval. The main requirements are that the initial state, possibly far from equilibrium, exhibits a macroscopic population of at most one energy level and that degeneracies of energy eigenvalues and of energy gaps (differences of energy eigenvalues) are not of exceedingly large multiplicities. Our approach closely follows and extends recent works by Short and Farrelly (2012 New. J. Phys. 14 013063), in particular going beyond the realm of finite-dimensional systems and large effective dimensions.

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We investigate the equilibration of an isolated macroscopic quantum system in the sense that deviations from a steady state become unmeasurably small for the overwhelming majority of times within any sufficiently large time interval. The main requirements are that the initial state, possibly far from equilibrium, exhibits a macroscopic population of at most one energy level and that degeneracies of energy eigenvalues and of energy gaps (differences of energy eigenvalues) are not of exceedingly large multiplicities. Our approach closely follows and extends recent works by Short and Farrelly (2012 New. J. Phys. 14 013063), in particular going beyond the realm of finite-dimensional systems and large effective dimensions.
We investigate the equilibration of an isolated macroscopic quantum system in the sense that deviations from a steady state become unmeasurably small for the overwhelming majority of times within any sufficiently large time interval.The main requirements are that the initial state, possibly far from equilibrium, exhibits a macroscopic population of at most one energy level and that degeneracies of energy eigenvalues and of energy gaps (differences of energy eigenvalues) are not of exceedingly large multiplicities.Our approach closely follows and extends recent works by Short and Farrelly (2012 New.J. Phys.14 013063), in particular going beyond the realm of finite-dimensional systems and large effective dimensions.
In how far does a non-equilibrium initial ensemble evolve towards a stationary long time behavior for an isolated macroscopic quantum system?We demonstrate that deviations from a steady state indeed become unmeasurably small or exceedingly rare after initial transients have died out under the following conditions: the Hamiltonian does not exhibit exceedingly large degeneracies of energy eigenvalues and energy gaps.A large number of energy levels are significantly populated by the initial ensemble.The system is observed by a measurement device with a reasonably bound working range compared to the resolution limit.The entire experiment, ending in the quantum mechanical measurement process, can only be repeated a 'reasonable' number of times.It is argued that all these prerequisites for equilibration are fulfilled under many, if not all, experimentally realistic conditions.
It has recently been shown that small quantum subsystems generically equilibrate, in the sense that they spend most of the time close to a fixed equilibrium state. This relies on just two assumptions: that the state is spread over many different energies, and that the Hamiltonian has non-degenerate energy gaps. Given the same assumptions, it has also been shown that closed systems equilibrate with respect to realistic measurements. We extend these results in two important ways. Firstly, we prove equilibration over a finite (rather than infinite) time-interval, allowing us to bound the equilibration time. Secondly, we weaken the non-degenerate energy gaps condition, showing that equilibration occurs provided that no energy gap is hugely degenerate.
Quantum systems governed by unitary and reversible microscopic dynamics may nevertheless exhibit equilibration, in the sense that some effective description becomes time-independent. Standard equilibration results usually consider two separate situations: system-environment structures, in which the composite system evolves unitarily while the system of interest equilibrates, and restricted measurements, such as coarse-grained POVMs and observables, in which the measurement statistics equilibrate. Here, we bring these descriptions into a common state-level framework using the concept of generalized subsystems, where the accessible effective state appears as the output of a quantum channel acting on the microscopic state. We derive bounds showing that generalized subsystems equilibrate when their dimension is small compared with the effective dimension of the discarded microscopic information. We further show that this condition is met for typical initial states in large subspaces and that the resulting equilibrium description is largely insensitive to microscopic initial details. The framework recovers the usual equilibration bounds for ordinary subsystems and finite families of POVMs. As an example, we also introduce a finite-resolution energy channel that maps unresolved microscopic energy levels into effective energy levels, thereby making residual effective coherences explicit and showing how spectral multiplicities constrain those coherences while strengthening equilibration. Our results provide a unified state-level formulation of quantum equilibration under general forms of limited accessible information.
We discuss the approach toward equilibrium of an isolated quantum system. For a wide class of systems, in particular, for chaotic systems, we argue that the expectation value of a local operator averaged over a time interval of length TTT is bounded by the so-called deviation function, which characterizes maximal deviation from the equilibrium of all states with a given value of energy fluctuations. This result applies to any initial state with a well-defined effective temperature. We provide numerical evidence that the bound is approximately saturated by the initial configurations with spatial inhomogeneities at a macroscopic level. In this way the deviation function establishes an explicit connection between the macroscopically observed timescales associated with the transport and the properties of microscopic matrix elements. The form of the deviation function indicates that among the ``slowest'' states which saturate the bound there are also those with arbitrarily long equilibration times.
Understanding how macroscopic systems exhibit irreversible thermal behavior has been a longstanding challenge, first brought to prominence by Boltzmann. Recent advances have established rigorous conditions for isolated quantum systems to equilibrate to a maximum entropy state, contingent upon weak assumptions. These theorems, while powerful, applied for a sudden quench. However, natural processes involve finite-time perturbations or quenches, which raises a crucial question: Can these systems still equilibrate under more realistic, finite-time dynamics? In this work, we extend the established results to account for finite-time quenches, demonstrating that, even under finite-time perturbations, the system will equilibrate provided it populates many significant energy levels. While the mathematical proof is more intricate than in the instantaneous case, the physical conclusion remains the same: sufficient perturbation leads to equilibration. Our results provide a broader and more physically realistic framework for understanding thermalization in isolated quantum systems.