The notion of entropy has been at the core of thermodynamics and statistical physics since the 19th century, originally mentioned in the statement of the second law of thermodynamics as ``entropy is non-decreasing in an isolated system.'' In the context of both classical and quantum mechanics, there are cases where the second law is violated. In other words, entropy of the system may fluctuate downward. The question of how low or high the entropy of a quantum system can get is of interest in the context of small systems that can maintain quantum coherence for short times, and in the context of our universe, assuming it is an isolated quantum system. We explore the rare and extreme fluctuations of two well-developed notions of entropy that are relevant and interesting in isolated thermodynamic quantum systems, namely the observational and entanglement entropy. We find several fundamental differences in the behavior of the two when fluctuating to their extremes. We also provide an analytical proof of a tight upper bound on entanglement entropy for systems constrained to conservation laws.
The notion of entropy has been at the core of thermodynamics and statistical physics since the 19th century, originally mentioned in the statement of the second law of thermodynamics as ``entropy is non-decreasing in an isolated system.'' In the context of both classical and quantum mechanics, there are cases where the second law is violated. In other words, entropy of the system may fluctuate downward. The question of how low or high the entropy of a quantum system can get is of interest in the context of small systems that can maintain quantum coherence for short times, and in the context of our universe, assuming it is an isolated quantum system. We explore the rare and extreme fluctuations of two well-developed notions of entropy that are relevant and interesting in isolated thermodynamic quantum systems, namely the observational and entanglement entropy. We find several fundamental differences in the behavior of the two when fluctuating to their extremes. We also provide an analytical proof of a tight upper bound on entanglement entropy for systems constrained to conservation laws.
The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schrödinger equation, which preserves the von Neumann entropy. Nonetheless, one finds that with respect to many observables, expectation values approach a fixed value—their equilibrium value. This ultimately raises the question: ? For classical systems, one introduces the assumption of a low-entropy initial state along with the concept of ignorance about the microscopic details of the physical system, leading to a statistical interpretation of the second law. By considering the observables through which we examine quantum systems, both these assumptions can be incorporated, building upon recent studies of the of observables. While the statistical behavior of observable expectation values is well established, a quantitative connection to entropy increase has been lacking so far. In deriving novel bounds for the equilibration of observables, and considering the entropy of the system relative to observables, we recover a variant of the second law: the entropy with respect to a given observable tends toward its equilibrium value in the course of the system’s unitary evolution. These results also support recent findings that question the necessity of nonintegrability for equilibration in quantum systems. We further illustrate our bounds using numerical results from the paradigmatic example of a quantum Ising model on a chain of spins. There, we observe entropy increasing up to equilibrium values, as well as fluctuations, which expose the underlying reversible evolution in accordance with the derived bounds.
In this paper, we investigate and compare two well-developed definitions of entropy relevant for describing the dynamics of isolated quantum systems: bipartite entanglement entropy and observational entropy. In a model system of interacting particles in a one-dimensional lattice, we numerically solve for the full quantum behavior of the system. We characterize the fluctuations and find the maximal, minimal, and typical entropy of each type that the system can eventually attain through its evolution. While both entropies are low for some particular configurations and high for more generic ones, there are several fundamental differences in their behavior. Observational entropy behaves in accord with classical Boltzmann entropy (e.g., equilibrium is a condition of near-maximal entropy and uniformly distributed particles, and minimal entropy is a very compact configuration). Entanglement entropy is rather different: Minimal entropy ``empties out'' one partition while maximal entropy apportions the particles between the partitions, and neither is typical. Beyond these qualitative results, we characterize both entropies and their fluctuations in some detail as they depend on temperature, particle number, and box size.
Since the days of Boltzmann the foundation of thermodynamics has been subject to an ongoing discussion. Various problems like the precise definition of entropy, the origin of the second law, etc. have always been issues. For a long time the discussion has not been in the center of interest, for statistical physics work extremely well from a practical point of view. But now, as research deals with single small objects like molecules or atoms, the question arises whether or not thermodynamics are applicable to them, which leads back to the old question of the foundation of thermodynamics. We examine whether thermodynamics can be viewed as emerging from Schrödinger-type quantum dynamics. Therefore we partially transfer concepts of thermodynamical behavior in Gamma-space to the Hilbertspace of compound systems. Central roles play the local Von Neumann entropy of a system and the inevitability of entanglement with its environment, causing it to increase.
Classical thermodynamics is unrivalled in its range of applications and relevance to everyday life. It enables a description of complex systems, made up of microscopic particles, in terms of a small number of macroscopic quantities, such as work and entropy. As systems get ever smaller, fluctuations of these quantities become increasingly relevant, prompting the development of stochastic thermodynamics. Recently we have seen a surge of interest in exploring the quantum regime, where the origin of fluctuations is quantum rather than thermal. Many questions, such as the role of entanglement and the emergence of thermalisation, lie wide open. Answering these questions may lead to the development of quantum heat engines and refrigerators, as well as to vitally needed simple descriptions of quantum many-body systems.
We show that the second law of thermodynamics holds for isolated genuine quantum systems, where pure quantum states obey unitary dynamics, by a rigorous theoretical proof based on the Lieb-Robinson bound and numerical simulation. The entanglement entropy of a subsystem is shown connected to thermodynamic heat, highlighting the foundation of the information-thermodynamics link. Furthermore, we show that the nonequilibrium fluctuation theorem, characterizing the small probability of occasional entropy decrease, holds true for pure quantum states, which implies that thermal fluctuations emerge from purely quantum fluctuations in nonequilibrium dynamics. Our result establishes a scenario that thermodynamics emerges from quantum mechanics, and can experimentally be tested by ultracold atoms.
Thermodynamics is a phenomenological theory describing the energy conversion of work and heat. At its origins thermodynamics was developed in order to understand and improve heat engines. In conventional thermodynamics, however, only such processes are completely describable which are slow enough to keep the system of interest in an equilibrium state with its thermal environment at all times. On the contrary, all real physical processes are accompanied by non-equilibrium phenomena. These are mathematically described with the help of the irreversible entropy production, i.e. the dissipated work divided by the temperature of the bath. The second law of thermodynamics merely states that the irreversible entropy production is on average always positive. The modern trend of miniaturization, however, leads to smaller and smaller devices. On short length scales thermal noise as well as quantum fluctuations become important. Thus, usual thermodynamic quantities as work and heat acquire stochastic nature. Moreover, in the quantum regime a completely new theory had to be invented, since classical notions of work and heat are no longer valid. The present dissertation contributes to this prevailing field by the derivation of analytical expressions for the entropy production in open and closed quantum system far from thermal equilibrium. The theoretical treatment is motivated by an experimental point of view. The obtained results were derived from the reduced dynamics of the quantum mechanical system, which may be coupled to a thermal bath. To this end, it was dealt with methods and approaches of statistical physics, conventional thermodynamics, quantum information theory and the theory of open quantum systems. In this dissertation the most important physical systems are treated. First, an isolated system is considered before later on a heat bath is included. The limit of weak as well as of strong coupling are analyzed in detail. For isolated systems it turns out that a geometric approach is able to capture the thermodynamic properties, completely. To this end, the irreversible entropy production is sharply estimated from below by the angle between the real non-equilibrium state and the corresponding equilibrium one. Further, it is shown that the Heisenberg uncertainty relation for energy and time can be formulated more precisely in terms of that angle. As experimental system cold ion traps are introduced, in which the theoretical predictions can be verified. For weakly coupled systems, then, the irreversible entropy production is identified and a fluctuation theorem is derived by merely thermodynamic arguments. As experimental system we, again, propose the cold ion traps, where the heat bath can be simulated with the help of LASER light. In the limit of strong coupling a semiclassical description of the reduced quantum system is discussed. Again, an analytically exact expression for the entropy production and the corresponding fluctuation theorem is derived. A physical system, in which strong coupling to the environment can be analyzed, is given by Josephson junctions. This dissertation discusses the entropy production for isolated, weakly coupled, and overdamped quantum systems. For these physical regimes analytical relation are derived and experimental systems proposed, with which the predictions can be verified.