We observe magnetic trapping of atomic nitrogen
(14N) and cotrapping of ground-state imidogen (
14NH, $X\phantom{\rule{0.2em}{0ex}}^{3}\ensuremath{\Sigma}^{\ensuremath{-}}$). Both are loaded directly from a room-temperature beam via buffer gas cooling. We trap approximately $1\ifmmode\times\else\texttimes\fi{}{10}^{11}$
14N atoms at a peak density of $5\ifmmode\times\else\texttimes\fi{}{10}^{11}\phantom{\rule{0.3em}{0ex}}{\mathrm{cm}}^{\ensuremath{-}3}$ at
550mK. The $12\ifmmode\pm\else\textpm\fi{}4\phantom{\rule{0.3em}{0ex}}\mathrm{s}$
1∕e lifetime of atomic nitrogen in the trap is consistent with a model for loss of atoms over the edge of the trap in the presence of helium buffer gas. Cotrapping of
14N and
14NH is accomplished, with
108 NH trapped molecules at a peak density of ${10}^{8}\phantom{\rule{0.3em}{0ex}}{\mathrm{cm}}^{\ensuremath{-}3}$.
In this work, we optically resolve and detect individual rubidium atoms trapped in solid neon. Additionally, we optically pump the rubidium's spin state using polarized light and measure the spin state via laser-induced fluorescence. When combined with the previously demonstrated magnetic field sensing capabilities of matrix-isolated rubidium atoms, these results are very promising for nanoscale sensing and for performing nuclear magnetic resonance (NMR) spectroscopy of individual molecules cotrapped in the matrix. Published by the American Physical Society 2024