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CRC Press eBooks

The Nonstationary Description of Matter

Nicolae Mazilu, Maricel Agop, Ioan Mercheş

Published Sep 12, 2019• 0 citations
Publisher

Abstract

The concept of a Madelung fluid makes us accept that the matter per se admits at least a description, if not even a physical structure, by ensembles of free Hertz material particles. This chapter elucidates the idea of physical freedom, according to the nonstationary Schrödinger equation. Louis de Broglie observed that either the standard deviation in the case of Gaussian, or the period ‘t’ in the case of Airy function, should be taken as ‘uncertainty parameters’ rather than geometrical quantities. According to Michael Berry and Nandor Balazs, the argument of Airy function actually represents a caustic, but in the phase space: it is the envelope of the ensemble of straight lines representing the corresponding uniform motions. The Berry-Klein theory of scaling the forces, in case it can be applied to a Wien-Lummer enclosure, acts as a universal gauging procedure which, in an undertaking of Georgescu-Roegen type, should be able to make us decide what is infrafinite, finite or transfinite.

DOI
10.1201/9780429329050-9

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The concept of a Madelung fluid makes us accept that the matter per se admits at least a description, if not even a physical structure, by ensembles of free Hertz material particles. This chapter elucidates the idea of physical freedom, according to the nonstationary Schrödinger equation. Louis de Broglie observed that either the standard deviation in the case of Gaussian, or the period ‘t’ in the case of Airy function, should be taken as ‘uncertainty parameters’ rather than geometrical quantities. According to Michael Berry and Nandor Balazs, the argument of Airy function actually represents a caustic, but in the phase space: it is the envelope of the ensemble of straight lines representing the corresponding uniform motions. The Berry-Klein theory of scaling the forces, in case it can be applied to a Wien-Lummer enclosure, acts as a universal gauging procedure which, in an undertaking of Georgescu-Roegen type, should be able to make us decide what is infrafinite, finite or transfinite.
The wave mechanics, with its quantum amendment, brings an important point to fore: a specific intervention of the geometry, in fact, of the differential geometry. The main result of Sir Michael Berry’s work on the geometry required by the existence of arbitrary phase factors makes its mark, showing that the nonstationary Schrödinger equation means much more than usually thought, when taken from the perspective of fundamental knowledge. There is a ‘Berry moment’ of the human knowledge, which carries, among others, the precise meaning of liberating the knowledge from the lock-up of adiabaticity, and this is reflected in the general attributes of this landmark of physics. The electromagnetic fields are, in general, Yang-Mills fields to be described in a geometry of the manifold of positions of Kepler orbits of classical material points. That geometry is a geometry of sl(2,R) Riemannian space. A Hertz material particle can be characterized exactly in the manner in which Schrödinger describes the color continuum.
Chapter 3 provides a brief review of a few concepts from classical Newtonian physics, and how this fails to explain phenomena at the nanoscopic scale. As is detailed within, the classical mechanical model is able to describe all observed physical phenomena; however, when it comes to the nanoscale this model breaks down, because the properties of the materials change dramatically. At this scale, the surface-to-volume ratio increases, gravitational forces become negligible and random molecular motion becomes more important. This changes the properties of the material and affects the devices that are fabricated at this scale. It is hence necessary to develop a new model that can explain such physical phenomena. This has led to a new branch of physics, i.e. quantum physics (QP) or quantum mechanics, which is able to explain the behavior observed at nanoscale. QP enables us to explain phenomena such as the photoelectric effect, Compton effect. etc. In this chapter, we introduce quantum mechanics and how it evolved in the late 19th and early 20th centuries. Further, light’s behaviour as a particle as well as a wave is described by the photoelectric effect and Young’s double-slit experiment, respectively. Further, the dual nature of the particle is explained using the de Broglie principle. Schrodinger’s equation is then explained, which gives the probability of finding a subatomic-scale particle at a certain position in a quantum well. In addition to the formulation of Schrodinger’s equation, its solution, the concept of a potential well, the characteristics of the wave function and its interpretation and significance, and, finally, the application of Schrodinger’s equation in the structure of an atom form subsequent parts of this chapter. The equation serves as a basis with which to understand band theory. Band theory explains the difference between conductors, insulators and semiconductors. Materials are distinguished according to the differences in their band gaps. Adding impurities or varying temperature changes the band gap in semiconductors, which consequently changes the properties of the semiconductor and its electrical conduction. One more important measure to understand and exploit the properties and behaviour of materials is Fermi–Dirac statistics. It is useful to acquire the probability of electrons at a given energy level at a specific temperature. These concepts can be utilised by physicists and chip makers to make more energy-efficient devices. Hence, this chapter details the fundamentals of quantum physics and how they relate to the electrical properties of nanodevices.
Every vertex of the magic cube of physics discussed so far introduced a major element in the development of physics and the whole of science. Mechanics introduced the basic concept of equations of motion, or time-evolution of a physical system given certain initial condition and the associated idea of determinism, even with its generalization in the form of chaos, the dependence of the outcomes of the temporal evolution on the initial conditions. These concepts taken for many particles, or elements of a physical system, led to the probabilistic description of many particle systems, in the realm of statistical physics and thermodynamics, whereby the averages over time of various observable quantities were related to the ensemble averages, that involve classical, so-called Kolmogorov, probability measures, at least for certain “equilibrium” situations. The second law of thermodynamics introduced the concept of entropy and its probabilistic increase, the first truly emergent, probabilistic law in physics (temperature and pressure, being other emergent quantities, apart from entropy, the measure of disorder of a statistical system). In the context of Newtonian gravity, one gets, at least in retrospect the geometric description of gravity in non-relativistic, Galilean spacetime. Galilean relativity, based on the asymmetric mixing of space and time, with the absolute, universal time, true for all observers, gets generalized in special theory of relativity to observer dependent space and observer dependent time, viewed as “slices” of a new concept of spacetime, with the new concept of causal structure, that distinguish timelike, null and spacelike events. This in turn is made into a full dynamical geometric structure of spacetime with a relativistic description of gravity stemming from curvature of spacetime, and a dynamical causal structure, tied to gravity. In our next story, the story of quantum theory, we will encounter fundamental, intrinsic probabilities, that can interfere, unlike the classical probabilities of statistical thermodynamics, and which are consistent with equations of motion of individual elements, and not, as in statistical thermodynamics, with temporal averages over the time evolution of many elements. This is the big new lesson of quantum theory, that transcends the lessons of classical spacetime physics.
Quantum hydrodynamics described by Madelung equations is analyzed in the framework of symplectic geometry i.e. in covariant phase space approach to geometric field theory. The pre-symplectic manifolds providing the phase spaces describing the Hamiltonian dynamics of quantum fluid are constructed from the set of all solutions of Madelung equations and their corresponding Lagrangian densities. The Madelung equations under consideration are the Madelung equations associated to Schroedinger equations (in the nonrelativistic case) and Madelung equations associated to Klein–Gordon equations (in the relativistic case). The cases where the coupling with electromagnetic fields is present are also considered here. Our symplectic formulation is different from that of [M. Spera, Moment map and gauge geometric aspects of the Schrodinger and Pauli equations, Int. J. Geom. Methods Mod. Phys. 13 (2016) 1–36] in the choice of fundamental fields or variables. Here we regard density function [Formula: see text] and phase function [Formula: see text] not as canonical pair but as the fundamental fields of the theory. The Hamiltonian vector fields corresponding to an observable are obtained from the Hamiltonian equation generated by the observable. The Poisson bracket of two observables then is determined by the Hamiltonian vector fields associated to each observable. In general, the Poisson bracket of two observables is not unique due to the fact that every observable has more than one corresponding Hamiltonian vector field. It is pointed out that the Poisson bracket has a unique value over a certain subset of the set of all observables defined on the pre-symplectic manifold of the Madelung equation under consideration.
Classical mechanics is usually valid at the macro scale. The changes in the position and the momentum of the object over time are described by the Hamiltonian equation of motion. The wave function in quantum mechanics, if unobserved, evolves in a smooth and continuous way according to the Schrodinger equation, which is related to the Hamiltonian equation of motion. This equation describes a linear superposition of different states at time. A quantum mechanical description of a physical system is related to a probabilistic representation; it is described by a vector in Hilbert space. This description extends the two- or three-dimensional Euclidean space into spaces that have any finite or infinite number of dimensions. The state of a compound system is projected to the subspace that corresponds to the observed state and the vector representing the state is renormalized to the unit length. An observable describes a subspace for some dimensions with a special case of one dimension.
This paper derives the non-relativistic time-dependent Schrödinger equation as the logically unavoidable dynamical law for de Broglie matter waves, extending the reconstruction begun in the companion work “The Logical Origin of the de Broglie Matter Wave and its Physical Meaning (the Born Rule)” (Chan, 2026). Starting from the same minimal premises—continuous position in real space, Fourier conjugacy (and the logical uncertainty principle), translation invariance via Noether’s theorem, and probability conservation via statistical energy flux—the Schrödinger equation follows deductively once norm preservation and classical non-relativistic correspondence are enforced. The derivation proceeds in clear stages: Plane-wave solutions for free particles and constant potentials, Quadratic dispersion relation from classical kinematics, Exact local plane-wave structure (defined via phase gradients) that must hold at every point for any smooth wave function, The unique linear differential operator of order ≤ 2 that consistently “glues” these local structures across smooth external potentials V(x,t) while preserving the L²-norm (unitarity). No canonical quantization, operator promotion, commutation relations, or postulated wave equations are used. The Born rule is taken as already established from the prior paper and serves only to constrain unitary evolution. The Schrödinger equation thus emerges not as an empirical postulate or convenient ansatz, but as the mathematically and symmetrically forced description of indivisible particles propagating in continuous, translationally invariant (or smoothly perturbed) space. Domain of validity and natural limitations (non-relativistic kinematics, smooth potentials, single-particle/mean-field regime, closed-system unitarity) are explicitly delineated.