Waveguide quantum electrodynamics (waveguide QED) describes the interaction between an electromagnetic field confined to a one-dimensional waveguide with atom-like quantum emitters close by. The characteristics of these kinds of systems are the possibility for strong and even ultrastrong interactions between the photonic and atom-like systems, and practically infinite range interactions between the emitters. These properties are valuable for a wide range of quantum optical applications, like quantum communication, quantum networks and quantum metrology. In this thesis we focus on two challenges in quantum optics, namely the generation and scattering of multiphoton states. In the first part of this thesis we demonstrate how waveguide QED systems can be exploited for the generation of multiphoton states, in particular of single-mode Fock states and superpositions thereof as well as multi-mode photonic states with metrological applications. The basic setup for this goal is an ensemble of quantum emitters coupled to a waveguide. In the so-called atomic mirror configuration symmetric Dicke states (or a superposition thereof) decay superradiantly to the ground state and emit the desired multiphoton state, which can be efficiently collected at the ends of the waveguide. We propose various protocols for the preparation of these Dicke states in waveguide QED systems and characterize the emitted photonic state. It turns out that in the low excitation regime, that is, if the number of photons is much lower than the ensemble size, the photonic state is emitted into a single mode. This single-mode structure is fundamental to current proposals for applications in quantum metrology with optical interferometers. Outside the low excitation regime, a multi-mode photonic state is generated, for which the metrological capabilities were unknown. We were able to show that these states still lead to quantum-enhanced optical interferometry. In the second part of this thesis we demonstrate how the scattering of multiphoton states on a single quantum emitter coupled to the waveguide can be used for testing the limits of the light-matter interaction strength. In particular, we investigate systems in the so-called ultrastrong coupling regime, where the coupling strength between the photonic and atom-like system is of the order of the emitter's transition energy. In this regime, many methods and approximations used in quantum optics, especially the Rotating Wave Approximation, break down and one needs to develop new analytical and numerical methods to study these systems. One approach is the so-called polaron Transformation. We show how this transformation can be applied for predicting the scattering amplitude of few photons scattering on the emitter. The comparison of these results with numerical simulations using matrix product states shows a good agreement for moderate coupling strengths. Both parts together show that waveguide QED systems are promising candidates for the generation of multiphoton states as well as for the investigation of fundamental limits probed through the scattering of multiphoton states. The latter also finds application in the implementation of photon-photon nonlinearities induced by the interaction with the quantum emitters. Apart from these and many other theoretical predictions, waveguide QED systems are also undergoing rapid progress in experiments. Therefore, we expect these kinds of systems to bring forth several advances in the field of quantum optics.
We give an exposure to diagrammatic techniques in waveguide quantum electrodynamics (QED) systems. A particular emphasis is placed on the systems with delayed coherent quantum feedback. Specifically, we show that the
N-photon scattering matrices in single-qubit waveguide QED systems, within the rotating wave approximation, admit for a parametrization in terms of ($N\ensuremath{-}1$)-photon effective vertex functions and provide a detailed derivation of a closed hierarchy of generalized Bethe-Salpeter equations satisfied by these vertex functions. The advantage of this method is that the above-mentioned integral equations hold independently of the number of radiation channels, their bandwidth, the dispersion of the modes they are supporting, and the structure of the radiation-qubit coupling interaction, thus enabling one to study multiphoton scattering problems beyond the Born-Markov approximation. Further, we generalize the diagrammatic techniques to the systems containing more than a single emitter by presenting an exact set of equations governing the generic two- and three-photon scattering operators. The above-described theoretical machinery is then showcased on the example of a three-photon scattering on a giant acoustic atom, recently studied experimentally [G. Andersson et al., Nat. Phys. 15, 1123 (2019)].
Strongly correlated multi-photon states are indispensable resources for advanced quantum technologies, yet their deterministic generation remains challenging due to the inherent weak nonlinearity in most optical systems. Here, we propose a scalable architecture for producing correlated few-photon entangled states via cascaded inelastic scattering in a nonlinear waveguide. When a single photon scatters off a far detuned excited two-level emitter, it coherently converts into a propagating doublon, a bound photon pair with anomalous dispersion. This doublon can subsequently scatter off a downstream excited emitter to further convert into a triplon, and so on, thereby establishing a photon-number amplification cascade
∣⋅⟩→∣:⟩→∣∴⟩→... Central to this process is the concept of a pseudo-giant atom, which we introduce here to capture the non-local scattering potential emergent from the wave functions of bound states. By implementing this scheme using a real giant atom with multiple engineered coupling points, we achieve unidirectional and full controllable photon conversion without backscattering. The resulting output state forms a programmable superposition of spatially and temporally isolated photon-number components, automatically sorted by their distinct group velocities. This work opens a new paradigm in quantum state engineering, enabling on-demand generation of complex multi-photon resources for quantum simulation, metrology, and scalable quantum networks.