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The imperfect quantum gas

D. ter Haar

Published Jan 1, 1971• 0 citations
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Using the free energy and the equation of state for an imperfect Bose gas, the analytical expression between the critical temperature and the length of dispersion wave and the pressure for the imperfect Bose gas is derived. The unusual properties of the specific heat at constant pressure and the expansion coefficient at constant pressure and isothermal compressibility by the attractive force for the imperfect Bose gas are revealed. The instability arising from the attractive force is pointed out, and the temperature criterion and particle density criterion of instability is given for the imperfect Bose gas under the action of attraction.

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We consider two-dimensional imperfect attractive Fermi and repulsive Bose gases consisting of spinless point particles whose total interparticle interaction energy is represented by $a{N}^{2}/2V$ with $a=\ensuremath{-}{a}_{F}\ensuremath{\le}0$ for fermions and $a={a}_{B}\ensuremath{\ge}0$ for bosons. We show that, in spite of the attraction, the thermodynamics of a $d=2$ imperfect Fermi gas remains well defined for $0\ensuremath{\le}{a}_{F}\ensuremath{\le}{a}_{0}={h}^{2}/2\ensuremath{\pi}m$, and is exactly the same as the one of the repulsive imperfect Bose gas with ${a}_{B}={a}_{0}\ensuremath{-}{a}_{F}$. In particular, for ${a}_{F}={a}_{0}$ one observes the thermodynamic equivalence of the attractive imperfect Fermi gas and the ideal Bose gas.

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We show that the pressure of the Bogoliubov weakly imperfect Bose gas (WIBG) can be calculated exactly in the thermodynamic limit. We point out the sufficient and necessary conditions for it not to equate with the pressure of the ideal Bose gas (IBG). We prove that they differ only in that part of the phase diagram where the WIBG has a Bose condensate. We show that in contast to the conventional Bose condensate (e.g. in the IBG) the condensate in the WIBG is due to an effective attraction between bosons in the zero-mode.

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The quantum ideal gas

J. P. Casquilho, P. I. C. Teixeira

Cambridge University Press eBooks•Dec 23, 2014•0 citations
Using the free energy and the equation of state for an imperfect Bose gas, the analytical expression between the critical temperature and the length of dispersion wave and the pressure for the imperfect Bose gas is derived. The unusual properties of the specific heat at constant pressure and the expansion coefficient at constant pressure and isothermal compressibility by the attractive force for the imperfect Bose gas are revealed. The instability arising from the attractive force is pointed out, and the temperature criterion and particle density criterion of instability is given for the imperfect Bose gas under the action of attraction.
We consider two-dimensional imperfect attractive Fermi and repulsive Bose gases consisting of spinless point particles whose total interparticle interaction energy is represented by aN2/2Va{N}^{2}/2VaN2/2V with $a=\ensuremath{-}{a}_{F}\ensuremath{\le}0$ for fermions and $a={a}_{B}\ensuremath{\ge}0$ for bosons. We show that, in spite of the attraction, the thermodynamics of a d=2d=2d=2 imperfect Fermi gas remains well defined for $0\ensuremath{\le}{a}_{F}\ensuremath{\le}{a}_{0}={h}^{2}/2\ensuremath{\pi}m$, and is exactly the same as the one of the repulsive imperfect Bose gas with ${a}_{B}={a}_{0}\ensuremath{-}{a}_{F}$. In particular, for aF=a0{a}_{F}={a}_{0}aF​=a0​ one observes the thermodynamic equivalence of the attractive imperfect Fermi gas and the ideal Bose gas.
We show that the pressure of the Bogoliubov weakly imperfect Bose gas (WIBG) can be calculated exactly in the thermodynamic limit. We point out the sufficient and necessary conditions for it not to equate with the pressure of the ideal Bose gas (IBG). We prove that they differ only in that part of the phase diagram where the WIBG has a Bose condensate. We show that in contast to the conventional Bose condensate (e.g. in the IBG) the condensate in the WIBG is due to an effective attraction between bosons in the zero-mode.