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Physics Today

Stories and statistics of bose

Michael Nauenberg

Published Jun 1, 2007• 0 citations
Publisher

Abstract

In his excellent article “The Man Behind Bose Statistics,” Kameshwar Wali mentions that Albert Einstein proposed to Bose that he work on two problems: “first, whether the new statistics implied a novel type of interaction between light quanta; and second, how the statistics of light quanta and transition probabilities would look in the new quantum mechanics.”Apparently, Bose did not make progress with either of the two questions, nor is there any evidence that Einstein considered them further. Bose had formulated an interaction between radiation and matter, 1 1. S. N. Bose, Z. Phys. 27, 383 (1924). which Einstein criticized because, according to Wali’s article, “the coefficient of absorption is independent of the density of the radiation.” It can be shown, without the need to appeal to the “new quantum theory,” that it is Einstein’s 1916 quantum theory for the interaction between matter and radiation 2 2. A. Einstein, in Sources of Quantum Mechanics, B. L. van der Waerden, ed., North-Holland, Amsterdam (1967), p. 63. that leads directly to Bose statistics. 3 3. M. Nauenberg, Am. J. Phys. 72, 313 (2004). https://doi.org/10.1119/1.1632488 Surprisingly, this deduction escaped the attention of Einstein, who otherwise would have discovered Bose statistics.REFERENCESSection:ChooseTop of pageREFERENCES <<1. S. N. Bose, Z. Phys. 27, 383 (1924). Google ScholarCrossref2. A. Einstein, in Sources of Quantum Mechanics, B. L. van der Waerden, ed., North-Holland, Amsterdam (1967), p. 63. Google Scholar3. M. Nauenberg, Am. J. Phys. 72, 313 (2004). https://doi.org/10.1119/1.1632488 , Google ScholarCrossref© 2007 American Institute of Physics.

DOI
10.1063/1.4796447

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Some time ago, John Bell and I wrote a tongue-in-cheek article on the interpretation of quantum mechanics;11. J. S. Bell, M. Nauenberg, in Preludes in Theoretical Physics, A. de Shalit, H. Feshbach, L. van Hove, eds., North Holland, Amsterdam (1966), p. 270;reprinted in J. S. Bell, Speakable and Unspeakable in Quantum Mechanics, Cambridge U. Press, New York (1987), p. 24. in it we remarked that only a minority of physicists had any interest in the topic and that the typical physicist thought he would understand it “if ever he can spare twenty minutes to think about it.” According to David Mermin, however, that situation has changed dramatically, and “new interpretations [of quantum mechanics] appear every year.”Actually, most textbooks on the subject continue to be based on the well-established Born interpretation of quantum mechanics, which postulates that the absolute square of the Schrödinger wavefunction, projected onto a particular quantum state, gives the probability for the occurrence of that state after an appropriate measurement has been made. Mermin indicated that the problem with the Born interpretation involves a confusion, “prevalent among physicists,” regarding the nature of probability. He presented his preference for a “personalist Bayesian view,” which leads separate “agents,” like Eugene Wigner and his friend, to make different probability assignments based on their beliefs. But as Richard Feynman remarked, “Nature does not know what you are looking at, and she behaves the way she is going to behave whether you bother to take down the data or not.”22. R. P. Feynman, R. B. Leighton, M. Sands, The Feynman Lectures on Physics, vol. 3, Addison-Wesley, Redwood City, CA (1989), p. 3–7.Indeed, as applied to experiments, probability simply corresponds to the relative frequency for the occurrence of a given final state after identical states are prepared initially and measurements are made by appropriate detectors—devices that, through an irreversible macroscopic process, provide a permanent record of the outcome. Hence, the results of an experiment are independent of any observers, whose only role is to set up appropriate measurement devices, calculate the probabilities from quantum theory, and then write papers based on the recorded results.As Max Born also emphasized, in classical mechanics the situation is analogous, when one takes into account that in practice initial conditions in an experiment are known only imprecisely.33. M. Born, Dan. Mat. Fys. Medd. 30 (2), 1 (1955). Hence the observed evolution of the system is also determined by a probability function that satisfies the Liouville equation. But in that case, after a measurement is performed, no one talks about the “collapse” of this classical function, whereas in quantum mechanics it is common to use that controversial expression for the Schrödinger wavefunction.Mermin discussed a “shifty split” between the classical and the quantum domain, a split that supposedly “haunts quantum mechanics.” He claimed that “regardless of what is split from what, all versions of the shifty split are vague and ambiguous.” However, that is not always the case, as a simple example shows. Consider an initial quantum wavepacket for a particle under an attractive central force that varies inversely with the square of the radial distance—the classic problem of planetary motion from the viewpoint of quantum mechanics, for example, or an excited electron in a Rydberg atom. For a finite time, the wavepacket will follow a classical Keplerian elliptic orbit, but like the Liouville distribution for the analogous classical problem, from the outset it will disperse due to the spread in initial position and momentum.For the classical distribution to be in close correspondence with the quantum wavepacket, its initial spread is assumed to satisfy the uncertainty relation. Eventually, however, the head of the wavepacket, like in the classical distribution, will catch up with its tail. Afterwards, further spreading of the wavepacket leads to interference effects between the two components, and the classical–quantum correspondence ceases to be valid. The time when such interference effects first appear is of order nτ/3, where n is the mean principal quantum number of the wavepacket and τ is the Kepler period.44. M. Nauenberg, Phys. Rev. A 40, 1133 (1989). https://doi.org/10.1103/PhysRevA.40.1133 Experimentally, that transition has been observed to agree with theory in Rydberg atoms55. M. Nauenberg, C. Stroud, J. Yeazell, Sci. Am., June 1994, p. 44. https://doi.org/10.1038/scientificamerican0694-44 for n = 100, τ = 152 picoseconds, and nothing shifty about this classical–quantum correspondence is found. For planetary orbits, however, n is of order 1070, and therefore the answer to Albert Einstein’s often repeated remark “Is the moon there when nobody looks?” (see David Mermin, Physics Today, April 1985, page 38) is yes.REFERENCESSection:ChooseTop of pageREFERENCES <<1. J. S. Bell, M. Nauenberg, in Preludes in Theoretical Physics, A. de Shalit, H. Feshbach, L. van Hove, eds., North Holland, Amsterdam (1966), p. 270; Google Scholarreprinted in J. S. Bell, Speakable and Unspeakable in Quantum Mechanics, Cambridge U. Press, New York (1987), p. 24. Google Scholar2. R. P. Feynman, R. B. Leighton, M. Sands, The Feynman Lectures on Physics, vol. 3, Addison-Wesley, Redwood City, CA (1989), p. 3–7. Google Scholar3. M. Born, Dan. Mat. Fys. Medd. 30 (2), 1 (1955). Google Scholar4. M. Nauenberg, Phys. Rev. A 40, 1133 (1989). https://doi.org/10.1103/PhysRevA.40.1133, Google ScholarCrossref, CAS5. M. Nauenberg, C. Stroud, J. Yeazell, Sci. Am., June 1994, p. 44. https://doi.org/10.1038/scientificamerican0694-44, Google ScholarCrossref© 2012 American Institute of Physics.

Physics Today•Nov 30, 2012•0 citations
In his excellent article “The Man Behind Bose Statistics,” Kameshwar Wali mentions that Albert Einstein proposed to Bose that he work on two problems: “first, whether the new statistics implied a novel type of interaction between light quanta; and second, how the statistics of light quanta and transition probabilities would look in the new quantum mechanics.”Apparently, Bose did not make progress with either of the two questions, nor is there any evidence that Einstein considered them further. Bose had formulated an interaction between radiation and matter, 1 1. S. N. Bose, Z. Phys. 27, 383 (1924). which Einstein criticized because, according to Wali’s article, “the coefficient of absorption is independent of the density of the radiation.” It can be shown, without the need to appeal to the “new quantum theory,” that it is Einstein’s 1916 quantum theory for the interaction between matter and radiation 2 2. A. Einstein, in Sources of Quantum Mechanics, B. L. van der Waerden, ed., North-Holland, Amsterdam (1967), p. 63. that leads directly to Bose statistics. 3 3. M. Nauenberg, Am. J. Phys. 72, 313 (2004). https://doi.org/10.1119/1.1632488 Surprisingly, this deduction escaped the attention of Einstein, who otherwise would have discovered Bose statistics.REFERENCESSection:ChooseTop of pageREFERENCES <<1. S. N. Bose, Z. Phys. 27, 383 (1924). Google ScholarCrossref2. A. Einstein, in Sources of Quantum Mechanics, B. L. van der Waerden, ed., North-Holland, Amsterdam (1967), p. 63. Google Scholar3. M. Nauenberg, Am. J. Phys. 72, 313 (2004). https://doi.org/10.1119/1.1632488 , Google ScholarCrossref© 2007 American Institute of Physics.
Abstract The year 2024 marks the 100th anniversary of the first article on Bose statistics. Bose breathed life into the Planck distribution of radiation by a microscopic derivation (Bose 1924Z. Phys.26178), adding a new insight, namelyindistinguishabilityinto the then evolving quantum theory. Einstein recognized the importance of this article and got it published. Using Bose statistics Einstein wrote an article on the theory (Einstein 1924Sutzungsber. Preuss. Akad. Wiss Phys.-Math Kl.261) of an ideal Bose gas and Bose–Einstein condensation. The groundbreaking discovery of Bose, an unveiling of a secret of quantum mechanics, continues to reverberate after a century. Bose’s paper is considered the fourth important paper in old quantum theory, following Planck’s (1900) article (Planck 1900Verh. Disch Phys. Ges.2202), Einstein’s (1905) photoelectric effect (Einstein 1905Ann. Phys., Lpz.17132) and Bohr’s model (1913) of the atom (Bohr 1913London, Edinburgh Dublin Phil. Mag. J. Sci.261). Dirac (1926Proc. R. Soc.A112661) coined the namebosonfor one of the two families of indistinguishable particles, the other family being fermion. The edifice of modern quantum field theory, many-body quantum theory, quantum-information and quantum-computing are built on bosons, fermions and anyons. The ever-blooming quantum garden of bosons has photons, gluons, W-bosons, mesons, Higgs-bosons, gravitons, phonons, magnons, excitons, plasmons, polaritons and so on. We present a brief historical account of Bose’s life and his discovery, followed by a bird’s eye view of the impacts of bosons in modern science and technology: from Bose’s distribution of 3-degree background radiation reaching us in the form of cosmic microwave background from the big bang era toboson sampling, a novel quantum computing method. Bosogenesis before Baryogenesis?: And God said, Let there be light: and there was light (Genesis, 1:4)
Classical electromagnetics in free space leaves no room for accommodation of a light particle. To underline this, it is sufficient to remember that Einstein in order to reach his lightquantum (energy-quantum) hypothesis had to mix classical theoretical physics with a piece of experimental information that defies description in classical terms. In his 1905-paper Einstein concluded [60]:Monochromatic radiation of low density (within the range of validity of Wien’s radiation formula) behaves thermodynamically as though it consisted of a number of mutually independent energy quanta of magnitude hν. The introduction of light quanta in the Wien regime (the high-frequency part of the Planck blackbody radiation law) is the first step toward the concept of electromagnetic radiation as a Bose gas of photons [180, 39, 68, 69]. Although a photon gas obeys Bose-Einstein statistics for all frequencies the statistical independence assumed by Einstein in 1905 is not true in general. Einstein used Boltzmann statistics when he conjectured the existence of light quanta. In the Wien regime Boltzmann and Bose-Einstein statistics lead to the same conclusion since the mean number of particles (photons) with a given energy is much less than one. The circumstance that the light quanta are not statistically independent in Bose-Einstein counting finds its explanation in quantum mechanics. Hence, the statistical correlation is induced by the requirement of totally symmetric wave functions.
In 1924, Satyendra Nath Bose's pioneering work laid the foundation for Bose-Einstein statistics, which describes particles with integral spins. His derivation of Planck's law for blackbody radiation bypassed classical assumptions, relying instead on the statistical mechanics of light quanta. Bose's methodology addressed limitations in existing theories, such as Einstein's dependence on classical concepts like Wien's displacement law and Bohr's correspondence principle. Further, his work underscored the incompatibility between classical electrodynamics and quantum theory, proposing innovative statistical approaches to thermodynamic equilibrium. The insights from Bose's work extend beyond theoretical physics. As was immediately noticed by Einstein, for temperatures below a critical threshold, Bose-Einstein statistics predicts the formation of a Bose-Einstein condensate (BEC), where particles condense en-masse into the ground state. This quantum phenomenon on a macroscopic scale opened avenues to explore new technologies in recent times, apart from throwing light on new phases of matter. This article revisits Bose's groundbreaking contributions, highlighting their enduring impact on quantum mechanics, statistical physics, and field theory.
We review here the main contributions of Einstein to the quantum theory. To put them in perspective we first give an account of Physics as it was before him. It is followed by a brief account of the problem of black body radiation which provided the context for Planck to introduce the idea of quantum. Einstein's revolutionary paper of 1905 on light-quantum hypothesis is then described as well as an application of this idea to the photoelectric effect. We next take up a discussion of Einstein's other contributions to old quantum theory. These include (i) his theory of specific heat of solids, which was the first application of quantum theory to matter, (ii) his discovery of wave-particle duality for light and (iii) Einstein's A and B coefficients relating to the probabilities of emission and absorption of light by atomic systems and his discovery of radiation stimulated emission of light which provides the basis for laser action. We then describe Einstein's contribution to quantum statistics viz Bose-Einstein Statistics and his prediction of Bose-Einstein condensation of a boson gas. Einstein played a pivotal role in the discovery of Quantum mechanics and this is briefly mentioned. After 1925 Einstein's contributed mainly to the foundations of Quantum Mechanics. We choose to discuss here (i) his Ensemble (or Statistical) Interpretation of Quantum Mechanics and (ii) the discovery of Einstein-Podolsky-Rosen (EPR) correlations and the EPR theorem on the conflict between Einstein-Locality and the completeness of the formalism of Quantum Mechanics. We end with some comments on later developments.
We discuss another of Einstein’s statistical contributions to quantum theory: his work on quantum statistics. It was prompted by a paper that S. Bose sent to him in 1924 when the physics community had finally accepted the photon idea upon the discovery and analysis of Compton scattering. We present in detail Bose’s derivation of Planck’s distribution, using a particle approach. Einstein extended Bose’s analysis of radiation to systems of matter particles. Here he made the discovery of the astounding phenomenon of Bose–Einstein condensation. The ultimate understanding of Planck’s spectral distribution came about in modern quantum mechanics with its notion of indistinguishable particles, and the connection between spin and statistics. We also provide a modern discussion of Bose–Einstein condensation.
Some time ago, John Bell and I wrote a tongue-in-cheek article on the interpretation of quantum mechanics;11. J. S. Bell, M. Nauenberg, in Preludes in Theoretical Physics, A. de Shalit, H. Feshbach, L. van Hove, eds., North Holland, Amsterdam (1966), p. 270;reprinted in J. S. Bell, Speakable and Unspeakable in Quantum Mechanics, Cambridge U. Press, New York (1987), p. 24. in it we remarked that only a minority of physicists had any interest in the topic and that the typical physicist thought he would understand it “if ever he can spare twenty minutes to think about it.” According to David Mermin, however, that situation has changed dramatically, and “new interpretations [of quantum mechanics] appear every year.”Actually, most textbooks on the subject continue to be based on the well-established Born interpretation of quantum mechanics, which postulates that the absolute square of the Schrödinger wavefunction, projected onto a particular quantum state, gives the probability for the occurrence of that state after an appropriate measurement has been made. Mermin indicated that the problem with the Born interpretation involves a confusion, “prevalent among physicists,” regarding the nature of probability. He presented his preference for a “personalist Bayesian view,” which leads separate “agents,” like Eugene Wigner and his friend, to make different probability assignments based on their beliefs. But as Richard Feynman remarked, “Nature does not know what you are looking at, and she behaves the way she is going to behave whether you bother to take down the data or not.”22. R. P. Feynman, R. B. Leighton, M. Sands, The Feynman Lectures on Physics, vol. 3, Addison-Wesley, Redwood City, CA (1989), p. 3–7.Indeed, as applied to experiments, probability simply corresponds to the relative frequency for the occurrence of a given final state after identical states are prepared initially and measurements are made by appropriate detectors—devices that, through an irreversible macroscopic process, provide a permanent record of the outcome. Hence, the results of an experiment are independent of any observers, whose only role is to set up appropriate measurement devices, calculate the probabilities from quantum theory, and then write papers based on the recorded results.As Max Born also emphasized, in classical mechanics the situation is analogous, when one takes into account that in practice initial conditions in an experiment are known only imprecisely.33. M. Born, Dan. Mat. Fys. Medd. 30 (2), 1 (1955). Hence the observed evolution of the system is also determined by a probability function that satisfies the Liouville equation. But in that case, after a measurement is performed, no one talks about the “collapse” of this classical function, whereas in quantum mechanics it is common to use that controversial expression for the Schrödinger wavefunction.Mermin discussed a “shifty split” between the classical and the quantum domain, a split that supposedly “haunts quantum mechanics.” He claimed that “regardless of what is split from what, all versions of the shifty split are vague and ambiguous.” However, that is not always the case, as a simple example shows. Consider an initial quantum wavepacket for a particle under an attractive central force that varies inversely with the square of the radial distance—the classic problem of planetary motion from the viewpoint of quantum mechanics, for example, or an excited electron in a Rydberg atom. For a finite time, the wavepacket will follow a classical Keplerian elliptic orbit, but like the Liouville distribution for the analogous classical problem, from the outset it will disperse due to the spread in initial position and momentum.For the classical distribution to be in close correspondence with the quantum wavepacket, its initial spread is assumed to satisfy the uncertainty relation. Eventually, however, the head of the wavepacket, like in the classical distribution, will catch up with its tail. Afterwards, further spreading of the wavepacket leads to interference effects between the two components, and the classical–quantum correspondence ceases to be valid. The time when such interference effects first appear is of order nτ/3, where n is the mean principal quantum number of the wavepacket and τ is the Kepler period.44. M. Nauenberg, Phys. Rev. A 40, 1133 (1989). https://doi.org/10.1103/PhysRevA.40.1133 Experimentally, that transition has been observed to agree with theory in Rydberg atoms55. M. Nauenberg, C. Stroud, J. Yeazell, Sci. Am., June 1994, p. 44. https://doi.org/10.1038/scientificamerican0694-44 for n = 100, τ = 152 picoseconds, and nothing shifty about this classical–quantum correspondence is found. For planetary orbits, however, n is of order 1070, and therefore the answer to Albert Einstein’s often repeated remark “Is the moon there when nobody looks?” (see David Mermin, Physics Today, April 1985, page 38) is yes.REFERENCESSection:ChooseTop of pageREFERENCES <<1. J. S. Bell, M. Nauenberg, in Preludes in Theoretical Physics, A. de Shalit, H. Feshbach, L. van Hove, eds., North Holland, Amsterdam (1966), p. 270; Google Scholarreprinted in J. S. Bell, Speakable and Unspeakable in Quantum Mechanics, Cambridge U. Press, New York (1987), p. 24. Google Scholar2. R. P. Feynman, R. B. Leighton, M. Sands, The Feynman Lectures on Physics, vol. 3, Addison-Wesley, Redwood City, CA (1989), p. 3–7. Google Scholar3. M. Born, Dan. Mat. Fys. Medd. 30 (2), 1 (1955). Google Scholar4. M. Nauenberg, Phys. Rev. A 40, 1133 (1989). https://doi.org/10.1103/PhysRevA.40.1133, Google ScholarCrossref, CAS5. M. Nauenberg, C. Stroud, J. Yeazell, Sci. Am., June 1994, p. 44. https://doi.org/10.1038/scientificamerican0694-44, Google ScholarCrossref© 2012 American Institute of Physics.