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APS

Spin-polarized Penning Ionizing Collisions at Ultra-low Temperature

Chad Orzel, Uwe Sterr, M. Walhout, S. L. Rolston

Published Apr 1, 1997• 0 citations
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We consider the decay kinetics of a trapped spin-polarized gas of metastable triplet helium 4He(23S^{4}\mathrm{He}(2^{3}S4He(23S at ultralow temperatures. The sample lifetime is found to be determined by spin relaxation and Penning ionization, both induced by spin-dipole interaction in pair collisions. The rates of these processes are calculated. The Penning ionization proves to be 5 orders of magnitude slower than in the unpolarized case. The results indicate that spin-polarized triplet helium is a promising candidate for Bose-Einstein condensation.
A quantum-mechanical close-coupled calculation for collisions of spin-polarized triplet helium atoms in a magnetostatic trap is presented in which the Penning and associative ionization processes are represented by a complex optical potential. The rate coefficients for the spin relaxation and relaxation-induced Penning ionization processes for a range of magnetic fields and temperatures, spanning the cold and ultracold temperature regimes, have been calculated and the sensitivity of these results to uncertainties in the molecular potentials and autoionization width investigated. The rate constants for both elastic and inelastic processes were found to be particularly sensitive to the short-range ${}^{5}{\ensuremath{\Sigma}}_{g}^{+}$ molecular potential and, to a lesser extent, the rate constants for relaxation-induced Penning ionization displayed sensitivity to the short-range form of the ${}^{1}{\ensuremath{\Sigma}}_{g}^{+}$ molecular potential and the autoionization width.