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Work recoverable from two-particle information

Lev B. Levitin, Tommaso Toffoli

Published Jan 6, 2011• 0 citations
OpenAlex

Abstract

It is shown how information contained in the pair-wise correlations between atoms of a gas can be used to convert completely heat taken from a thermostat into mechanical work in a process of relaxation of the system to its thermal equilibrium state. Both classical correlations and quantum correlations (entanglement) are considered. The amount of heat converted into work is proportional to the entropy defect of the initial state of the system. The equivalence relation between information and work is explicitly demonstrated for the case of two-particle correlations. The amount of work obtained per particle is twice as large in the case of entanglement as in the case of classical correlations.

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Work recoverable from two-particle information

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It is shown how information contained in the pair-wise correlations between atoms of a gas can be used to convert completely heat taken from a thermostat into mechanical work in a process of relaxation of the system to its thermal equilibrium state. Both classical correlations and quantum correlations (entanglement) are considered. The amount of heat converted into work is proportional to the entropy defect of the initial state of the system. The equivalence relation between information and work is explicitly demonstrated for the case of two-particle correlations. The amount of work obtained per particle is twice as large in the case of entanglement as in the case of classical correlations.

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Thermodynamics and information have intricate interrelations. Often thermodynamics is considered to be the logical premise to justify that information is physical - through Landauer's principle -, thereby also linking information and thermodynamics. This approach towards information has been instrumental to understand thermodynamics of logical and physical processes, both in the classical and quantum domain. In the present work, we formulate thermodynamics as an exclusive consequence of information conservation. The framework can be applied to the most general situations, beyond the traditional assumptions in thermodynamics: we allow systems and thermal baths to be quantum, of arbitrary sizes and even possessing inter-system correlations.Here, systems and baths are not treated differently, rather both are considered on an equal footing. This leads us to introduce a ''temperature''-independent formulation of thermodynamics. We rely on the fact that, for a fixed amount of information, measured by the von Neumann entropy, any system can be transformed to a state with the same entropy that possesses minimal energy. This state, known as a completely passive state, acquires Boltzmann-Gibbs canonical form with an intrinsic temperature. We introduce the notions of bound and free energy and use them to quantify heat and work, respectively. Guided by the principle of information conservation, we develop universal notions of equilibrium, heat and work, Landauer's principle and universal fundamental laws of thermodynamics. We demonstrate that the maximum efficiency of a quantum engine with a finite bath is in general lower than that of an ideal Carnot engine. We introduce a resource theoretic framework for our intrinsic temperature based thermodynamics, within which we address the problem of work extraction and state transformations. Finally, the framework is extended to multiple conserved quantities.

•Feb 14, 2019•59 citations
It is shown how information contained in the pair-wise correlations between atoms of a gas can be used to convert completely heat taken from a thermostat into mechanical work in a process of relaxation of the system to its thermal equilibrium state. Both classical correlations and quantum correlations (entanglement) are considered. The amount of heat converted into work is proportional to the entropy defect of the initial state of the system. The equivalence relation between information and work is explicitly demonstrated for the case of two-particle correlations. The amount of work obtained per particle is twice as large in the case of entanglement as in the case of classical correlations.
It is shown how information contained in the pair-wise correlations between atoms of a gas can be used to convert completely heat taken from a thermostat into mechanical work in a process of relaxation of the system to its thermal equilibrium state. Both classical correlations and quantum correlations (entanglement) are considered. The amount of heat converted into work is proportional to the entropy defect of the initial state of the system. The equivalence relation between information and work is explicitly demonstrated for the case of two-particle correlations. The amount of work obtained per particle is twice as large in the case of entanglement as in the case of classical correlations.
The physical meaning of the entropy defect and information in quantum systems is analyzed in connection with Gibbs paradox and the M(uimLun work obtainable by use of a non-equilibrium system. The question is studied of the maximum amount of heat that can be converted into mechanical work in the process of isothermic mixing of two gases, whose molecules differ only in their quantum states, having non-commuting density matrices. It is shown that schemes for producing work that involve direct discrimination of nonorthogonal states (such as the method of semipermeable partitions) yield an amount of work that is determined not by the entropy ddect. but by the information in the system about its state, which reflects the fundamental irreversibility of the measurement process. An equivalence relation is suggested between quantum information and work.
According to the first and second laws of thermodynamics and the definitions of work and heat, microscopic expressions for the non-equilibrium entropy production have been achieved. Recently, a redefinition of heat has been presented in [Nature Communications volume 8, Article number: 2180 (2017)]. Since thermal operations play an important role in the resource theory of thermodynamics, it would be very interesting to find out the effect of the above-mentioned definition on the expression of the entropy production for these kind of operations. This is one of the aims of the present paper. Using the new definition of heat, it is shown that the entropy production is the same as the mutual information between a system and a bath both for thermal operations and, if the system-bath initial state is factorized, for entropy-preserving operations. It is also discussed that how one can recognize the type of the correlation between a system and a bath through knowledge of the initial state of the system only. It is shown that if the initial state of a system is diagonal in the energy basis, the thermal operations cannot create a quantum correlation between the system and the bath, however, if the system initial state is coherent Gibbs state, there cannot be classical correlation due to the thermal operations.
Thermodynamics and information have intricate interrelations. Often thermodynamics is considered to be the logical premise to justify that information is physical - through Landauer's principle -, thereby also linking information and thermodynamics. This approach towards information has been instrumental to understand thermodynamics of logical and physical processes, both in the classical and quantum domain. In the present work, we formulate thermodynamics as an exclusive consequence of information conservation. The framework can be applied to the most general situations, beyond the traditional assumptions in thermodynamics: we allow systems and thermal baths to be quantum, of arbitrary sizes and even possessing inter-system correlations.Here, systems and baths are not treated differently, rather both are considered on an equal footing. This leads us to introduce a ''temperature''-independent formulation of thermodynamics. We rely on the fact that, for a fixed amount of information, measured by the von Neumann entropy, any system can be transformed to a state with the same entropy that possesses minimal energy. This state, known as a completely passive state, acquires Boltzmann-Gibbs canonical form with an intrinsic temperature . We introduce the notions of bound and free energy and use them to quantify heat and work, respectively. Guided by the principle of information conservation, we develop universal notions of equilibrium, heat and work, Landauer's principle and universal fundamental laws of thermodynamics. We demonstrate that the maximum efficiency of a quantum engine with a finite bath is in general lower than that of an ideal Carnot engine. We introduce a resource theoretic framework for our intrinsic temperature based thermodynamics, within which we address the problem of work extraction and state transformations. Finally, the framework is extended to multiple conserved quantities.
Thermodynamics and information have intricate interrelations. Often thermodynamics is considered to be the logical premise to justify that information is physical - through Landauer's principle -, thereby also linking information and thermodynamics. This approach towards information has been instrumental to understand thermodynamics of logical and physical processes, both in the classical and quantum domain. In the present work, we formulate thermodynamics as an exclusive consequence of information conservation. The framework can be applied to the most general situations, beyond the traditional assumptions in thermodynamics: we allow systems and thermal baths to be quantum, of arbitrary sizes and even possessing inter-system correlations.Here, systems and baths are not treated differently, rather both are considered on an equal footing. This leads us to introduce a ''temperature''-independent formulation of thermodynamics. We rely on the fact that, for a fixed amount of information, measured by the von Neumann entropy, any system can be transformed to a state with the same entropy that possesses minimal energy. This state, known as a completely passive state, acquires Boltzmann-Gibbs canonical form with an intrinsic temperature. We introduce the notions of bound and free energy and use them to quantify heat and work, respectively. Guided by the principle of information conservation, we develop universal notions of equilibrium, heat and work, Landauer's principle and universal fundamental laws of thermodynamics. We demonstrate that the maximum efficiency of a quantum engine with a finite bath is in general lower than that of an ideal Carnot engine. We introduce a resource theoretic framework for our intrinsic temperature based thermodynamics, within which we address the problem of work extraction and state transformations. Finally, the framework is extended to multiple conserved quantities.