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Graduate texts in physics

Path Integral Formulation of Quantum Mechanics

Michael T. Strickland

Published Nov 1, 2019• 1 citation
Publisher

Abstract

This chapter introduces the path integral formulation of quantum mechanics as a rigorous and systematic alternative to canonical quantization. It begins by defining the transition probability amplitude (propagator) and deriving the path integral by discretizing time and summing over all possible intermediate paths between initial and final spacetime points. The chapter shows the final form of the propagator as a functional integral over all paths, weighted by the exponential of the action. This formulation provides an intuitive understanding that paths near the classical trajectory (which minimizes the action) interfere constructively, dominating the overall amplitude.

DOI
10.1007/978-3-032-14357-0_6

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This chapter introduces the path integral formulation of quantum mechanics as a rigorous and systematic alternative to canonical quantization. It begins by defining the transition probability amplitude (propagator) and deriving the path integral by discretizing time and summing over all possible intermediate paths between initial and final spacetime points. The chapter shows the final form of the propagator as a functional integral over all paths, weighted by the exponential of the action. This formulation provides an intuitive understanding that paths near the classical trajectory (which minimizes the action) interfere constructively, dominating the overall amplitude.
The conventional approach to quantum mechanics begins with the classical Hamiltonian and changes observables to noncommuting operators. Canonically conjugate observables have to be noncommuting operators in order to satisfy the Heisenberg uncertainty principle. The dynamics of a quantum mechanical system is given by the time-dependent Schrödinger equation. In the early 1940s Feynman realized that it would be possible to construct a quantum model using the classical Lagrangian approach (a method closely related to the action integral). Dirac had earlier pointed out that eit times the Lagrangian was analogous to a transformation function for the wave function in which the wave function at one instant could be related to the wave function at a next instant in a time interval of t by multiplying with such an exponential function. Feynman found the exponential phase factor to be the action S which is the time integral of the Lagrangian. Further, he noticed that it was necessary to perform integrals over all space variables at every instant of time to find the transition amplitudes. He developed a way for describing and evaluating the integration using the idea of integral over all paths. In Feynman’s approach, the particles are described using amplitudes calculated along the paths they may or may not follow. These amplitudes behave like waves, their phase changes as the quantum system moves along the path and the amplitudes for all paths superpose and interfere. This interference between all paths is called as sum-over-histories and the resulting amplitude is connected in the same way that the amplitude of a wave function is linked to probability as magnitude-squared.
To introduce the formalism of the functional integral in quantum mechanics, this chapter starts from the definition of the temporal evolution operator. It is important to emphasize that in the classical limit is not only the classic trajectory that have the grater contribution, but all the paths close to this also contribute. The chapter shows how integral formulation is perfectly consistent with Schrödinger's time-dependent differential equation. It retrieves this equation from definition of transition amplitude as a path integral. The chapter discusses functional derivative generalized to the case of the ordinary functional derivative. A very useful tool to solve problems related to functional integrals is the Wick rotation or Euclidean rotation. In quantum mechanics there are few problems we can solve exactly, and very often, when possible, we use perturbation theory to find an approximate solution. The chapter follows this approach with formalism of functional integration and construct a perturbation theory from which can be obtained a physical interpretation.
A path , in general, is defined by a determinate trajectory in time, from an initial to a final point. The classical trajectory is only one of the possible trajectories, and in quantum mechanics all the possible paths between the initial and final point come into play. Recall that the probability amplitude is a complex number that is assigned to each determinate path. Indeterminate paths are defined as a collection of determinate paths that are experimentally indistinguishable . In the Dirac–Feynman approach, the inherent indeterminacy of the quantum entity is realized by the degree of freedom – in undergoing time evolution – “taking” indeterminate paths [Baaquie (2013e)]. For a quantum degree of freedom evolving from an observed initial state to the observed final state – and with no other observations made – the Feynman path integral is a mathematical construction that computes the probability amplitudes by summing over all the allowed determinate paths of the degree of freedom – discussed in Feynman and Hibbs (1965), Zinn-Justin (1993), Zinn-Justin (2005) and Baaquie (2013e). Probability amplitude and time evolution Recall that the description of a quantum system, at a particular instant,isgiven by its state vector, namely |ψ>. To avoid confusion with the concept of a state vector, the term probability amplitude is used for describing a quantum entity undergoing transitions in time.
In this thesis we are investigating a different formalism of non-relativistic quantum mechanics called the path integral formalism. It is a generalization of the classical least action principle. The introduction to this subject begins with the construction of the path integral in terms of the idea of probability amplitudes whose absolute square gives the probability of finding a system in a particular state. Then we show that if the Lagrangian is a quadratic form one needs only to calculate the classical action besides from a time-dependent normalization constant to find the explicit expression of the path integral. We look in to the subject of two kinds of slit-experiments: The square slit, the single- and the double-Gaussian slit. Also, the propagator for constrained paths is calculated and applied to the Aharonov-Bohm effect, which shows that the vector potential defined in classical electrodynamics have a physical meaning in quantum mechanics. It is also shown that the path integral formulation is equivalent to the Schrödinger description of quantum mechanics, by deriving the Schrödinger equation from the path integral. Further applications of the path integral are discussed.
In this thesis we are investigating a different formalism of non-relativistic quantum mechanics called the path integral formalism.It is a generalization of the classical least action principle.The introduction to this subject begins with the construction of the path integral in terms of the idea of probability amplitudes whose absolute square gives the probability of finding a system in a particular state.Then we show that if the Lagrangian is a quadratic form one needs only to calculate the classical action besides from a time-dependent normalization constant to find the explicit expression of the path integral.We look in to the subject of two kinds of slit-experiments: The square slit, the single-and the double-Gaussian slit.Also, the propagator for constrained paths is calculated and applied to the Aharonov-Bohm effect, which shows that the vector potential defined in classical electrodynamics have a physical meaning in quantum mechanics.It is also shown that the path integral formulation is equivalent to the Schrödinger description of quantum mechanics, by deriving the Schrödinger equation from the path integral.Further applications of the path integral are discussed.
As an alternative formulation of quantum mechanics, path integral is based on the notion of transition amplitude which gives the wave function of a quantum system at a time t f by acting on the wave function at an earlier time ti.We show that for a general quadratic form for the Lagrangian of the system, transition amplitude has the form f (t f -ti)e i h S class., where S class. is the classical action.We then present an algebraic method to evaluate the function f (t f -ti) without refereing to the path integral calculations.We examine the presented method to the cases of free particle and harmonic oscillator and obtain their propagators.