Quantum Physics of Light and Matter - Relativistic Wave Equations

Saviour Worlanyo Akuamoah, ALY RAMADAN SEADAWY, Dianchen Lu

In this paper, the energy and momentum operator substitution method derived from the Schrödinger equation is used to list all possible light and matter wave equations, among which the first light wave equation and relativistic approximation equation are proposed for the first time. We expect that we will have some practical application value. The negative sign pairing of energy and momentum operators are important characteristics of this paper. Then the Klein–Gordon equation and Dirac equation are introduced. The process of deriving relativistic energy–momentum relationship by undetermined coefficient method and establishing Dirac equation are mainly introduced. Dirac’s idea of treating negative energy in relativity into positrons is also discussed. Finally, the four-dimensional space-time representation of relativistic wave equation is introduced, which is usually the main representation of quantum electrodynamics and quantum field theory.

Eugene Paul Wigner

Ophelliam Loiselet

Quantum mechanics describes multi-electronic system by using non-relativistic probabilistic theories (non-relativistic many-body Hamiltonian, Bethe-Salpeter equation, Breit equation, density functional theory and so on).All of these theories are approximations and provide a probabilistic conception of quantum mechanics, which prevents it to be compatible with general relativity (or "macro scale" physics).Indeed, the real observable world (or Minkowski space) is for us a 3D+time space but quantum mechanics is expressed in multi-dimensional Hilbert space, which is not physical but purely mathematical.In this article we try to make a relativistic equation that gives a correct description of atomic physics in the real three-dimensional space for N ≥ 2 electrons systems: i.e a N-electrons Dirac equation.The starting point is to use the wave mechanics concept of De Broglie and Schrödinger: considering the electron as a mini oscillating cloud or matter-wave.For this we start from the Hartree equation, which gives already a 3D space description of each electron wave function.Then we jump into Hartree-Fock theory, that takes into account the electron exchange and can be also expressed in 3D, thanks to Slater-Condon rules.By extending the concept of exchange potential to a relativistic 4-exchange potential, and doing the same for the electron-electron repulsion potential, we have obtained a relativistic N electrons Dirac equation, in 3D+time space, including new relativistic interactions.The non-relativistic equivalence to Hartree-Fock equations will be demonstrated, which shows that the equation is already correct to describe light atoms.

Slobodan Danko Bosanac

Egidio Landi Degl’Innocenti

Isaac Shnaid

Principle of locality means that any local change (perturbation) of the stationary state wave function field propagates with finite speed, and therefore reaches distant regions of the field with time delay. If a one-particle or multi-particle non-relativistic quantum system is initially in a stationary state, and its wave function field is locally perturbed, then perturbed and non-perturbed sub-regions appear in the region. According to Schrödinger equation, borders of the perturbed sub-region propagate with infinite speed, and the perturbation instantaneously affects all infinite region. It means that Schrödinger equation predicts infinite speed of the wave function perturbations propagation. This feature of classical Schrödinger equation is traditionally interpreted as non-locality of quantum mechanics. From physical point of view, such mathematical behavior of Schrödinger equation solutions is questionable because it is difficult to accept that in real world infinite physical objects can instantaneously appear. We introduce a hypothesis that in reality speed of propagation of the perturbed sub-region borders is equal speed of light. On this basis we develop and analyze a finite propagation speed concept for non-relativistic quantum equations. It leads to local interpretation of non-relativistic quantum mechanics consistent with principle of locality and free of local hidden variables. The theory is applied to analysis of Einstein-Podolsky-Rosen (EPR) paradox, entanglement and properties of perturbed matter waves. We proved that formulated theory agrees with results of classical experiments on electron matter waves diffraction.