Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

N-electrons Dirac equation in Minkowski space

Ophelliam Loiselet

Published Jul 3, 2024• 0 citations
OpenAlex

Abstract

Quantum mechanics describes multi-electronic system by using non-relativistic probabilistic theories (non-relativistic many-body Hamiltonian, Bethe-Salpeter equation, Breit equation, density functional theory and so on).All of these theories are approximations and provide a probabilistic conception of quantum mechanics, which prevents it to be compatible with general relativity (or "macro scale" physics).Indeed, the real observable world (or Minkowski space) is for us a 3D+time space but quantum mechanics is expressed in multi-dimensional Hilbert space, which is not physical but purely mathematical.In this article we try to make a relativistic equation that gives a correct description of atomic physics in the real three-dimensional space for N ≥ 2 electrons systems: i.e a N-electrons Dirac equation.The starting point is to use the wave mechanics concept of De Broglie and Schrödinger: considering the electron as a mini oscillating cloud or matter-wave.For this we start from the Hartree equation, which gives already a 3D space description of each electron wave function.Then we jump into Hartree-Fock theory, that takes into account the electron exchange and can be also expressed in 3D, thanks to Slater-Condon rules.By extending the concept of exchange potential to a relativistic 4-exchange potential, and doing the same for the electron-electron repulsion potential, we have obtained a relativistic N electrons Dirac equation, in 3D+time space, including new relativistic interactions.The non-relativistic equivalence to Hartree-Fock equations will be demonstrated, which shows that the equation is already correct to describe light atoms.

Related papers

N-electrons Dirac equation in Minkowski space and the Helium test

Ophelliam Loiselet

Quantum mechanics describes multi-electronic systems by using probabilistic theories (non-relativistic many-body Hamiltonian, Bethe-Salpeter equation, Breit equation, density functional theory and so on).All of these theories are approximations and provide a probabilistic conception of quantum mechanics, which prevents it to be compatible with general relativity (or "macro scale" physics).Indeed, the real observable world (or Minkowski space) is for us a 3D+time space but quantum mechanics is expressed in multi-dimensional Hilbert space, which is not physical but purely mathematical.In this article we try to make a relativistic equation that gives a correct description of atomic physics in the real space for N ≥ 2 electrons systems: i.e a N-electrons Dirac equation.The starting point is to use the wave mechanics concept of De Broglie and Schrödinger: considering the electron as a matter-wave.For this we start from the Hartree equation, which gives already a 3D space description of each electron wave function.Then we jump into Hartree-Fock theory, that takes into account the electron exchange and can be also expressed in 3D, thanks to Slater-Condon rules.By extending the concept of exchange potential to a relativistic 4-exchange potential, and doing the same for the electron-electron repulsion, kinetic and rest mass energy: we obtain a relativistic N electrons Dirac equation, in 3D+time space that takes into account relativistic and correlation effects.The non-relativistic, stationary, uncorrelated and scalar approximation will show the reduction of the N-electrons Dirac equation into Hartree-Fock equation.

•Sep 13, 2024•0 citations

Constructing a 2-electrons Dirac equation in Minkowski space

Ophelliam Loiselet

Abstract Quantum mechanics describes multi-electronic systems by using probabilistic theories. All of these theories provide a probabilistic conception of quantum mechanics, with an astonishing accuracy (for instance the Helium atom ground state is computed with more than 20 digits of accuracy) but unfortunately seems to be a bit “disconnected” with macro-scale physics. Indeed, the real observable world is for us a 3D+time Minkowski space but quantum mechanics is expressed in multi-dimensional Hilbert space: which is not intuitively physical but seems to be purely mathematical. In this article we try to construct a relativistic equation that gives an approximately correct description of atomic physics in the spacetime (i.e the “real space”) for 2 electrons systems: i.e a 2-electrons Dirac equation. The starting point is to use the wave mechanics concept of De Broglie and Schrödinger: considering the electron as a matter-wave. For this we start from the Hartree equation, which gives already a spacetime description of each electron wave function. Then, we switch to Hartree-Fock representation, which gives birth to the exchange potential, that can be also expressed in spacetime. By extending the concept of exchange potential to the relativistic 4-exchange: we obtain a relativistic 2-electrons spacetime Dirac-Hartree-Fock (STDHF) equation (i.e in Minkowski space). That equation takes into account relativistic effects but not correlation effects, which is the difficulty of this study. Then we will show the equivalence of the 2-electrons STDHF equation with the Hartree-Fock equation in non-relativistic, stationary and scalar regime. Electron correlation issues will be discussed as well.

Journal of Physics Conference Series•Apr 1, 2025•0 citations

The Relativistic Configuration Space Formulation of the Multi-Electron Problem

Marian Günther

A relativistic configuration space (many-time) presentation of quantum electrodynamics is developed, which, being equivalent to the Tomonaga-Schwinger formalism, may be expected to have the advantage of its direct applicability to bound-state problems of multi-electron systems. The main purpose of this paper is therefore to get an evidently relativistically invariant description of the interactions between individual electrons, in such a way, however, as to avoid those divergence difficulties which may be accounted for by the use of electron plane waves for building up the actual state of the system. The order of the presentation is as follows: a general relativistically invariant proof of equivalence of the Tomonaga-Schwinger formalism and the many-time formalism of Dirac, Fock, and Podolski given in Sec. I will provide a necessary starting point for further generalization in the form of Eq. (53). This equation, when eventually solve in Sec. II, gives rise to a formal extension of the multi-electron wave function concept into regions for which the latter remained hitherto undefined. In Sec. III a method of elimination of virtual processes is outlined and invariant expressions for the multi-electron interactions are derived. All explicit derivations in this paper are carried out to terms of the order of ${e}^{2}$. An example, a relativistic two-electron wave equation, is given. This equation accounts for the Coulomb and Breit interactions.

Physical Review•Dec 15, 1952•16 citations

The track of 2-electrons Dirac Lagrangian in Minkowski space

Ophelliam Loiselet

In this paper, based on previous work, we are trying to describe 2-electrons atom using a real space representation of each electrons and starting by the Lagrangian formalism. The very compact Lagrangian formalism allows us to unlock a new potential that could takes into account the electron correlation energy, which is the last piece that forbids to express quantum mechanics in the real 3D+time space.

•Dec 29, 2024•0 citations

Phase space formulation of the quantum many-body problem

Paul H. Levine

By means of a quantum mechanical phase space distribution function introduced by von Roos, the Schroedinger equation for a non-relativistic system of N identical particles with scalar interactions is transformed into a quantum mechanical generalization of the Liouville equation, thereby formulating the problem in terms of a generalized density in phase space, a quantity of primary interest in most treatments of the corresponding classical system (or plasma). This transformation permits a parallel development of the theories of classical and quantum plasmas and thus allows the quantum many-body problem to be discussed virtually completely in classical terms. In particular, a kinetic theory of quantum plasmas is obtained by deriving the quantum analogue of the BBGKY hierarchy, and applying thereto approximation techniques similar to those of Rostocker and Rosenbluth, and Bogoliubov. The point of departure from similar previous studies based on the Wigner distribution function is that the proper exchange symmetry can be tractably introduced into the formalism. Attention is first focused on the Hartree and Hartree-Fock approximations, in which case the quantum BBGKY system reduces to a simple quantum generalization of the Vlasov equation. This equation is used to study the response of spatially homogeneous systems to weak external forces, and the associated problems of plasmon and spin-wave excitations. It is also used to derive the quantum and exchange corrected equations of inviscid hydrodynamical transport which are then applied to the problem of sound propagation in the degenerate electron gas. The second part of the study is concerned with the theory of the many-electron atom in the Hartree and Hartree-Fock approximations. The relevant quantum Vlasov equations lead naturally to a statistical theory of the atom which reduces to the Thomas-Fermi-Amaldi and Thomas Fermi models (respectively) as ħ → 0. For ħ ≠ 0, the quantum and exchange corrections to these models are simultaneously generated. The quantum hydrodynamical theory developed earlier is used to determine the influence of these corrections on the boundary conditions of the model, and a theory of the compressed atom is consequently obtained. Considered in somewhat less detail are the effects of non-zero temperature, net orbital angular momentum, relativity and correlations, as well as time dependent processes. The final part deals with the problem of the degenerate electron gas with a uniform neutralizing background. Going beyond the Hartree-Fock approximation, the pair functions for particles with parallel and anti-parallel spin are obtained by neglecting three particle correlations. From these functions, a quantum-mechanical collision integral is derived which differs from that obtained by Silin and Guernsey and conjectured by Wyld and Pines in that dynamical exchange effects are included. Also obtained from the pair function is an expression for the correlation which reduces in the high density limit to the result of Gell-Mann and Brueckner. At intermediate densities an additional term appears in the energy due to the screening of the exchange interaction by the dielectric properties of the medium. It is evaluated in the high density limit and found to be -0.151 r_s ln r_s Ryd/electron in marked disagreement with the corresponding value obtained by DuBois.

•Jan 1, 1963•0 citations

The 4-Dimensional Dirac Equation in Relativistic Field Theory

Wim Vegt

An important milestone in quantum physics has been reachedby the publication of the Relativistic Quantum MechanicalDirac Equation in 1928. However, the Dirac equationrepresents a 1-Dimensional quantum mechanical equationwhich is unable to describe the 4-Dimensional PhysicalReality.In this article the 4-Dimensional Relativistic QuantumMechanical Dirac Equation expressed in the vectorprobability functions  and the complex conjugated vectorprobability function  *will be published. To realize this, theclassical boundaries of physics has to be changed. It isnecessary to go back in time 300 years ago. More than 200years ago before the Dirac Equation had been published.A Return to the Inception of Physics. The time of IsaacNewton who published in 1687 in the “PhilosophiaeNaturalis Principia Mathematica” a Universal FundamentalPrinciple in Physics which was in Harmony with Science andReligion. The Universal Path, the Leitmotiv, the UniversalConcept in Physics. Newton found the concept of “UniversalEquilibrium” which he formulated in his famous thirdequation Action = - Reaction. This article presents a New Kind of Physics based on this Universal Fundamental Concept in Physics which results in a New Approach in Quantum Physics and General Relativity.The physical concept of quantum mechanical probability waves has been created during the famous 1927 5th Solvay Conference. During that period there were several circumstances which came together and made it possible to create an unique idea of material waves being complex (partly real and partly imaginary) and describing the probability of the appearance of a physical object (elementary particle). The idea of complex probability waves was new in the beginning of the 20th century. Since then the New Concept has been protected carefully within the Copenhagen Interpretation. When Schrödinger published his famous material wave equation in 1926, he found spherical and elliptical solutions for the presence of the electron within the atom. The first idea of the material waves in Schrödinger’s wave equation was the concept of confined Electromagnetic Waves. But according to Maxwell this was impossible. According to Maxwell’s equations Electromagnetic Waves can only propagate along straight lines and it is impossible that Light (Electromagnetic Waves) could confine with the surface of a sphere or an ellipse. For that reason these material waves in Schrödinger’s wave equation could only be of a different origin than Electromagnetic Waves. Niels Bohr introduced the concept of “Probability Waves” as the origin of the material waves in Schrödinger’s wave equation. And defined the New Concept that the electron was still a particle but the physical presence of the electron in the Atom was equally divided by a spherical probability function.In the New Theory it will be demonstrated that because of a mistake in the Maxwell Equations, in 1927 Confined Electromagnetic waves could not be considered to be the material waves expressed in Schrödinger's wave equation. The New Theory presents a new equation describing electromagnetic field configurations which are also solutions of the Schrodinger's wave equation and the relativistic quantum mechanical Dirac Equation and carry mass, electric charge and magnetic spin at discrete values.

European journal of applied sciences•Feb 10, 2021•14 citations
Quantum mechanics describes multi-electronic system by using non-relativistic probabilistic theories (non-relativistic many-body Hamiltonian, Bethe-Salpeter equation, Breit equation, density functional theory and so on).All of these theories are approximations and provide a probabilistic conception of quantum mechanics, which prevents it to be compatible with general relativity (or "macro scale" physics).Indeed, the real observable world (or Minkowski space) is for us a 3D+time space but quantum mechanics is expressed in multi-dimensional Hilbert space, which is not physical but purely mathematical.In this article we try to make a relativistic equation that gives a correct description of atomic physics in the real three-dimensional space for N ≥ 2 electrons systems: i.e a N-electrons Dirac equation.The starting point is to use the wave mechanics concept of De Broglie and Schrödinger: considering the electron as a mini oscillating cloud or matter-wave.For this we start from the Hartree equation, which gives already a 3D space description of each electron wave function.Then we jump into Hartree-Fock theory, that takes into account the electron exchange and can be also expressed in 3D, thanks to Slater-Condon rules.By extending the concept of exchange potential to a relativistic 4-exchange potential, and doing the same for the electron-electron repulsion potential, we have obtained a relativistic N electrons Dirac equation, in 3D+time space, including new relativistic interactions.The non-relativistic equivalence to Hartree-Fock equations will be demonstrated, which shows that the equation is already correct to describe light atoms.
Quantum mechanics describes multi-electronic systems by using probabilistic theories (non-relativistic many-body Hamiltonian, Bethe-Salpeter equation, Breit equation, density functional theory and so on).All of these theories are approximations and provide a probabilistic conception of quantum mechanics, which prevents it to be compatible with general relativity (or "macro scale" physics).Indeed, the real observable world (or Minkowski space) is for us a 3D+time space but quantum mechanics is expressed in multi-dimensional Hilbert space, which is not physical but purely mathematical.In this article we try to make a relativistic equation that gives a correct description of atomic physics in the real space for N ≥ 2 electrons systems: i.e a N-electrons Dirac equation.The starting point is to use the wave mechanics concept of De Broglie and Schrödinger: considering the electron as a matter-wave.For this we start from the Hartree equation, which gives already a 3D space description of each electron wave function.Then we jump into Hartree-Fock theory, that takes into account the electron exchange and can be also expressed in 3D, thanks to Slater-Condon rules.By extending the concept of exchange potential to a relativistic 4-exchange potential, and doing the same for the electron-electron repulsion, kinetic and rest mass energy: we obtain a relativistic N electrons Dirac equation, in 3D+time space that takes into account relativistic and correlation effects.The non-relativistic, stationary, uncorrelated and scalar approximation will show the reduction of the N-electrons Dirac equation into Hartree-Fock equation.
Abstract Quantum mechanics describes multi-electronic systems by using probabilistic theories. All of these theories provide a probabilistic conception of quantum mechanics, with an astonishing accuracy (for instance the Helium atom ground state is computed with more than 20 digits of accuracy) but unfortunately seems to be a bit “disconnected” with macro-scale physics. Indeed, the real observable world is for us a 3D+time Minkowski space but quantum mechanics is expressed in multi-dimensional Hilbert space: which is not intuitively physical but seems to be purely mathematical. In this article we try to construct a relativistic equation that gives an approximately correct description of atomic physics in the spacetime (i.e the “real space”) for 2 electrons systems: i.e a 2-electrons Dirac equation. The starting point is to use the wave mechanics concept of De Broglie and Schrödinger: considering the electron as a matter-wave. For this we start from the Hartree equation, which gives already a spacetime description of each electron wave function. Then, we switch to Hartree-Fock representation, which gives birth to the exchange potential, that can be also expressed in spacetime. By extending the concept of exchange potential to the relativistic 4-exchange: we obtain a relativistic 2-electrons spacetime Dirac-Hartree-Fock (STDHF) equation (i.e in Minkowski space). That equation takes into account relativistic effects but not correlation effects, which is the difficulty of this study. Then we will show the equivalence of the 2-electrons STDHF equation with the Hartree-Fock equation in non-relativistic, stationary and scalar regime. Electron correlation issues will be discussed as well.
A relativistic configuration space (many-time) presentation of quantum electrodynamics is developed, which, being equivalent to the Tomonaga-Schwinger formalism, may be expected to have the advantage of its direct applicability to bound-state problems of multi-electron systems. The main purpose of this paper is therefore to get an evidently relativistically invariant description of the interactions between individual electrons, in such a way, however, as to avoid those divergence difficulties which may be accounted for by the use of electron plane waves for building up the actual state of the system. The order of the presentation is as follows: a general relativistically invariant proof of equivalence of the Tomonaga-Schwinger formalism and the many-time formalism of Dirac, Fock, and Podolski given in Sec. I will provide a necessary starting point for further generalization in the form of Eq. (53). This equation, when eventually solve in Sec. II, gives rise to a formal extension of the multi-electron wave function concept into regions for which the latter remained hitherto undefined. In Sec. III a method of elimination of virtual processes is outlined and invariant expressions for the multi-electron interactions are derived. All explicit derivations in this paper are carried out to terms of the order of e2{e}^{2}e2. An example, a relativistic two-electron wave equation, is given. This equation accounts for the Coulomb and Breit interactions.
By means of a quantum mechanical phase space distribution function introduced by von Roos, the Schroedinger equation for a non-relativistic system of N identical particles with scalar interactions is transformed into a quantum mechanical generalization of the Liouville equation, thereby formulating the problem in terms of a generalized density in phase space, a quantity of primary interest in most treatments of the corresponding classical system (or plasma). This transformation permits a parallel development of the theories of classical and quantum plasmas and thus allows the quantum many-body problem to be discussed virtually completely in classical terms. In particular, a kinetic theory of quantum plasmas is obtained by deriving the quantum analogue of the BBGKY hierarchy, and applying thereto approximation techniques similar to those of Rostocker and Rosenbluth, and Bogoliubov. The point of departure from similar previous studies based on the Wigner distribution function is that the proper exchange symmetry can be tractably introduced into the formalism. Attention is first focused on the Hartree and Hartree-Fock approximations, in which case the quantum BBGKY system reduces to a simple quantum generalization of the Vlasov equation. This equation is used to study the response of spatially homogeneous systems to weak external forces, and the associated problems of plasmon and spin-wave excitations. It is also used to derive the quantum and exchange corrected equations of inviscid hydrodynamical transport which are then applied to the problem of sound propagation in the degenerate electron gas. The second part of the study is concerned with the theory of the many-electron atom in the Hartree and Hartree-Fock approximations. The relevant quantum Vlasov equations lead naturally to a statistical theory of the atom which reduces to the Thomas-Fermi-Amaldi and Thomas Fermi models (respectively) as ħ → 0. For ħ ≠ 0, the quantum and exchange corrections to these models are simultaneously generated. The quantum hydrodynamical theory developed earlier is used to determine the influence of these corrections on the boundary conditions of the model, and a theory of the compressed atom is consequently obtained. Considered in somewhat less detail are the effects of non-zero temperature, net orbital angular momentum, relativity and correlations, as well as time dependent processes. The final part deals with the problem of the degenerate electron gas with a uniform neutralizing background. Going beyond the Hartree-Fock approximation, the pair functions for particles with parallel and anti-parallel spin are obtained by neglecting three particle correlations. From these functions, a quantum-mechanical collision integral is derived which differs from that obtained by Silin and Guernsey and conjectured by Wyld and Pines in that dynamical exchange effects are included. Also obtained from the pair function is an expression for the correlation which reduces in the high density limit to the result of Gell-Mann and Brueckner. At intermediate densities an additional term appears in the energy due to the screening of the exchange interaction by the dielectric properties of the medium. It is evaluated in the high density limit and found to be -0.151 r_s ln r_s Ryd/electron in marked disagreement with the corresponding value obtained by DuBois.
An important milestone in quantum physics has been reachedby the publication of the Relativistic Quantum MechanicalDirac Equation in 1928. However, the Dirac equationrepresents a 1-Dimensional quantum mechanical equationwhich is unable to describe the 4-Dimensional PhysicalReality.In this article the 4-Dimensional Relativistic QuantumMechanical Dirac Equation expressed in the vectorprobability functions  and the complex conjugated vectorprobability function  *will be published. To realize this, theclassical boundaries of physics has to be changed. It isnecessary to go back in time 300 years ago. More than 200years ago before the Dirac Equation had been published.A Return to the Inception of Physics. The time of IsaacNewton who published in 1687 in the “PhilosophiaeNaturalis Principia Mathematica” a Universal FundamentalPrinciple in Physics which was in Harmony with Science andReligion. The Universal Path, the Leitmotiv, the UniversalConcept in Physics. Newton found the concept of “UniversalEquilibrium” which he formulated in his famous thirdequation Action = - Reaction. This article presents a New Kind of Physics based on this Universal Fundamental Concept in Physics which results in a New Approach in Quantum Physics and General Relativity.The physical concept of quantum mechanical probability waves has been created during the famous 1927 5th Solvay Conference. During that period there were several circumstances which came together and made it possible to create an unique idea of material waves being complex (partly real and partly imaginary) and describing the probability of the appearance of a physical object (elementary particle). The idea of complex probability waves was new in the beginning of the 20th century. Since then the New Concept has been protected carefully within the Copenhagen Interpretation. When Schrödinger published his famous material wave equation in 1926, he found spherical and elliptical solutions for the presence of the electron within the atom. The first idea of the material waves in Schrödinger’s wave equation was the concept of confined Electromagnetic Waves. But according to Maxwell this was impossible. According to Maxwell’s equations Electromagnetic Waves can only propagate along straight lines and it is impossible that Light (Electromagnetic Waves) could confine with the surface of a sphere or an ellipse. For that reason these material waves in Schrödinger’s wave equation could only be of a different origin than Electromagnetic Waves. Niels Bohr introduced the concept of “Probability Waves” as the origin of the material waves in Schrödinger’s wave equation. And defined the New Concept that the electron was still a particle but the physical presence of the electron in the Atom was equally divided by a spherical probability function.In the New Theory it will be demonstrated that because of a mistake in the Maxwell Equations, in 1927 Confined Electromagnetic waves could not be considered to be the material waves expressed in Schrödinger's wave equation. The New Theory presents a new equation describing electromagnetic field configurations which are also solutions of the Schrodinger's wave equation and the relativistic quantum mechanical Dirac Equation and carry mass, electric charge and magnetic spin at discrete values.