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A new look at the quantum Liouville theorem

Pui Tak Leung

Published Aug 8, 2020• 0 citations
OpenAlex

Abstract

We clarify certain confusions in the literature of the density operator in quantum mechanics, and demonstrate that the quantum Liouville theorem has the same form in both the Schrodinger and the Heisenberg pictures.Our starting point is to treat the density operator as an observable which has its specific time dependence in each of the two pictures.It is further shown that such a formulation will provide the exact correspondence between classical and quantum statistical mechanics with the Liouville theorem being interpreted as a conservation law, which is derivable from the equation of motion only in the quantum case.

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We clarify certain confusions in the literature of the density operator in quantum mechanics, and demonstrate that the quantum Liouville theorem has the same form in both the Schrodinger and the Heisenberg pictures.Our starting point is to treat the density operator as an observable which has its specific time dependence in each of the two pictures.It is further shown that such a formulation will provide the exact correspondence between classical and quantum statistical mechanics with the Liouville theorem being interpreted as a conservation law, which is derivable from the equation of motion only in the quantum case.
In classical mechanics the state of a system is defined by the numerical values of a set of dynamical variables such as the position coordinates and the velocities. In quantum mechanics the state of a system at an instant is represented by a unit vector in a Hilbert space, where a set of axes are the eigenvectors of a complete set of observables. The description of quantum dynamics where the wave function is time-dependent and the operators describing the observables are time-independent is known as the Schrodinger picture. The use of total time derivative of operator that depends on the time evolution of the wave function as well as on any intrinsic time-dependence in the operators simplifies the development of quantum mechanics and allows the development to more closely follow the corresponding development of classical mechanics. The difference between the Schrodinger and Heisenberg pictures is best understood as the difference in the basic set of observables.
We explore whether quantum field theory can be understood as the statistical mechanics of a time-reversal-invariant stochastic generalization of Hamiltonian dynamics. The motivation for this project, started with this paper, is to assign sharp values to all observables and thereby avoid the quantum measurement problem. In classical mechanics, motion is deterministic and corresponds to an evolution of the phase space probability density according to Liouville's equation that is governed by first derivatives of the Hamiltonian in phase space. We derive a generalization of the Liouville equation with natural constraints -- namely, reduction to classical Hamiltonian dynamics as the stochasticity parameter ℏ↦0\hbar\mapsto0ℏ↦0, Fokker-Planck form for the probability density evolution, local Hamiltonian dependence, time-reversal invariance, energy conservation, and minimality -- which turns out to be a Fokker-Planck equation with a generalized diffusion matrix that is symmetric, traceless, and constructed from the Hessian of the Hamiltonian. We then show that the Schrödinger equation in the coherent-state phase-space formulation of certain bosonic QFTs has precisely this form, with the Husimi function playing the role of the phase space probability density. The question to what extent this equation can be interpreted in terms of objective stochastic field theories is discussed in a companion paper.
Quantum mechanics takes various forms. For atomic and nuclear physics, the Schrödinger picture is convenient. For quantum field theory and for correspondence with classical mechanics through Poisson brackets, the Heisenberg picture is useful. The interaction picture is useful in calculations. The Wigner phase-space is convenient for studying the uncertainty relations and their symmetries. The density matrix and probability distribution are necessary for extracting measurable dynamic quantities and are essential for ensemble averages. Mathematical instruments, such as the Lie algebra of the rotation group, the creation and annihilation operators of the Fock space and the Lie algebra governing Dirac’s two oscillators are shown to be derivable from Heisenberg’s commutation relations.
In this chapter, the authors describe the Heisenberg picture of quantum mechanics by formally accomplishing a time-dependent transformation of state vectors and operators of the Schrodinger picture. Any new picture of quantum mechanics will be acceptable, if the Schrodinger state vectors and operators are subjected to a transformation, which does not alter: the spectrum of the eigenvalues of the operators and the scalar product of an arbitrary state vector with the eigenstate vectors. These two conditions are easily fulfilled by means of the unitary transformations. The authors show that a unitary operator represents an isomorph mapping of a certain unitary vector space onto itself. Since the physical quantities measured in the experiment are, in fact, a measure of the scalar product, as implied by the definition of the probability W through the scalar product in, it is clear that the predictions based upon the new, Heisenberg picture must be identical to those obtained in the Schrodinger picture.
Abstract This chapter introduces the density operator and the Liouville equation and outlines how reduced dynamical description of open quantum systems naturally leads to the appearance of relaxation processes. (1) The density operator and the quantum Liouville equation (the density matrix for a pure system, statistical mixtures, representations, coherences, thermodynamic equilibrium). (2) An example: The time evolution of a two-level system in the density matrix formalism. (3) Reduced descriptions. (4) Time evolution equations for reduced density operators: The quantum master equation (projection operators, The Nakajima–Zwanzig equation, Derivation of the quantum master equation using the thermal projector, The quantum master equation in the interaction representation, The Markovian limit—the Redfield equation, The secular approximation and the Lindblad equation). (5) The Lindblad equation in the ‘Heisenberg representation’. (6) Relaxation of a two-level system and a harmonic oscillator revisited. (7) The optically driven two-level system in a thermal environment—the Bloch equations. (8) The oscillating dipole model of a two-level molecule. (9) Analogy of a coupled two-level system to a spin ½ system in a magnetic field.
In the frames of classical mechanics the generalized Langevin equation is derived for an arbitrary mechanical subsystem coupled to the harmonic bath of a solid. A time-acting temperature operator is introduced for the quantum Klein-Kramers and Smoluchowski equations, accounting for the effect of the quantum thermal bath oscillators. The model of Brownian emitters is theoretically studied and the relevant evolutionary equations for the probability density are derived. The Schrodinger equation is explained via collisions of the target point particles with the quantum force carriers, transmitting the fundamental interactions between the point particles. Thus, electrons and other point particles are no waves and the wavy chapter of quantum mechanics originated for the force carriers. A stochastic Lorentz-Langevin equation is proposed to describe the underlaying Brownian-like motion of the point particles in quantum mechanics. Considering the Brownian dynamics in the frames of the Bohmian mechanics, the density functional Bohm-Langevin equation is proposed, and the relevant Smoluchowski-Bohm equation is derived. A nonlinear master equation is proposed by proper quantization of the classical Klein-Kramers equation. Its equilibrium solution in the exact canonical Gibbs density operator, while the well-known Caldeira-Leggett equation is simply a linearization at high temperature. In the case of a free quantum Brownian particles, a new law for the spreading of the wave packet it discovered, which represents the quantum generalization of the classical Einstein law of Brownian motion. A new projector operator is proposed for the collapse of the wave function of a quantum particle moving in a classical environment. Its application results in dissipative Schrodinger equations, as well as in a new form of dissipative Liouville equation in classical mechanics.