We have measured the lifetime of the
3P1 metastable state of Mg and obtained a value of 2.2 \ifmmode\pm\else\textpm\fi{} 0.2 msec. The level was excited with a dye laser tuned to the intercombination line ($3s3p^{3}P_{1}\ensuremath{\leftrightarrow}3{s}^{2}^{1}S_{0}$). In addition to the
3P1 state, the
3P2 and
3P0 levels were populated by mixing collisions owing to the presence of an inert buffer gas. The populations of all three metastable levels were monitored as a function of time by observing the absorption of Mg resonance radiation ($^{3}P_{0,1,2}\ensuremath{\rightarrow}^{3}S_{1}$) out of each level. The mixing time was short compared to the
3P1 lifetime, so that the populations of the three metastable levels were in thermal equilibrium with each other. This produced an apparent lengthening of the
3P1 lifetime, which would introduce a large systematic error if the degree of mixing were not known. Cenventionally, one observes the fluorescence from the excited levels to obtain their lifetimes. Because the lifetimes of the
3P2 and
3P0 states are too long, fluorescence from these states cannot be observed, and the observation of fluorescence from the
3P1 state alone provides insufficient information to determine its lifetime.
The lifetime of the metastable
3P1 state of Mg has been remeasured by a dye-laser excitation technique. The metastable state was populated by an intense pulse of 4571-\AA{} radiation from a flashlamp-pumped dye laser, and the decay of the population was monitored by observing the absorption of 5173-\AA{} resonance radiation from a Mg discharge lamp. The measured value for the
3P1 lifetime is 4.5 \ifmmode\pm\else\textpm\fi{} 0.5 msec.
A study of the 6/sup 3/P/sub 1/ level of isotope pairs of Mg by magnetic resonance methods leads to the determination of a coherence time'' which is much longer than the duration of the life of the level. At very low vapor densities, the coherence time'' approaches the level lifetime. Experimental resilts verified that the coherence time'' is dependent only on the number of diffusing atoms and on the obseved hypefiine level and that it approaches the level lifetime. (J.S.R.)