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Zeitschrift für Physik D Atoms Molecules and Clusters

Population transfer between the fine-structure levels 5s5p 3 P 1 and 5s5p 3 P 0 of114Cd atoms by collisions with molecular gases

H. -P. Didra, M. Baumann

Published Jun 1, 1993• 3 citations
Publisher
DOI
10.1007/bf01450161

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ChemInform Abstract: Hyperfine Structure Transfer, Fine Structure Transfer, and Quenching of 113Cd Atoms in the 5s5p 3P1 State by Collisions with Molecular Gases

Th. von der Haar, C. KRAMER, M. BAUMANN

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

ChemInform•May 28, 1991•0 citations
Collisions of excited 113Cd(5 3P1) atoms with various molecular gases (N2, H2, D2, CO, CO2, CH4, C2H6, C2H4, O2) have been investigated using atomic fluorescence spectroscopy. By selective excitation of a hyperfine structure level with a pulsed dye laser and studying the time dependence of the fluorescence signals as a function of the buffer gas density the cross sections for quenching, fine structure transfer, and hyperfine structure transfer could be obtained. For N2 molecules the collisions can be described by a decoupling model as has been shown previously for the noble gases as collision partners.