The entropy approach to a description of quantum processes, represented like the Markov chain, is elaborated. It is supposed that at an atomic scale the law of the conservation of entropy holds. From this principle issues the simple explanation of the different behavior of bosons and fermions in experiments with scattering particles, proved by Pauli. Introducing in consideration Markov’ chain, applied to a motion of particles, made possible to write an equation, determining the change of their states. This pure logical result, completed by physical laws, brought to a new equation, generalizing Schrödinger one. It includes electric and magnetic fields as well as the spin of particles. Analysis of its solution for a case of only electric field, led to the formula of tunnel effect. Consideration of the motion of a particle in magnetic field gave the fundamental expression of Lorentz force without any mention of electrodynamics. Addition of an angular momentum in the reasoning by including Hamiltonian, allowed deducing the result, which coincides with the spherically symmetric Schrödinger equation for hydrogen atom. In general case there is the system of equations. If the atom is put in a weak magnetic field, without a possibility of flipping, the classical formulas of Bohr radius orbits and Rydberg energy obtained. The property of intrinsic quantization of electron spin ħ/2 is explained easily as a solution of the proposed system. These equations do not repeat the known arguments only, but can predict the new phenomena. They describe the effect of spin depolarization of electrons in a strong magnetic field, earlier considered been related to vacuum polarization. The obtained solution gives its magnetic induction equal about 1012 Gs, that corresponds well with experimental data.
The entropy approach to a description of quantum processes, represented like the Markov chain, is elaborated. It is supposed that at an atomic scale the law of the conservation of entropy holds. From this principle issues the simple explanation of the different behavior of bosons and fermions in experiments with scattering particles, proved by Pauli. Introducing in consideration Markov’ chain, applied to a motion of particles, made possible to write an equation, determining the change of their states. This pure logical result, completed by physical laws, brought to a new equation, generalizing Schrödinger one. It includes electric and magnetic fields as well as the spin of particles. Analysis of its solution for a case of only electric field, led to the formula of tunnel effect. Consideration of the motion of a particle in magnetic field gave the fundamental expression of Lorentz force without any mention of electrodynamics. Addition of an angular momentum in the reasoning by including Hamiltonian, allowed deducing the result, which coincides with the spherically symmetric Schrödinger equation for hydrogen atom. In general case there is the system of equations. If the atom is put in a weak magnetic field, without a possibility of flipping, the classical formulas of Bohr radius orbits and Rydberg energy obtained. The property of intrinsic quantization of electron spin ħ/2 is explained easily as a solution of the proposed system. These equations do not repeat the known arguments only, but can predict the new phenomena. They describe the effect of spin depolarization of electrons in a strong magnetic field, earlier considered been related to vacuum polarization. The obtained solution gives its magnetic induction equal about 1012 Gs, that corresponds well with experimental data.
We expose the Schrödinger quantum mechanics with traditional applications to Hydrogen atom. We discuss carefully the experimental and theoretical background for the introduction of the Schrödinger, Pauli and Dirac equations, as well as for the Maxwell equations. We explain in detail all basic theoretical concepts. We explain all details of the calculations and mathematical tools: Lagrangian and Hamiltonian formalism for the systems with finite degree of freedom and for fields, Geometric Optics, the Hamilton-Jacobi equation and WKB approximation, Noether theory of invariants including the theorem on currents, four conservation laws (energy, momentum, angular momentum and charge), Lie algebra of angular momentum and spherical functions, scattering theory (limiting amplitude principle and limiting absorption principle), the Lienard-Wiechert formulas, Lorentz group and Lorentz formulas, Pauli theorem and relativistic covariance of the Dirac equation, etc. We give a detailed oveview of the conceptual development of the quantum mechanics, and expose main achievements of the ``old quantum mechanics'' in the form of exercises. One of our basic aim in writing this book, is an open and concrete discussion of the problem of a mathematical description of the following two fundamental quantum phenomena: i) Bohr's quantum transitions and ii) de Broglie's wave-particle duality. Both phenomena cannot be described by autonomous linear dynamical equations, and we give them a new mathematical treatment related with recent progress in the theory of global attractors of nonlinear hyperbolic PDEs.
The Schrödinger-Pauli (SP) theory of electrons in an electromagnetic field explicitly accounts for the electron spin moment. The many-electron theory is complemented via a new descriptive perspective viz. that of the individual electron via its equation of motion or ‘Quantal Newtonian’ first law. The law is in terms of ‘classical’ fields whose sources are quantum mechanical expectation values of Hermitian operators taken with respect to the system wave function. The law states that each electron experiences an external and an internal field, the sum of which vanish. The external field is the sum of the binding electrostatic and a Lorentz field. The internal field is a sum of fields representative respectively of electron correlations due to the Pauli principle and Coulomb repulsion; the electron density; kinetic effects; and an internal magnetic field. The energy can be expressed in integral virial form in terms of these fields. The law is elucidated by application to the 23S state of a quantum dot in a magnetic field. It is proved that the Hamiltonian is an exactly known and universal functional of the wave function. This generalizes the SP equation, and reveals that its eigenfunctions and eigenvalues may be determined self-consistently. A Quantal density functional theory (QDFT) of the SP system is developed whereby additional properties are determined. A physical interpretation of Spin-DFT based on the QDFT mapping is provided. Further generalizations of the present work to the temporal case, and relativistic Dirac theory, are proposed.
Despite its successes, quantum mechanics (QM) has remained mysterious to all who have encountered it. Starting with Bohr and progressing into the present, the departure from intuitive, physical reality has widened. The connection between QM and reality is more than just a “philosophical” issue. It reveals that QM is not a correct or complete theory of the physical world and that inescapable internal inconsistencies and incongruities arise when attempts are made to treat it as physical as opposed to a purely mathematical “tool.” Some of these issues are discussed in a review by F. Laloe [Am. J. Phys. 69, 655 (2001)]. In an attempt to provide some physical insight into atomic problems and starting with the same essential physics as Bohr of e moving in the Coulombic field of the proton and the wave equation as modified by Schrodinger, a classical approach is explored that yields a remarkably accurate model and provides insight into physics on the atomic level. The proverbial view, deeply seated in the wave-particle duality notion, that there is no large-scale physical counterpart to the nature of the electron may not be correct. Physical laws and intuition may be restored when dealing with the wave equation and quantummechanical problems. Specifically, a theory of classical quantum mechanics (CQM) is derived from first principles that successfully applies physical laws on all scales. Rather than using the postulated Schrodinger boundary condition “Ψ → 0 as r → ∞,” which leads to a purely mathematical model of the electron, the constraint is based on experimental observation. Using Maxwell’s equations, the classical wave equation is solved with the constraint that the bound (n = 1)state electron cannot radiate energy. By further application of Maxwell’s equations to electromagnetic and gravitational fields at particle production, the Schwarzschild metric is derived from the classical wave equation, which modifies general relativity to include conservation of spacetime in addition to momentum and matter/energy. The result gives a natural relationship among Maxwell’s equations, special relativity, and general relativity. CQM holds over a scale of spacetime of 85 orders of magnitude — it correctly predicts the nature of the universe from the scale of the quarks to that of the cosmos. A review is given by G. Landvogt [Internat. J. Hydrogen Energy 28, 1155 (2003)].
Spin is an intrinsic form of angular momentum carried by elementary particles, composite particles, and atomic nuclei. It is wildly believed that spin is a purely quantum mechanical concept and has no classical analogue. In fact, elementary particles are conceived as point objects which have no axis to “spin” around. Therefore, there is no explaining how spin arises at the fundamental level, why particles have the values they do, and what underpins the Pauli Exclusion principle and Bose-Einstein behavior. However, spin is like a vector quantity; it has a definite magnitude, and it has a “direction”, in order to spin should be composite. In this paper we propose a physical explanation for spin of the electron at the sub-particle level, relying on the vortex model of the electron. The electron is described as a superfluid frictionless vortex which has a mass, angular momentum and spin to provide a complete explanation of all properties of the electron: it composite, spinning around its own axis, produces a tiny magnetic fields independent of those from its orbital motions. The classical hydrodynamic laws are used to describe the quantum properties of the electron, such as spin, angular momentum, magnetic momentum and a magnetic dipole. The circulation in the vortex is constant, and the angular momentum of the vortex is conserved and has the same value of Planck constant. The direction of the angular momentum of a spinning electron vortex is along the axis of rotation and determined by the direction of spin. The spin quantum number 1/2 has a fixed value which represents the gap between the circulation rate of the core of the vortex and the boundaries of the vortex. The changeable values +1/2 “spin-up” or -1/2 “spin-down” indicate the direction of the magnetic dipole of the vortex. The relation between spin and Planck constant is discussed and the origin h/4pi angular momentum units are revealed.
Chapter 4 deals with Quantum Mechanical (QM) phenomena. The first section describes the first attempts at quantization of energy, momentum, angular momentum, etc. We start with Plank's solution to the black-body problem, introducing the concept of photons: discrete packets of electromagnetic energy. We show how Plank's description of black-body radiation is perfectly fit by the cosmic microwave radiation, providing the strongest evidence for the Big-Bang at the origin of the Universe. We then describe Bohr's solution to the paradoxical stability of atoms, introducing quantization of angular momentum (or action) and correctly predicting the energy levels of the hydrogen atom. We show how Einstein used Plank's idea to explain the photo-electric effect (an effect exploited in CCD cameras and solar cells) and how he used Bohr's understanding of energy levels in atoms to provide an intuitive explanation of Plank's law. Einstein insight opened the way to the field of spectroscopy and the development of the laser. In the second section, following the lead of Dirac, we show that QM is equivalent to Linear Algebra in the space of complex functions (which describe the state of the system). We show that Schrödinger's equation is a natural consequence of that description, once the relation between energy and frequency established by Plank (for photons) and de Broglie (for particles) is taken into account. In the context of the chiral ammonia molecule we discuss the queerness of QM which describes physical systems as superposition of states (such as left and right chirality state of a molecule, dead and alive cat). We show that this queerness is nonetheless supported by experiments and is behind much of our technology: masers and lasers, atomic clocks, semiconductors (diodes, transistors, etc.). In the following section we introduce the representation of operators in QM (the equivalent of matrices in linear algebra): momentum, position, energy, etc. which correspond to measurements on the system. We show that the non-commutability of some operators (common with matrix operations) leads to Heisenberg uncertainty principle: the position and momentum of a particle cannot be determined with absolute precision. We discuss the solution of Schrödinger's equation for free particles demonstrating their equivalence with EM phenomena: particles undergo refraction and diffraction, exemplifying the particle/wave duality inherent to QM systems. We discuss QM tunneling and its use in the Scanning Tunneling Microscope. In the following section we study Dirac's equation: the successful attempt by Dirac to unify QM with Einstein's relativity, with the resulting prediction of anti-particles and spin. We then solve for the energy levels of electrons in the hydrogen atom (from Schrödinger's equation) and show that the existence of spin profoundly affects the behavior of electrons in an atom: they cannot share the same energy level, a rule known as Pauli's exclusion principle. Pauli's principle is central to the understanding of the chemical properties of atoms and fully explains Mendeleev's periodic table of the elements. In the next section we discuss along with two exactly soluble systems (diatomic rotational and vibrational levels), various approximations used to study systems (e.g. molecules) for which there are no analytical solutions. In particular, we introduce Pauling's variational approach, Hückel molecular orbital theory and time independent perturbation theory. We apply those approaches to determine the energy levels in alkenes, in multi-electron atoms and in systems under constant electric or magnetic field (such as in Magnetic Resonance Imaging). In the last section we discuss time dependent perturbation theory. We use it to establish the rules allowing for transitions between energy levels and revisit Einstein description of absorption/emission phenomena.
Abstract The Schrödinger–Pauli (SP) theory of electrons in an electromagnetic field explicitly accounts for the electron spin moment. The many‐electron theory is complemented via a new descriptive perspective namely, that of the individual electron via its equation of motion or “Quantal Newtonian” first law. The law is in terms of ‘classical’ fields whose sources are quantum mechanical expectation values of Hermitian operators taken with respect to the system wave function. The law states that each electron experiences an external and an internal field, the sum of which vanish. The external field is the sum of the binding electrostatic and a Lorentz field. The internal field is a sum of fields representative respectively of electron correlations due to the Pauli principle and Coulomb repulsion; the electron density; kinetic effects; and an internal magnetic field. The energy can be expressed in integral virial form in terms of these fields. The law is elucidated by application to the 23S state of a quantum dot in a magnetic field. It is proved that the Hamiltonian is an exactly known and universal functional of the wave function. This generalizes the SP equation, and reveals that its eigenfunctions and eigenvalues may be determined self‐consistently. A quantal density functional theory (QDFT) of the SP system is developed whereby additional properties are determined. A physical interpretation of Spin‐DFT based on the QDFT mapping is provided. Further generalizations of the present work to the temporal case, and relativistic Dirac theory, are proposed.