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Quantum Thermodynamics of an Infinite System of Harmonic Oscillators

E. Verboven

Published Jan 1, 1967• 0 citations
OpenAlex

Abstract

Abstract Inequivalent representation of the commutation relations of an infinite system of harmonic oscillators with frequency ω (Einstein model of a crystal) are constructed and their physical significance is discussed.

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We consider a quantum system consisting of a one-dimensional chain of M identical harmonic oscillators with natural frequency ω, coupled by means of springs. Such systems have been studied before, and appear in various models. In this paper, we approach the system as a Wigner quantum system, not imposing the canonical commutation relations, but using instead weaker relations following from the compatibility of Hamilton’s equations and the Heisenberg equations. In such a setting, the quantum system allows solutions in a finite-dimensional Hilbert space, with a discrete spectrum for all physical operators. We show that a class of solutions can be obtained using generators of the Lie superalgebra gl(1∣M). Then we study – from a mathematical point of view – the properties and spectra of the physical operators in a class of unitary representations of gl(1∣M). These properties are both interesting and intriguing. In particular, we can give a complete analysis of the eigenvalues of the Hamiltonian and of the position and momentum operators (including multiplicities). We also study probability distributions of position operators when the quantum system is in a stationary state, and the effect of the position of one oscillator on the positions of the remaining oscillators in the chain.
As known all physical properties of solids are described well by the system of quantum linear harmonic oscillators. It is shown in the present paper that the system consisting of classical linear harmonic oscillators having temperature dependent masses or (and) frequencies has the same partition function as the system consisting of quantum linear harmonic oscillators having temperature independent masses and frequencies while the means of the square displacements of the positions of the oscillators from their mean positions for the system consisting of classical linear harmonic oscillators having: the temperature dependent masses; temperature dependent frequencies; and temperature dependent masses and frequencies differ from each other and from that of the system consisting of quantum linear harmonic oscillators, and hence, the system consisting of classical linear harmonic oscillators describes well the thermodynamic properties of the system consisting of quantum linear harmonic oscillators and solids.
The study of quantum properties of the harmonic oscillator is important in physics as many real-world systems oscillate harmonically. Motion of systems in a confined space is often modeled as being a quantized harmonic motion or, in first instance, is approximated by a harmonic motion. This chapter helps the reader to solve the equation employing an algebraic operator technique, which is based on the Dirac notation. This approach has several definite advantages and exploits the commutation relations among the operators involved and their properties. The chapter transforms the stationary Schrodinger equation into a second-order differential equation and finds the solution to the equation with the aid of a more advanced mathematical technique that involves special functions. The energy of a harmonic oscillator is quantized, with the sequence of values. The difference in energy between adjacent energy levels is equal to the energy of a single photon, ħω.
The harmonic oscillator is a useful model for the interpretation of many physical phenomena. It is used as a first approximation to the vibration of molecules and crystal lattices and for the quantization of electromagnetic fields, among other applications. One can solve the time-independent Schrodinger equation for the harmonic oscillator in many different ways; operator methods give rise to recurrence relations and generating functions for the stationary states. The coordinate representation renders the coordinate operator diagonal. In this particular representation the eigenvectors of the harmonic oscillator are functions of the coordinate that are commonly expressed in terms of Hermite polynomials. The chapter shows that calculation with the eigenfunctions of the harmonic oscillator is remarkably simple in the realm of the Lie algebras. The application of the bosonic algebra in theoretical physics and chemistry is so vast that it is impossible even to give a reasonable summary. An important application of the bosonic algebra is the modeling of simple quantum-mechanical systems.