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Quantum Information Processing

Construction of a quantum Carnot heat engine cycle

Selçuk Çakmak, Mustafa Çandır, Ferdi Altintas

Published Aug 27, 2020• 16 citations
Publisher
DOI
10.1007/s11128-020-02831-1

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A cyclic thermodynamic heat engine runs most efficiently if it is reversible. Carnot constructed such a reversible heat engine by combining adiabatic and isothermal processes for a system containing an ideal gas. Here, we present an example of a cyclic engine based on a single quantum mechanical particle confined to a potential well. The efficiency of this engine is shown to equal the Carnot efficiency because quantum dynamics is reversible. The quantum heat engine has a cycle consisting of adiabatic and isothermal quantum processes that are close analogues of the corresponding classical processes.
We investigate, in an analytical fashion, quantum Carnot cycles of a microscopic heat engine coupled to two nite heat reservoirs, whose internal cycles could own higher e ciency than the standard Carnot limit without consuming extra quantum resources, e.g., coherence or squeezing properties. The engine runs time-dependently, involving both the internal and external cycles to collaboratively accomplish a complete Carnot cycle, and the e ciency of the engine depends on the reservoirs heat capacities and the working substance. Our analytical results of the maximum efficiency and the maximum power output clarify the mechanism behind the high performance of the microscopic engines, displaying the key roles played by the nite-sized heat reservoirs. Our proposal is generally valid for any microscopic thermodynamic system and fully feasible under current laboratory conditions.
The quantum analog of Carnot cycles in few-particle systems consists of two quantum adiabatic steps and two isothermal steps. This construction is formally justified by use of a minimum work principle. It is then shown, using minimal assumptions of work or heat in nanoscale systems, that the heat-to-work efficiency of such quantum heat engine cycles can be further optimized via two conditions regarding the expectation value of some generalized force operators evaluated at equilibrium states. In general the optimized efficiency is system specific, lower than the Carnot efficiency, and dependent upon both temperatures of the cold and hot reservoirs. Simple computational examples are used to illustrate our theory. The results should be an important guide towards the design of favorable working conditions of a realistic quantum heat engine.